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Metal Organic Framework 199- Catalyzed Domino Sulfur-Coupling and Transfer Reactions: The Direct Synthesis of Symmetric Diaryl Disulfides from Aryl Halides

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Abstract

A highly porous metal–organic framework Cu3 BTC2 (copper(II)-benzene-1,3,5-tricarboxylate) that known as MOF-199 was synthesized, and characterized by common methods including, FT-IR, XRD, EDX, SEM and then used as an efficient and recyclable catalyst for the direct synthesis of symmetric organic disulfides. A variety of symmetric diaryl disulfides with high chemoselectivity can be obtained by domino reaction of aryl halides (and tosylates) and potassium 5-methyl-1,3,4-oxadiazole-2- thiolate, as the base and sulfur-transfer reagent, in the presence of MOF-199.

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Acknowledgments

We acknowledge the financial support of Ilam University Research Council.

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Authors and Affiliations

  1. Department of Chemistry, Basic of Sciences Faculty, Ilam University, Ilam, PO Box 69315-516, Iran

    Mohammad Soleiman-Beigi & Fariba Mohammadi

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  1. Mohammad Soleiman-Beigi
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  2. Fariba Mohammadi
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Correspondence to Mohammad Soleiman-Beigi.

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Soleiman-Beigi, M., Mohammadi, F. Metal Organic Framework 199- Catalyzed Domino Sulfur-Coupling and Transfer Reactions: The Direct Synthesis of Symmetric Diaryl Disulfides from Aryl Halides. Catal Lett 146, 1497–1504 (2016). https://doi.org/10.1007/s10562-016-1768-8

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  • DOI: https://doi.org/10.1007/s10562-016-1768-8

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