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Tetrahydropyranylation of Alcohols in the Presence of a Slightly Basic, Heterogeneous Titanium Catalyst

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Abstract

4 Å molecular sieve modified with titanium(IV) is an efficient heterogeneous catalyst for the tetrahydropyranylation of alcohols under mild, slightly basic reaction conditions. The catalyst can be reused with good yield after a simple treatment with dichloromethane.

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Acknowledgments

Á. M. is grateful to Chinoin Pharmaceuticals Ltd. for the financial support. The authors express their gratitude to Prof. K. László for the gas adsorption measurements. This work was financially supported by the New Széchenyi Development Plan (TÁMOP-4.2.1/B-09/1/KMR-2010-0002).

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Authors and Affiliations

  1. Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Műegyetem rkp. 3, Budapest, 1111, Hungary

    Ágnes Magyar & Zoltán Hell

  2. Department of Physical Chemistry and Materials Science, Budapest University of Technology and Economics, Budapest, 1521, Hungary

    Balázs Nagy

Authors
  1. Ágnes Magyar
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  2. Balázs Nagy
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  3. Zoltán Hell
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Correspondence to Zoltán Hell.

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Magyar, Á., Nagy, B. & Hell, Z. Tetrahydropyranylation of Alcohols in the Presence of a Slightly Basic, Heterogeneous Titanium Catalyst. Catal Lett 145, 1876–1879 (2015). https://doi.org/10.1007/s10562-015-1590-8

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  • DOI: https://doi.org/10.1007/s10562-015-1590-8

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