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Polyamine Anchored Palladium Catalyst for Suzuki–Miyaura and One-Pot O-Alkylation-Suzuki Reactions

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Abstract

Polymer anchored amine–palladium complexes were screened as catalysts for Suzuki–Miyaura coupling reactions of aryl halides. The robust, recyclable catalyst was effective in this reaction of aryl bromides and iodides. Aryl bromide was found to undergo selective Suzuki–Miyaura reaction with phenyl boronic acid, even in presence of styrene. The catalyst system was further employed for one-pot O-alkylation-Suzuki reaction to prepare alkoxy biaryl systems in good conversions.

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Acknowledgment

We thank Council of Scientific and Industrial Research (CSIR), New Delhi for a research fellowship to KNP.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, M. S. University of Baroda, Vadodara, 390 002, India

    Krupa N. Patel & Ashutosh V. Bedekar

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  1. Krupa N. Patel
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  2. Ashutosh V. Bedekar
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Correspondence to Ashutosh V. Bedekar.

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Patel, K.N., Bedekar, A.V. Polyamine Anchored Palladium Catalyst for Suzuki–Miyaura and One-Pot O-Alkylation-Suzuki Reactions. Catal Lett 145, 1710–1717 (2015). https://doi.org/10.1007/s10562-015-1570-z

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