Abstract
A semitransparent, flexible single-walled carbon nanotube (SWCNT) film was efficiently used in place of evaporated silver as the counter electrode of a poly(3,4-ethylenedioxythiophene) polymer-based solid-state dye solar cell (SSDSC): the solar-to-electrical energy conversion efficiency of the SWCNT-SSDSC was 4.8 % when it was 5.2 % for the Ag-SSDSC. The efficiency difference stemmed from a 0.1-V difference in the open-circuit voltage, whose reason was speculated to be related to the different recombination processes in the two types of SSDSCs.
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References
O’Regan B, Grätzel M (1991) A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature 353:737–740
Asghar MI, Miettunen K, Halme J et al (2010) Review of stability for advanced dye solar cells. Energy Environ Sci 3:418–426
Bach U, Lupo D, Comte P et al (1998) Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies. Nature 395:583–585
Yang L, Xu B, Bi D et al (2013) Initial light soaking treatment enables hole transport material to outperform spiro-OMeTAD in solid-state dye-sensitized solar cells. J Am Chem Soc 135:7378–7385
Saito Y, Kitamura T, Wada Y, Yanagida S (2002) Poly(3,4-ethylenedioxythiophene) as a hole conductor in solid state dye sensitized solar cells. Synth Met 131:185–187
Liu X, Zhang W, Uchida S et al (2010) An efficient organic-dye-sensitized solar cell with in situ polymerized poly(3,4-ethylenedioxythiophene) as a hole-transporting material. Adv Mater 22:150–155
Liu X, Cheng Y, Wang L et al (2012) Light controlled assembling of iodine-free dye-sensitized solar cells with poly(3,4-ethylenedioxythiophene) as a hole conductor reaching 7.1 % efficiency. Phys Chem Chem Phys 14:7098–7103
Kaskela A, Nasibulin AG, Timmermans MY et al (2010) Aerosol-synthesized SWCNT networks with tunable conductivity and transparency by a dry transfer technique. Nano Lett 10:4349–4355
Du Pasquier A, Unalan HE, Kanwal A et al (2005) Conducting and transparent single-wall carbon nanotube electrodes for polymer-fullerene solar cells. Appl Phys Lett 87:1–3
Rowell MW, Topinka MA, McGehee MD et al (2006) Organic solar cells with carbon nanotube network electrodes. Appl Phys Lett 88:233506
Kymakis E, Stratakis E, Koudoumas E (2007) Integration of carbon nanotubes as hole transport electrode in polymer/fullerene bulk heterojunction solar cells. Thin Solid Films 515:8598–8600
Suzuki K, Yamaguchi M, Kumagai M, Yanagida S (2003) Application of carbon nanotubes to counter electrodes of dye-sensitized solar cells. Chem Lett 32:28–29
Trancik JE, Barton SC, Hone J (2008) Transparent and catalytic carbon nanotube films 2008. Nano Lett 8:19–24
Aitola K, Kaskela A, Halme J et al (2010) Single-walled carbon nanotube thin-film counter electrodes for indium tin oxide-free plastic dye solar cells. J Electrochem Soc 157:B1831–B1837
Aitola K, Halme J, Feldt S et al (2013) Highly catalytic carbon nanotube counter electrode on plastic for dyesolar cells utilizing cobalt-based redox mediator. Electrochim Acta 111:206–209
Lee MM, Teuscher J, Miyasaka T et al (2012) Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites. Science 338:643–647
Li Z, Kulkarni SA, Boix PP et al (2014) Laminated carbon nanotube networks for metal electrode-free efficient perovskite solar cells. ACS Nano 8:6797–6804
Habisreutinger SN, Leijtens T, Eperon GE et al (2014) Enhanced hole extraction in perovskite solar cells through carbon nanotubes. J Phys Chem Lett 5:4207–4212
Habisreutinger SN, Leijtens T, Eperon GE et al (2014) Carbon nanotube/polymer composites as a highly stable hole collection layer in perovskite solar cells. Nano Lett 14:5561–5568
Rong Y, Li X, Ku Z et al (2012) Monolithic all-solid-state dye-sensitized solar module based on mesoscopic carbon counter electrodes. Sol Energy Mater Sol Cells 105:148–152
Xu M, Liu G, Li X et al (2013) Efficient monolithic solid-state dye-sensitized solar cell with a low-cost mesoscopic carbon based screen printable counter electrode. Org Electron Phys Mater Appl 14:628–634
Manseki K, Jarernboon W, Youhai Y et al (2011) Solid-state dye-sensitized solar cells fabricated by coupling photoelectrochemically deposited poly(3,4-ethylenedioxythiophene) (PEDOT) with silver-paint on cathode. Chem Commun 47:3120–3122
Gabrielsson E, Ellis H, Feldt S et al (2013) Convergent/divergent synthesis of a linker-varied series of dyes for dye-sensitized solar cells based on the D35 donor. Adv Energy Mater 3:1647–1656
Yang L, Zhang J, Shen Y et al (2013) New approach for preparation of efficient solid-state dye-sensitized solar cells by photoelectrochemical polymerization in aqueous micellar solution. J Phys Chem Lett 4:4026–4031
Acknowledgments
Financial assistance has been provided by the Swedish Energy Agency, the STandUP for Energy program, the Swedish Research Council (VR), the Knut and Alice Wallenberg Foundation, and the Aalto University project MIDECNB-E/FLEXCAP/MOPPI. K.A. acknowledges the Finnish Cultural Foundation and the Swedish Cultural Foundation in Finland for the Säätiöiden Post doc -pooli scholarships. J.Z. gratefully acknowledges the China Scholarship Council for a PhD study fellowship.
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Aitola, K., Zhang, J., Vlachopoulos, N. et al. Carbon nanotube film replacing silver in high-efficiency solid-state dye solar cells employing polymer hole conductor. J Solid State Electrochem 19, 3139–3144 (2015). https://doi.org/10.1007/s10008-015-2937-1
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DOI: https://doi.org/10.1007/s10008-015-2937-1