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Electrochemical resonance under harmonic current perturbations and chaotic potential perturbations

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Abstract

The resonating properties of the electrochemical interface are studied under harmonic perturbations in galvanostatic control and under chaotic perturbations in potentiostatic control. The resonance conditions in galvanostatic control are derived analytically and explored numerically. The theoretical findings are confirmed experimentally for the Ni | 1 M H2SO4 system. The implementation of a Rössler and a Chua chaotic perturbation to an electrochemical resonator is explored numerically. It is shown that the electrochemical resonator acts effectively as a band pass filter thus enhancing the periodicity of the chaotic input.

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Authors and Affiliations

  1. 21 Korai Str., Chalandri, 15233, Athens, Greece

    Dimitris Karaoulanis

  2. Department of Materials Science and Engineering, School of Chemical Engineering, National Technical University of Athens, 15780, Zografou, Athens, Greece

    Pavlos Chryssafidis & Antonis Karantonis

Authors
  1. Dimitris Karaoulanis
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  2. Pavlos Chryssafidis
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  3. Antonis Karantonis
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Correspondence to Antonis Karantonis.

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Karaoulanis, D., Chryssafidis, P. & Karantonis, A. Electrochemical resonance under harmonic current perturbations and chaotic potential perturbations. J Solid State Electrochem 19, 3277–3286 (2015). https://doi.org/10.1007/s10008-015-2794-y

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  • DOI: https://doi.org/10.1007/s10008-015-2794-y

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