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Hydrothermal synthesis, structure, porosity, and luminescent properties of 3D coordination polymer of holmium with 1,4-phenylenediacetic acid [Ho2(PDA)3(H2O)] n ·2nH2O

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Abstract

Coordination polymer formulated as [Ho2(PDA)3(H2O)] n ·2nH2O having three-dimensional network was hydrothermally synthesized (H2PDA is 1,4-phenylenediacetic acid). The polymer crystallizes in the monoclinic space group P 21/c, unit cell parameters: a = 21.7025(2) Ǻ, b = 10.03560(10) Ǻ, c = 14.03430(10) Ǻ, β = 91.7110(10)° (Z = 4), and exhibits a three-dimensional porous framework. The polymer contains two and four crystallographically independent holmium(III) ions and 1,4-phenylenediacetate anions, respectively. The two types of Ho(III) ions adopt an extended zigzag orientation and act as nodes alternately, while three different carboxylate (COO−) groups bridge two adjacent Ho(III) ions. The coordination polymer chains are reinforced by well-directed hydrogen bonds involving guest water molecules. The polymer is mesoporous in nature with average pore size diameter of 5.6 nm. The polymer exhibits intense emission bands in visible region upon excitation at 390 nm. The polymer is thermally robust and undergoes thermal decomposition in well-defined steps.

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Acknowledgments

We gratefully acknowledge financial support from DRDO, New Delhi. We thank Sophisticated Analytical Instrumentation Facility, CIL and UCIM Panjab University for FTIR study. Authors are grateful to Dr. Shaikh M. Mobin, Incharge, Sophisticated Instrumentation Centre (SIC), Indian Institute of Technology Indore (IITI), M. P. India for single-crystal X-ray diffraction study. The authors thank Dr. Vinay Kumar, Assistant Professor, School of Physics, Shri Mata Vaishno Devi University (SMVDU) for photoluminescence studies.

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  1. Post-Graduate Department of Chemistry, University of Jammu, Jammu Tawi, Jammu, 180 006, India

    Mohd Yawer, Swati Sharma, Mukaddus Kariem, Haq N. Sheikh & Mohita Sharma

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  1. Mohd Yawer
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  2. Swati Sharma
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  3. Mukaddus Kariem
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  4. Haq N. Sheikh
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Correspondence to Haq N. Sheikh.

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Yawer, M., Sharma, S., Kariem, M. et al. Hydrothermal synthesis, structure, porosity, and luminescent properties of 3D coordination polymer of holmium with 1,4-phenylenediacetic acid [Ho2(PDA)3(H2O)] n ·2nH2O. Monatsh Chem 146, 47–55 (2015). https://doi.org/10.1007/s00706-014-1289-3

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