Abstract
The layered mafic–ultramafic rocks in the Sierras de San Luis, Argentina (Las Águilas, Las Higueras and Virorco), constitute a 3–5-km-wide belt that extends over 100 km from NE to SW. They carry a sulphide mineralization consisting of pyrrhotite, pentlandite and chalcopyrite, in veins and as disseminated to massive ore. Disseminated spinels are frequently associated with the sulphide minerals as well as platinum group minerals. A strong correlation between S, Ni, Co, Cu, Cr, Pt and Pd indicates the presence of one to three levels of mineralization within the ultramafic units. The maximum concentration of these elements coincides with the units containing platinum group minerals (PGM) and spinel group minerals. This clear relationship constitutes a good prospecting guide in the search for layers with high-grade ore, probably associated with deeper stratigraphic levels where ultramafic rocks are dominant. The bulk rock chemistry and concentrations of metals and platinum group elements as well as textural evidence suggest that the parental magma was mafic with tholeiitic affinities and MgO rich. The Las Águilas layered mafic–ultramafic body and the remaining bodies in the area bear similar characteristics to well-known stratified complexes developed in extensional tectonic regimes, as it is the case of Jinchuan (China), Kabanga (Tanzania) and Fiambala (Argentina).
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References
Andersen JC (2002) IGCP Project 427 field meeting and excursion on the skaergaard intrusion. Conference reports Episodes 25:38–40
Barnes SJ, Naldrett AJ, Gorton MP (1985) The origin of the fractionation of platinum-group elements in terrestrial magmas. Chem Geol 53:303–323
Barnes SJ, Boyd R, Korneliussen A, Nilsson LP, Often M, Pedersen RB, Robins B (1987) The use of mantle normalization and metal ratios in discriminating between the effects of partial melting, crystal fractionation and sulfide segregation on platinum-group elements, gold, nickel and copper: examples from norway. In: Prichard HM, Potts PJ, Bowles JFW, Cribb S (eds) Geo-platinum 87. Elsevier, London, pp 113–134
Barnes SJ, Couture JF, Sawyer EW, Couchaib C (1993) Nickel–Copper occurrences in the belleterre-angliers belt of the pontiac subprovince and the use of Cu-Pd ratios in interpreting platinum group element distributions. Econ Geol 88:1402–1418
Barnes SJ, Makovicky E, Karup-Moller S, Makovicky M, Rose-Hansen J (1997) Partition coefficients for Ni, Cu, Pd, Pt, Rh and Ir between monosulphide solid solution and sulphide liquid and the implications for the formation of compositionally zoned Ni-Cu sulphide bodies by fractional crystallization of sulphide liquid. Can J Ear Sci 34:366–374
Brogioni N (1994) Petrología de la Faja de Rocas Máficas y Ultramáficas de la Sierra de San Luis, Argentina. 7º Cong Geol Chileno Actas 2:967–971
Brogioni N (2001a) Geología de los cuerpos Virorco y El Fierro, faja máfica-ultramáfica del borde oriental de la sierra de San Luis. Revista de la Asociación Geológica Argentina 56:281–292
Brogioni N (2001b) Petrología de los cuerpos Virorco y El Fierro, faja máfica-ultramáfica del borde oriental de la sierra de San Luis. Revista de la Asociación Geológica Argentina 56:535–547
Campbell IH, Naldrett AJ (1979) The influence of silicate: sulfide ratios on the geochemistry of magmatic sulfides. Econ Geol 74:1503–1505
Candia MAF, Gaspar JC (1997) Chromian spinels in metamorphosed ultramafic rocks from mangabal I and II complexes, Goiás, Brasil. Miner Petrol 60:27–40
Chai G, Naldrett AJ (1992a) Characteristics of Ni-Cu-PGE Mineralization and Genesis of the Jinchuan Deposit, Northwest China. Econ Geol 87:1475–1495
Chai G, Naldrett A (1992b) The jinchuan ultramafic intrusion: cumulate of a high-Mg basaltic magma. J Petrol 33:277–303
Cox KG, Bell JD, Pankhurst RJ (1979) The interpretation of igneous rocks. Feorge Allen and Unwin, London, p 450
DeBari S (1994) Petrogenesis of th Fiambalá Gabbroic Intrusion, Northwestern Argentina, a deep crustal syntectonic pluton in a continental magmatic arc. J Petrol 35:679–713
Delpino SH, Bjerg EA, Ferracutti GR, Mogessie A (2007) Mylonitization and related geological processes in the Sierra de San Luis central block, Argentina: implications for the tectono-metamorphic evolution of the region. J S Am Ear Sci 23:147–175
Evans DM, Boadi I, Byemelwa L, Gilligan J, Kabete J, Marcet P (2000) Kabanga magmatic nickel sulphide deposits, Tanzania: morphology and geochemistry of associated intrusions. J Afr Ear Sci 30:651–674
Felfernig A, Mogessie A, Hauzenberger ChA, Hoinkes G, Bjerg EA, Kostadinoff J, Delpino S, Dimieri L (1997) Petrology and mineralization of the Las Águilas ultramafic body, San Luis province, Argentina. Terra Nova 9:532–533
Ferracutti G, Bjerg EA (2002) Platinoideos en el yacimiento Las Águilas, San Luis, Argentina. VI Cong Mineral Metalog (Eds.: M. K. De Brodtkorb, M. Koukharsky y P. Leal). 135–138. Buenos Aires
Ferracutti G, Bjerg EA, Mogessie A (2004) Cromo espinelos de Las Águilas, provincia de San Luis, como indicadores tectónicos”. 7º Cong Miner Metalog 321–326. Río Cuarto, Córdoba
Ferracutti G, Mogessie A, Bjerg EA (2006a) Chrome spinels from the Las Águilas mafic-ultramafic intrusion, San Luis province, Argentina. Neues Jahrbuch für Mineralogie 183:63–77
Ferracutti G, Bjerg E, Mogessie A, (2006b) Segregación temprana de sulfuros en la extracción de elementos del grupo del platino de las rocas máficas-ultramáficas de Las Águilas y alrededores, San Luis, Argentina. 8º Cong Miner Metalog. 347–350, Buenos Aires
Ferracutti G, Bjerg E, Mogessie A (2007) Metales base y preciosos en Las Águilas, Argentina: génesis y evolución. Revista de la Asociación Geológica Argentina 62:434–446
Gervilla F, Sabalúa J, Carrillo R, Hach-Alí PF, Acevedo RD (1993) Mineralogy and mineral chemestry of the Las Águilas Ni-Cu deposit (province of San Luis, Argentina). In: Torres-Ruiz J, Gervilla F (eds) Fenoll Hach-Alí P. Current research in geology applied to ore deposits. Universidad de Granada, España, pp 461–464
Gervilla F, Sanchez-Anguita A, Acevedo RD, Hach-Alí PF, Paniagua A (1997) Platinum-group element sulpharsenides and Pd bismuthotellurides in the metamorphosed Ni-Cu deposit at Las Águilas (province of San Luis, Argentina). Miner Mag 61:861–877
Godard M, Jousselin D, Bodinier JL (2000) Relationships between geochemistry and structure beneath a palaeo-spreading centre: a study of the mantle section in the Oman ophiolite. Ear Plan Sci Lett 180:133–148
ChA Hauzenberger, Mogessie A, Hoinkes G, Bjerg EA, Kostadinoff J, Delpino S, Dimieri L (1997) Granulite facies metamorphism of the basament of the Sierras de San Luis, Argentina-An Anticlockwise P-T path. Terra Nova 9:678
Hauzenberger ChA, Mogessie A, Hoinkes G, Bjerg EA, Kostadinoff J, Delpino S, Dimieri L (1997) Platinum group minerals in the basic to ultrabasic complex of the Sierras de San Luis, Argentine. In: Papunen H (ed) Mineral Deposits: Research and Exploration-Where Do They Meet? A. A BALKEMA Publishers, Brookfield, VT, pp 439–442
Irvine TN (1982) Terminology for layered Intrusions. J Petrol 23:127–162
Kilmurray JO, Villar LM (1981) El basamento de la Sierra de San Luis y su petrología. In: Yrigoyen M (ed) Geología y recursos naturales de la provincia de San Luis, Relatorio del 8º Cong Geol Arg, San Luis, p 33–54
Mahéo G, Bertrand H, Guillot S, Villa I, Keller F, Capiez P (2004) The South Ladakh ophiolites (NW Himalaya, India): an intra-oceanic tholeiitic arc origin with implication for the closure of the Neo-Tethys. Chem Geol 203:273–303
Malvicini L, Brogioni N (1992) El depósito hidrotermal de Ni, Cu y metales del “Grupo del Platino”, Las Águilas Este, Provincia de San Luis. 4º Cong Nac y 1º Cong Latinoam Geol Econ, Actas:93–102
Malvicini L, Brogioni N (1993) Petrología y génesis del yacimiento de sulfuros de Ni, Cu y platinoideos Las Águilas Este, Provincia de San Luis. Revista de la Asociación Geológica Argentina 48:3–20
Malvicini L, Brogioni N (1996) Las Águilas Este Deposit: shear zone hosted hydrothermal Cu-Ni sulfide and platinum-group elements mineralization in the mafic-ultramafic complex of San Luis Range, Argentina. Geology and Ore Deposits of the American Cordillera, Symposium Proceedings, pp 1475–1485
McBirney AR, Noyes RM (1979) Crystallization and Layering of the Skaergaard Intrusion. J Petrol 20:487–554
Mogessie A, Hoinkes G, Stumpfl EF, Bjerg EA, Kostadinoff J (1994) The petrology and mineralization of the basement and associated mafic-ultramafic rocks, San Luis province, Argentina. Mitteilungen der Österreichischen Mineralogischen Gesellschaft 139:347–348
Mogessie A, Hoinkes G, Stumpfl EF, Bjerg EA, Kostadinoff J (1995) Occurrence of platinum group minerals in the las Águilas ultramafic unit within a granulite facies basament, San Luis province, central Argentina. In: Pasava J, Kribek B, Zak K (eds) Mineral Deposits: from Their Origin to Their Environmental Impact. A.A Balkema Publishers, Brookfield, VT, pp 897–900
Mogessie A, Hauzenberger ChA, Hoinkes G, Felfernig A, Stumpfl EF, Bjerg EA, Kostadinoff J (2000) Genesis of platinum-group minerals in the Las Águilas mafic-ultramafic rocks, San Luis Province, Argentina: textural, chemical and mineralogical evidence. Min Petrol 68:85–114
Naldrett AJ, Duke JM (1980) Platinum metals in magmatic sulfide ores. Science 208:1417–1428
Naldrett AJ, Von Gruenevaldt G (1989) Association of platinum group elements with chromite in layered intrusions and ophiolite complexes. Econ Geol 84:180–187
Pearce JA (1983) Role of the cub-continental lithosphere in magma genesis at active continental margins. In: Hawkesworth CJ, Norry MJ (eds) Continental basalts and mantle xenoliths. Shiva Publications, Nantwich, pp 230–249
Proenza JA, Zaccarini F, Escayola M, Cábana C, Schalamuk A, Garuti G (2008) Chromite composition and platinum-group minerals in chromitites of the western ophiolitic belt from Pampean Ranges of Córdoba, Argentine. Ore Geol Rev 33:32–48
Rajamani V, Naldrett AJ (1978) Partitioning of Fe, Co, Ni and Cu between sulfide liquid and basaltic melts and the composition of Ni–Cu sulfide deposits. Econ Geol 73:82–93
Ramos V (1988) Late proterozoic-early paleozoic history of South America-a collisional history. Episodes 11:168–174
Ramos VA, Escayola M, Mutti D, Vujovich G (2000) Proterozoic-early ophiolites in the Andean basament of southern South America. In: Y. Diley, E. M. Moores, D. Elthon and A. Nicolas (eds.) Ophiolites and Oceanic Crust: New insights from field studies and ocean drilling program. Geol Soc Am, Sp Paper 349:331–349
Rapela CW, Pankhurst RJ, Casquet C, Baldo E, Saavedra J, Galindo C (1998) Early evolution of the Proto-Andean margin of South America. Geol 26:707–710
Roeder P, Emslei R (1970) Olivine-liquid equilibrium. Contrib Miner Petrol 29:275–289
Sabalúa J (1986) Yacimiento Las Águilas. Mineralización Ni–Cu–Co, Departamento Pringles, Provincia de San Luis, República Argentina. Informe final, DGFM, Subdirección de Desarrollo Minero, Centro de Exploración Geológico Minero-Mendoza. p 32
Sabalúa J, Chabert M, Santamaria G (1981) Mineralización de sulfuros de hierro, cobre y niquel, en el cuerpo básico de Las Águilas, Provincia de San Luis. 8º Cong Geol Arg Actas 4:497–507
Sato AM, González PD, Sato K (2002) First indication of Mesoproterozoic age from Western Basement of Sierra de San Luis, Argentina. 3 Simp Sudam Geol Isot. Pucon-Chile. In CD-ROM
Saunders AD, Tarney J (1979) The geochemistry of basalts from back-arc spreading centre in the E. Scotia Sea. Geochim et Cosmochim Acta 43:555–572
Shelley D (1993) Igneous and metamorphic rocks under the microscope: classification, textures, microstructures and mineral preferred - orientations. Chapman & Hall, London, p 445
Sims J, Stuart Smith P, Lyons P, Skirrow R (1997) Informe Geológico y Metalogénico de las Sierras de San Luis y Comechingones, provincias de San Luis y Córdoba. Geológico Minero Argentino, Anales 28:1–148
Sims JP, Ireland TR, Camacho A, Lyons P, Pieters PE, Skirrow RG, Stuart-Smith PG, Miró R (1998) U-Pb, Th-Pb and Ar–Ar geochronology from the southern Sierras Pampeanas, Argentina. In: Pankhurst R, Rapela C (eds) Implications for the Paleozoic tectonic evolution of the western Gondwana margin, implications for the Proto-Andean margin of Gondwana. Geol Soc Lon, Sp Publ 142:259–281
Sun S, McDonough W (1989) Chemical and isotopic systematic of oceanic basalts: implications for mantle composition and processes. In: Saunders AD, Norry MJ (eds) Magmatism in ocean basin. Geol Soc Lon, Sp Publ 42:313–345
Taylor SR, McLennan SM (1985) The Continental Crust: Its composition and evolution. Blackwell. Oxford, p 312
Theriault RD, Barnes SJ, Severson MJ (2000) Origin of Cu-Ni-PGE Sulfide mineralization in the partridge river intrusion, Duluth Complex, Minnesota. Econ Geol 95:929–943
Villar ML (1975) Las fajas y otras manifestaciones ultrabásicas de la República Argentina y su significado metalogenético. 2º Cong. Iberoam. Geol. Econ Actas 3:135–156
Von Gosen W, Loske W, Prozzi C (2002) New isotopic dating of intrusive rocks in the Sierra de San Luis (Argentina): implications for the geodynamic history of the Eastern Sierras Pampeanas. J S Am Ear Sci 15:237–250
Winter J (2001) An Introduction to Igneous and Metamorphic Petrology. Prentice Hall, pp 699
Zientek ML, Likhachev AP, Kunilov VE, Barnes SJ, Meier AL, Carlson RR, Briggs PH, Fries TL, Adrian BM (1994) Cumulus processes and the composition of magmatic ore deposits: examples from the Talnakh district. Ontario Geolo Surv 5:373–392
Acknowledgments
This work was financed with projects 24/H085—Secretaria General de Ciencia y Tecnología de la Universidad Nacional del Sur (SGCyT-UNS), and PIP112-200801-02306—Consejo Nacional de Investigaciones Científicas y Tecnológicas (CONICET), Argentina, granted to EAB and project PICT 2008-0025—Agencia Nacional de Promoción Científica y Tecnológica granted to GF. The authors thank Dr. Bernhardt Saini-Eidukat, Dr. Frank Melcher and an anonymous reviewer for their constructive comments and suggestions.
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Ferracutti, G., Bjerg, E. & Mogessie, A. Petrology, geochemistry and mineralization of the Las Águilas and Virorco mafic–ultramafic bodies, San Luis Province, Argentina. Int J Earth Sci (Geol Rundsch) 102, 701–720 (2013). https://doi.org/10.1007/s00531-012-0834-8
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DOI: https://doi.org/10.1007/s00531-012-0834-8