Abstract
Multiphase waterborne polymer particles provide advantages in more demanding applications, and their performance depends on particle morphology. Currently, no dynamic model for the prediction of the development of the morphology of multiphase latex particles is available. In this work, a model was developed for the prediction of the dynamic development of the morphology of multiphase waterborne systems, such as polymer–polymer and polymer–polymer–inorganic hybrids.
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References
Asua JM (ed) (1997) Polymeric dispersions: principles and applications. Kluwer Academic, Dordrecht
Lovell PA, El-Aasser MS (eds) (1997) Emulsion polymerization and emulsion polymers. Wiley, Chichester
Urban D, Takamura K (2002) Polymer dispersions and their industrial applications. Wiley-VCH, Weinheim
Schuler B, Baumstark R, Kirsch S, Pfau A, Sandor M, Zosel A (2000) Structure and properties of multiphase particles and their impact on the performance of architectural coatings. Prog Org Coat 40:139–150
Sato F, Tateyama M (1988) Impact resistant methacrylic resin composition. US 47300023
Tsavalas JG, Schork FJ, Landfester K (2004) Particle morphology development in hybrid miniemulsion polymerization. J Coat Technol Res 1:53–63
Goikoetxea M, Minari RJ, Beristain I, Paulis M, Barandiaran MJ, Asua JM (2009) Polymerization kinetics and microstructure of waterborne acrylic/alkyd nanocomposites synthesized by miniemulsion. J Polym Sci Part A Polym Chem 47:4871–4885
Li CY, Chiu WY, Don TM (2007) Morphology of PU/PMMA hybrid particles from miniemulsion polymerization: thermodynamic considerations. J Polym Sci Part A Polym Chem 45:3359–3369
Kawahara H, Goto T, Ohnishi K, Ogura H, Kage H, Matsuno Y (2001) Preparation of epoxy resin/acrylic composite latexes by miniemulsion polymerization method. J Appl Polym Sci 81:128–133
Bourgeat-Lami E (2002) Organic–inorganic nanostructured colloids. J Nanosci Nanotechnol 2:1–24
Negrete-Herrera N, Putaux JL, Laurent D, Bourgeat-Lami E (2006) Polymer/laponite composite colloids through emulsion polymerization: influence of the clay modification level on particle morphology. Macromolecules 39:9177–9184
Cheng J, Chen M, Zhou S, Wu L (2006) Preparation of SiO2/PMMA composite particles via conventional emulsion polymerization. J Polym Sci Part A Polym Chem 44:3807–3816
Diaconu G, Asua JM, Paulis M, Leiza JR (2007) High-solids content waterborne polymer–clay nanocomposites. Macromol Symp 259:305–317
Diaconu G, Micusik M, Bonnefond A, Paulis M, Leiza JR (2009) Macroinitiator and macromonomer modified montmorillonite for the synthesis of acrylic/MMT nanocomposite latexes. Macromolecules 42:3316–3325
Sundberg DC, Durant YG (2003) Latex particle morphology, fundamental aspects: a review. Polym React Eng 11:379–432
Torza S, Mason SG (1970) Three-phase interactions in shear and electrical fields. J Colloid Interface Sci 33:67–83
Winzor CL, Sundberg DC (1992) Conversion dependent morphology predictions for composite emulsion polymers: 1. Synthetic lattices. Polymer 33:3797–3810
Chen YC, Dimonie V, El-Aasser MS (1991) Effect of interfacial phenomena on the development of particle morphology in a polymer latex system. Macromolecules 24:3779–3787
González-Ortiz LJ, Asua JM (1995) Development of particle morphology in emulsion polymerization. 1. Cluster dynamics. Macromolecules 28:3135–3145
Shen S, El-Aasser MS, Dimonie VL, Vanderhoff JW, Sudol ED (1991) Preparation and morphological characterization of microscopic composite particles. J Polym Sci Part A Polym Chem 29:857–867
Kirsch S, Pfau A, Stubbs J, Sundberg DC (2001) Control of particle morphology and film structures of carboxylated poly(n butylacrylate/poly(methyl methacrylate) composite latex particles. Colloid Surf A Phys Eng Asp 183–185:725–737
Colombini D, Ljungberg N, Hassander H, Karlsson O (2005) The effect of polymerisation route on the amount of interphase in structured latex particles and their corresponding films. Polymer 46:1295–1308
Sundberg E, Sundberg DC (1993) Morphology development for three component emulsion polymers—theory and experiments. J Appl Polym Sci 47:1277–1294
Reyes Y, Asua JM (2010) Modeling multiphase latex particle equilibrium morphology. J Polym Sci Part A Polym Chem 48:2579–2583
Stubbs J, Durant YG, Sundberg DC (2003) Polymer phase separation in composite latex particles. 1. Considerations for the nucleation and growth mechanism. C R Chem 6:1217–1232
Stubbs J, Karlsson O, Jönsson JE, Sundberg E, Durant Y, Sundberg DC (1999) Non-equilibrium particle morphology development in seeded emulsion polymerization. 1: penetration of monomer and radicals as a function of monomer feed rate during second stage polymerization. Colloid Surf A Phys Eng Aspects 153:255–270
Stubbs J, Carrier R, Sundberg DC (2008) Monte Carlo simulation of emulsion polymerization kinetics and the evolution of latex particle morphology and polymer chain architecture. Macromol Theory Simul 17:147–162
Lee CF (2005) Effects of surfactants on the morphology of composite polymer particles produced by two-stage seeded emulsion polymerization. J Polym Sci Part A Polym Chem 43:2224–2236
Tillier DL, Meuldijk J, Höhne GWH, Frederik PM, Regev O, Koning CO (2005) About morphology in ethylene–propylene(-diene) copolymers-based latexes. Polymer 46:7094–7108
Stubbs J, Sundberg DC (2008) The dynamics of morphology development in multiphase latex particles. Prog Org Coat 61:156–165
González-Ortiz LJ, Asua JM (1996) Development of particle morphology in emulsion polymerization. 2. Cluster dynamics in reacting systems. Macromolecules 29:383–389
González-Ortiz LJ, Asua JM (1996) Development of particle morphology in emulsion polymerization. 2. Cluster nucleation and dynamics in polymerizing systems. Macromolecules 29:4520–4527
Akhmatskaya E, Asua JM (2012) Dynamic modeling of the morphology of latex particles with in situ formation of graft copolymer. J Polym Sci Part A Polym Chem 50:1383–1393
Landfester K, Rothe R, Antonietti M (2002) Convenient synthesis of fluorinated latexes and core–shell structures by miniemulsion polymerization. Macromolecules 35:1658–1662
Li M, Daniels ES, Dimonie V, Sudol ED, El-Aasser MS (2005) Preparation of polyurethane/acrylic hybrid nanoparticles via a miniemulsion polymerization process. Macromolecules 38:4183–4192
Boutti S, Bourgeat-Lami E, Zydowicz N (2005) Silica/polyamide nanocomposite synthesis via an original double emulsification process in miniemulsion. Macromol Rapid Commun 26:1860–1865
Rodriguez R, de las Heras Alarcon C, Ekanayake P, McDonald PJ, Keddie JL, Barandiaran MJ, Asua JM (2008) Correlation of silicone incorporation with the hydrophobic and thermal properties of hybrid silicone-acrylic coatings. Macromolecules 41:8537–8546
Wang T, de las Heras Alarcon C, Goikoetxea M, Beristain I, Paulis M, Barandiaran MJ, Asua JM, Keddie JL (2010) Crosslinked network development in compatibilized alkyd/acrylic hybrid latex films for the creation of hard coatings. Langmuir 26:14323–14333
Jönsson JEL, Hassander H, Törnell B (1994) Polymerization conditions and the development of a core–shell morphology in PMMA/PS latex particles. 1. Influence of initiator properties and mode of monomer addition. Macromolecules 27:1932–1937
Rajatapiti P, Dimonie VL, El-Aasser MS (1995) In-situ synthesis of PBA-graft-PMMA copolymers to be used as compatibilizing agents in PBA/PMMA composite latex particles via the macromonomer method. J Macromol Sci Pure Appl Chem A32:1445–1460
Herrera V, Pirri R, Leiza JR, Asua JM (2006) Effect of in-situ formation of block copolymers on the latex particle morphology. Macromolecules 39:6969–6974
Bourgeat-Lami E, Espiard P, Guyot A, Gauthier C, David L, Vigier G (1996) Emulsion polymerization in the presence of colloidal silica particles. Angew Makromol Chem 242:105–122
Erdem B, Sudol ED, Dimonie VL, El-Aasser MS (2000) Encapsulation of inorganic particles via miniemulsion polymerization(I). Dispersion of titanium dioxide particles in organic media using OLOA 370 as stabilizer. J Polym Sci Part A Polym Chem 38:4419–4430
Erdem B, Sudol ED, Dimonie VL, El-Aasser MS (2000) Encapsulation of inorganic particles via miniemulsion polymerization(II). Preparation and characterization of styrene miniemulsion droplets containing TiO2 particles. J Polym Sci Part A Polym Chem 38:4431–4440
Erdem B, Sudol ED, Dimonie VL, El-Aasser MS (2000) Encapsulation of inorganic particles via miniemulsion polymerization(III). Characterization of encapsulation. J Polym Sci Part A Polym Chem 38:4441–4450
Pattamasattayasonthi N, Chaochanchaikul K, Rosarpitak V, Sombatsompop N (2011) Effects of UV weathering and a CeO2-based coating layer on the mechanical and structural changes of wood/PVC composites. J Vinyl Addit Technol 17:9–16
Binks BP (2002) Particles as surfactants—similarities and differences. Curr Opin Colloid Interf Sci 7:21–41
Cauvin S, Colver PJ, Bon SAF (2005) Pickering stabilized miniemulsion polymerization: preparation of clay armored latexes. Macromolecules 38:7887–7889
Galian RE, Guardia M (2009) The use of quantum dots in organic chemistry. Trends Anal Chem 394:47–59
Mattoussi H, Radzilowski LH, Dabbousi BO, Thomas EL, Bawendi MG, Rubner MF (1998) Electroluminescence from heterostructures of poly(phenylene vinylene) and inorganic CdSe nanocrystals. J Appl Phys 83:7965–7974
Gu I, Fromer NA, Geier ML, Alivisatos AP (2005) Air-stable all-inorganic nanocrystal solar cells processed from solution. Science 310:462–465
Woggon U, Wannemacher R, Artemyev MV, Moller B, Le Thomas N, Anikeyev V, Schöps O (2003) Dot-in-a-dot: electronic and photonic confinement in all three dimensions. Appl Phys B 77:469–484
Bruchez M, Moronne M, Gin P, Weiss S, Alivisatos AP (1998) Semiconductor nanocrystals as fluorescent biological labels. Science 281:2013–2016
Manea M, Chemtob A, Paulis M, de la Cal JC, Barandiaran MJ, Asua JM (2008) Miniemulsification in high pressure homogenizers. AIChEJ 54:289–297
Lopez A, Chemtob A, Milton JL, Manea M, Paulis M, Barandiaran MJ, Theisinger S, Landfester K, Hergeth WD, Udagama R, McKenna T, Simal F, Asua JM (2008) Miniemulsification of monomer-resin hybrid systems. Ind Eng Chem Res 47:6289–6297
Alduncin JA, Asua JM (1994) Molecular-weight distributions in the miniemulsion polymerization of styrene initiated by oil-soluble initiators. Polymer 35:3758–3765
Chern CS, Poehlein GW (1987) Polymerization in nonuniform latex particles: distribution of free radicals. J Polym Sci Part Polym Chem Ed 25:617–635
de la Cal JC, Urzay R, Zamora A, Forcada J, Asua JM (1990) Simulation of the latex particle morphology. J Polym Sci Part A Polym Chem 28:1011–1031
Binder K (1982) Monte Carlo calculation of the surface tension for two- and three-dimensional lattice-gas models. Phys Rev A 25:1699–1709
Salomons E, Mareschal M (1991) Surface tension, adsorption and surface entropy of liquid–vapour by atomistic simulation. J Phys Condens Matter 3:3645–3661
Singh JK, Kofke DA, Errington JR (2003) Surface tension and vapor-liquid phase coexistence of the square-well fluid. J Chem Phys 119:3405–3412
Gloor GJ, Jackson G, Blas FJ, de Miguel E (2005) Test-area simulation method for the direct determination of the interfacial tension of systems with continuous or discontinuous potentials. J Chem Phys 123:134703
van Krevelen DW (1992) Properties of polymers. Their correlation with chemical structure, their numerical estimation and prediction from additive group contributions, 3rd edn. Elsevier, Amsterdam, p 516
Oh JK, Yang J, Tomba JP, Rademacher J, Farwaha R, Winnik MA (2003) Molar mass effect on the rate of polymer diffusion in poly(vinyl acetate-co-butyl acrylate) latex films. Macromolecules 36:8836–8845
Wu J, Tomba JP, Winnik MA, Farwaha R, Rademacher J (2004) Effect of gel content on polymer diffusion in poly(vinyl acetate-co-dibutyl maleate) latex films. Macromolecules 37:4247–4253
Farinha JPS, Wu J, Winnik MA, Farwaha R, Rademacher J (2005) Polymer diffusion in gel-containing poly(vinyl acetate-co-dibutyl maleate) latex films. Macromolecules 38:4393–4402
Tomba JP, Portinha D, Schroeder WF, Winnik MA, Lau W (2009) Polymer diffusion in high-M/low-M hard–soft latex blends. Colloid Polym Sci 287:367–378
Hess B, Kutzner C, van der Spoel D, Lindahl E (2008) GROMACS 4: algorithms for highly efficient, load-balanced, and scalable molecular simulation. J Chem Theory Comput 4:435–447
Humphrey W, Dalke A, Schulten K (1996) VMD: visual molecular dynamics. J Mol Graph 14:33–38
Acknowledgments
The financial support from the Diputacion Foral de Gipuzkoa, Basque Government (GV IT373-10 and Saiotek 2010S-PE 10UN25) and Ministerio de Ciencia y Tecnologia (CTQ 2011-25572) as well as the use of the computing facilities of I2BASQUE are gratefully acknowledged.
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Akhmatskaya, E., Asua, J.M. Dynamic modeling of the morphology of multiphase waterborne polymer particles. Colloid Polym Sci 291, 87–98 (2013). https://doi.org/10.1007/s00396-012-2740-9
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DOI: https://doi.org/10.1007/s00396-012-2740-9