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Properties of nanoparticles generated during femtosecond laser machining in air and water

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Abstract

Femtosecond laser ablation is used to generate nanoparticle aerosols and colloids from solid targets of various materials (Ti, Ag, Au, Co, etc.) in air and water ambience. We determine the influence of different laser parameters (pulse energy, pulse overlap) and properties of media (air, airbrush, water) on the rate of production and size distribution of the laser-generated nanoparticles. It is shown that the pulse overlap and laser fluence are the parameters determining the nanoparticle size. At optimum conditions the nanoparticle productivity can be increased by 150–300%. The generation of multimaterial nanoparticle dispersions is demonstrated. Being free of toxic impurities, the laser-produced nanoparticles may be promising for biomedical applications.

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References

  1. A. Ebenau, in Nanotechnology in Chemistry – Experience Meets Vision, Mannheim, 28–29 October 2002 (BASF Future Business GmbH, Ludwigshafen, 2002), press release

  2. P.T. Anastas, J.C. Warner, Green Chemistry: Theory and Practice (Oxford University Press, New York, 1998)

    Google Scholar 

  3. T.-H. Her, R.J. Finlay, C. Wu, S. Deliwala, E. Mazur, Appl. Phys. Lett. 73, 1673 (1998)

    Article  ADS  Google Scholar 

  4. C.H. Crouch, J.E. Carey, J.M. Warrender, M.J. Aziz, E. Mazur, F.Y. Genin, Appl. Phys. Lett. 84, 1850 (2004)

    Article  ADS  Google Scholar 

  5. A.J. Pedraza, J.D. Fowlkes, D.H. Lowndes, Appl. Phys. Lett. 74, 2322 (1999)

    Article  ADS  Google Scholar 

  6. F. Costache, M. Henyk, J. Reif, Appl. Surf. Sci. 186, 352 (2002)

    Article  Google Scholar 

  7. F. Korte, J. Serbin, J. Koch, A. Egbert, C. Fallnich, A. Ostendorf, B.N. Chichkov, Appl. Phys. A 77, 229 (2003)

    ADS  Google Scholar 

  8. F. Korte, J. Koch, B.N. Chichkov, Appl. Phys. A 79, 879 (2004)

    Article  ADS  Google Scholar 

  9. J. Koch, F. Korte, T. Bauer, C. Fallnich, A. Ostendorf, B.N. Chichkov, Appl. Phys. A 81, 325 (2005)

    Article  ADS  Google Scholar 

  10. A.V. Kabashin, M. Meunier, Appl. Phys. Lett. 82, 1619 (2003)

    Article  ADS  Google Scholar 

  11. A.V. Kabashin, M. Meunier, Mater. Sci. Eng. B 101, 60 (2003)

    Article  Google Scholar 

  12. D.-Q. Yang, A.V. Kabashin, V.-G. Pilon-Marien, E. Sacher, M. Meunier, J. Appl. Phys. 95, 5722 (2004)

    Article  ADS  Google Scholar 

  13. A.V. Kabashin, M. Meunier, in Recent Advances in Laser Processing of Materials, ed. by J. Perriere, E. Millon, E. Fogarassi (Elsevier, Amsterdam, 2006), pp. 1–36

  14. I.A. Movtchan, R.W. Dreyfus, W. Marine, M. Sentis, M. Autric, G. Le Lay, N. Merk, Thin Solid Films 255, 286 (1995)

    Article  Google Scholar 

  15. Y. Yamada, T. Orii, I. Umezu, S. Takeyama, T. Yoshida, Japan. J. Appl. Phys. 35, 1361 (1996)

    Article  Google Scholar 

  16. T. Makimura, Y. Kunii, K. Murakami, Japan. J. Appl. Phys. 35, 4780 (1996)

    Article  Google Scholar 

  17. A.V. Kabashin, J.-P. Sylvestre, S. Patskovsky, M. Meunier, J. Appl. Phys. 91, 3248 (2002)

    Article  ADS  Google Scholar 

  18. A. Fojtik, A. Henglein, Ber. Bunsenges. Phys. Chem. 97, 252 (1993)

    Google Scholar 

  19. J. Nedderson, G. Chumanov, T.M. Cotton, Appl. Spectrosc. 47, 1959 (1993)

    Article  ADS  Google Scholar 

  20. F. Mafuné, J.-Y. Kohno, Y. Takeda, T. Kondow, H. Sawabe, J. Phys. Chem. B 104, 9111 (2000)

    Article  Google Scholar 

  21. F. Mafuné, J.-Y. Kohno, Y. Takeda, T. Kondow, J. Phys. Chem. B 105, 5114 (2001)

    Article  Google Scholar 

  22. Y.-H. Chen, C.S. Yeh, Colloid Surf. A 197, 133 (2002)

    Article  Google Scholar 

  23. T. Tsuji, K. Iryo, N. Watanabe, M. Tsuji, Appl. Surf. Sci. 202, 80 (2002)

    Article  Google Scholar 

  24. S.I. Dolgaev, A.V. Simakin, V.V. Voronov, G.A. Shafeev, F. Bozon-Verduraz, Appl. Surf. Sci. 186, 546 (2002)

    Article  Google Scholar 

  25. A.V. Kabashin, M. Meunier, J. Appl. Phys. 94, 7941 (2003)

    Article  ADS  Google Scholar 

  26. A.V. Kabashin, M. Meunier, C. Kingston, J.H.T. Luong, J. Phys. Chem. B 107, 4527 (2003)

    Article  Google Scholar 

  27. J.-P. Sylvestre, A.V. Kabashin, E. Sacher, M. Meunier, J.H.T. Luong, J. Am. Chem. Soc. 126, 7176 (2004)

    Article  Google Scholar 

  28. J.-P. Sylvestre, S. Poulin, A.V. Kabashin, E. Sacher, M. Meunier, J.H.T. Luong, J. Phys. Chem. B 108, 16864 (2004)

    Article  Google Scholar 

  29. J. Muramoto, Y. Nakata, T. Okada, M. Maeda, Japan. J. Appl. Phys. 36, L563 (1997)

    Article  Google Scholar 

  30. D.B. Geohegan, A.A. Puretzky, G. Duscher, S.J. Pennycook, Appl. Phys. Lett. 73, 438 (1998)

    Article  ADS  Google Scholar 

  31. D.B. Geohegan, A.A. Puretzky, G. Duscher, S.J. Pennycook, Appl. Phys. Lett. 72, 2987 (1998)

    Article  ADS  Google Scholar 

  32. S.R. Foltyn, in Pulsed Laser Deposition of Thin Films, ed. by D.B. Chrisey, G.K. Hubler (Wiley, New York, 1994), Chap. 4 and references therein

  33. D.J. Krajnovich, J.E. Vazquez, J. Appl. Phys. 73, 3001 (1993)

    Article  ADS  Google Scholar 

  34. F.F. Abraham, Homogeneous Nucleation Theory: The Pretransition Theory of Vapor Condensation (Academic, New York, 1974)

    Google Scholar 

  35. D. Kashchiev, Nucleation: Basic Theory with Applications (Butterworth-Heinemann, Oxford, 2000)

    Google Scholar 

  36. M. Goede, VDI Rep., Ser. 5, No. 587 (VDI, Düsseldorf, 2000)

  37. First International Symposium on High-Power Laser Macroprocessing, ed. by I.M. Miyamoto, K.F. Kobayashi, K. Sugioka, R. Poprawe, H. Heliajian, Proceedings of the SPIE, Volume 4831 (2003), pp. 459–462

  38. J. Koch, A. von Bohlen, R. Hergenröder, K. Niemax, J. Anal. Atom. Spectrom. 19, 267 (2004)

    Article  Google Scholar 

  39. A. Ostendorf, S. Barcikowski, T. Püster, J. Bunte, in Tagung Optische Technologien in der Kunststofftechnik, Munich, 11–12 November 2003 (VDI Rep. No. 1810) (VDI, Düsseldorf, 2003), pp. 113–130

  40. S. Barcikowski, R. Ostrowski, J. Marczak, M. Strzelec, J. Walter, A. Ostendorf, in Laser Cleaning II. ed. by D.M. Kane (World Scientific, Singapore, 2006), Chapt. 9, pp. 197–208

  41. S. Preuss, A. Demchuk, M. Stuke, Appl. Phys. A 63, 315 (1996)

    Google Scholar 

  42. T. Götz, M. Stuke, Appl. Phys. A 64, 539 (1997)

    Article  ADS  Google Scholar 

  43. I. Zergioti, M. Stuke, Appl. Phys. A 67, 391 (1998)

    Article  ADS  Google Scholar 

  44. J. Bunte, S. Barcikowski, T. Puester, T. Burmester, M. Brose, T. Ludwig, in Femtosecond Technology for Technical and Medical Applications, ed. by F. Dausinger et al. (Springer Top. Appl. Phys. 96) (Springer, Berlin, 2004), Chap. 9.2, pp. 309–321

  45. J. Perrière, E. Millon, W. Seiler, C. Boulmer-Leborgne, V. Craciun, O. Albert, J.C. Loulergue, J. Etchepare, J. Appl. Phys. 91, 690 (2002)

    Article  ADS  Google Scholar 

  46. J.-P. Sylvestre, A.V. Kabashin, E. Sacher, M. Meunier, Appl. Phys. A 80, 753 (2005)

    Article  ADS  Google Scholar 

  47. S. Besner, J.-Y. Degorce, A.V. Kabashin, M. Meunier, Appl. Surf. Sci. 247, 163 (2005)

    Article  ADS  Google Scholar 

  48. A. Vogel, J. Noack, K. Nahen, D. Theisen, S. Busch, U. Parlitz, D.X. Hammer, G.D. Noojin, B.A. Rockwell, R. Birngruber, Appl. Phys. B 68, 271 (1999)

    Article  ADS  Google Scholar 

  49. M. Kerker, The Scattering of Light and Other Electromagnetic Radiation (Academic, New York, 1969)

    Google Scholar 

  50. U. Kreibig, M. Vollmer, Optical Properties of Metal Clusters (Springer, Berlin, 1996)

    Google Scholar 

  51. P.G. Kik, S.A. Maier, H.A. Atwater, Mater. Res. Soc. 705, Y3.6.1 (2002)

  52. J.R. Morones, J.L. Elechiguerra, A. Camacho, K. Holt, J.B. Kouri, J.T. Ramirez, M.J. Yacaman, Nanotechnology 16, 2346 (2005)

    Article  ADS  Google Scholar 

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Correspondence to B.N. Chichkov.

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PACS

79.20.Ds; 81.16.Mk; 81.16.-c; 52.38.Ph; 06.60.Jn

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Barcikowski, S., Hahn, A., Kabashin, A. et al. Properties of nanoparticles generated during femtosecond laser machining in air and water. Appl. Phys. A 87, 47–55 (2007). https://doi.org/10.1007/s00339-006-3852-1

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  • DOI: https://doi.org/10.1007/s00339-006-3852-1

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