Abstract
A detailed study of the room temperature structure of high quality single crystalline SrB6 has been made. Minute changes in interatomic distances may drastically affect the electronic spectrum of this compound. Electronic transport properties both at zero and non-zero frequencies above 4He temperatures indicate that SrBP6 is close to be a semiconductor. However, at very low temperatures this compound enters a metallic state with a low concentration of itinerant charge carriers. Possible correlation effects are indicated by anomalous temperature dependences of the electrical resistivity and the specific heat below 1 K.
Similar content being viewed by others
References
Johnson, R.W., Daane, A.H.: J. Chem. Phys. 38, 425 (1963)
Etourneau, J., Mercurio, J.P., Naslain, R., Hagenmuller, P.: J. Solid State Chem. 2, 332 (1970)
see, e.g., Boron and Refractory Borides, ed. V.I. Matkovich, (Springer, Berlin 1977)
von Stackelberg, M., Neumann, F.: Z. Phys. Chem. B19, 314 (1932)
Allard, G.: Bull. Soc. Chim. France 51, 1213 (1932)
Pauling L., Weinbaum, S.: Z. Kristallogr. 187, 181 (1934)
Travaglini, G., Wachter, P.: Phys. Rev. B29, 893 (1984)
von Molnar, S., Teis, T., Benoit, A., Briggs, A., Flouquet, J., Ravex, J., Fisk, Z.: in Valence Instabilities, ed. P. Wachter and H. Boppart, (North Holland, Amsterdam 1982) p. 389
XSCANS and SHELXTL PC are products of Siemens Analytical X-ray Instruments, Madison, WI 53719. SHELX-93 is a program for crystal structure refinement, written by G.M. Sheldrick, (University of Göttingen 1993, Germany)
Walker, N., Stuart D., Acta Cryst, A39, 158 (1983)
Willis, B.T., Pryor, A.W.: in Thermal Vibrations in Crystallography, Cambridge University Press, Cambridge (1975) p. 104
Larson, A.C.: Crystallographic Computing, ed. F.R. Ahmed, (Munksgaard, Copenhagen 1970) p. 291
Scheringer, C.: Acta Crystallogr. A29, 82 (1973)
Blomberg, M.K., Merisalo, M.J., Korsukova, M.M., Gurin, V.N.: J. of Alloys and Compounds 217, 123 (1995)
Blomberg, M.K., Merisalo M.J., Korsukova, M.M., Gurin, V.N.: J. of Alloys and Compounds 168, 313 (1993)
Trunov, V.A., Malyshev, A.L., Yu. Chernyshev, D., Kurbakov, A.I., Korsukova, M.M., Gurin, V.N., Aslanov, L.A., Chernyshev, V.V., J. Appl. Cryst. 24, 888 (1991)
Trunov, V.A., Malyshev, A.L., Yu. Chernishev, D., Korsukova, M.M., Gurin, V.N., Aslanov, L.A., Chernishev, V.V.: J. Phys.: Cond. Mat. 5, 2479 (1993)
Eliseev, A.A., Efremov, V.A., Kuz'micheva, G.M., Konovaleva, E.S., Lazorenk, V.I., Paderno, Yu. B., Khlyustova, S. Yu.: Sov. Phys. Crystallogr. 31, (1986)
Korsukova, M.M.: Gurin, V.N., Lundstrom, T., Tergenius, L.E.: J. of Alloys and Compounds 117, 73 (1986)
Murakawa, S., Kawai, S.: J. Cryst. Growth 26, 165 (1974)
Turrell, S., Yahia, Z., Huvenne, J.P., Lacroix, B. and Turrell, G.: J. Mol. Struct. 174, 455 (1988)
see, e.g., F. Wooten, in Optical Properties of Solids, (Academic, New York 1972)
Massidda, S., Continenza, A., de Pascale, T.M., Monnier, R.: to appear in Z. Phys. B.
Otsuka, Y., Ikehata, S., Kobayashi, S., Sasaki, W.: Solid State Comm. 20, 441 (1976)
Monnier, R.: private communication
Degiorgi, L., Hunt, M., Ott, H.R., Dressel, M., Feenstra, J., Grüner, G., Fisk, Z.: Europhys. Lett. 28, 341 (1994)
Mott, N.F., Davis, E.A.: in Electronic Processes in NonCrystalline Materials, (Clarendon, Oxford 1971)
Milward, R.C., Neuringer, L.J.: Phys. Rev. Lett. 15, 664 (1965)
Pollak, M.: Phil Mag. 23, 519 (1971)
Kimura, S., Nanba, N., Tomikawa, M., Kunii, S., Kasuya, Y.: Phys. Rev. B46, 12196 (1992)
Fisk, Z., Canfield, P.C., Beyermann, W.P., Thompson, J.D., Hundley, M.F., Ott, H.R., Felder, E., Maple, M.B., Lopez de la Torre, M.A., Visani, P., Seaman, C.L.: Phys. Rev. Lett. 67, 3310 (1991)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ott, H., Chernikov, M., Felder, E. et al. Structure and low temperature properties of SrB6 . Z. Phys. B 102, 337–345 (1997). https://doi.org/10.1007/s002570050297
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s002570050297