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Structure and low temperature properties of SrB6

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Zeitschrift für Physik B Condensed Matter

Abstract

A detailed study of the room temperature structure of high quality single crystalline SrB6 has been made. Minute changes in interatomic distances may drastically affect the electronic spectrum of this compound. Electronic transport properties both at zero and non-zero frequencies above 4He temperatures indicate that SrBP6 is close to be a semiconductor. However, at very low temperatures this compound enters a metallic state with a low concentration of itinerant charge carriers. Possible correlation effects are indicated by anomalous temperature dependences of the electrical resistivity and the specific heat below 1 K.

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References

  1. Johnson, R.W., Daane, A.H.: J. Chem. Phys. 38, 425 (1963)

    Google Scholar 

  2. Etourneau, J., Mercurio, J.P., Naslain, R., Hagenmuller, P.: J. Solid State Chem. 2, 332 (1970)

  3. see, e.g., Boron and Refractory Borides, ed. V.I. Matkovich, (Springer, Berlin 1977)

  4. von Stackelberg, M., Neumann, F.: Z. Phys. Chem. B19, 314 (1932)

  5. Allard, G.: Bull. Soc. Chim. France 51, 1213 (1932)

    Google Scholar 

  6. Pauling L., Weinbaum, S.: Z. Kristallogr. 187, 181 (1934)

    Google Scholar 

  7. Travaglini, G., Wachter, P.: Phys. Rev. B29, 893 (1984)

  8. von Molnar, S., Teis, T., Benoit, A., Briggs, A., Flouquet, J., Ravex, J., Fisk, Z.: in Valence Instabilities, ed. P. Wachter and H. Boppart, (North Holland, Amsterdam 1982) p. 389

  9. XSCANS and SHELXTL PC are products of Siemens Analytical X-ray Instruments, Madison, WI 53719. SHELX-93 is a program for crystal structure refinement, written by G.M. Sheldrick, (University of Göttingen 1993, Germany)

  10. Walker, N., Stuart D., Acta Cryst, A39, 158 (1983)

  11. Willis, B.T., Pryor, A.W.: in Thermal Vibrations in Crystallography, Cambridge University Press, Cambridge (1975) p. 104

  12. Larson, A.C.: Crystallographic Computing, ed. F.R. Ahmed, (Munksgaard, Copenhagen 1970) p. 291

  13. Scheringer, C.: Acta Crystallogr. A29, 82 (1973)

  14. Blomberg, M.K., Merisalo, M.J., Korsukova, M.M., Gurin, V.N.: J. of Alloys and Compounds 217, 123 (1995)

    Google Scholar 

  15. Blomberg, M.K., Merisalo M.J., Korsukova, M.M., Gurin, V.N.: J. of Alloys and Compounds 168, 313 (1993)

    Google Scholar 

  16. Trunov, V.A., Malyshev, A.L., Yu. Chernyshev, D., Kurbakov, A.I., Korsukova, M.M., Gurin, V.N., Aslanov, L.A., Chernyshev, V.V., J. Appl. Cryst. 24, 888 (1991)

  17. Trunov, V.A., Malyshev, A.L., Yu. Chernishev, D., Korsukova, M.M., Gurin, V.N., Aslanov, L.A., Chernishev, V.V.: J. Phys.: Cond. Mat. 5, 2479 (1993)

  18. Eliseev, A.A., Efremov, V.A., Kuz'micheva, G.M., Konovaleva, E.S., Lazorenk, V.I., Paderno, Yu. B., Khlyustova, S. Yu.: Sov. Phys. Crystallogr. 31, (1986)

  19. Korsukova, M.M.: Gurin, V.N., Lundstrom, T., Tergenius, L.E.: J. of Alloys and Compounds 117, 73 (1986)

    Google Scholar 

  20. Murakawa, S., Kawai, S.: J. Cryst. Growth 26, 165 (1974)

    Google Scholar 

  21. Turrell, S., Yahia, Z., Huvenne, J.P., Lacroix, B. and Turrell, G.: J. Mol. Struct. 174, 455 (1988)

    Google Scholar 

  22. see, e.g., F. Wooten, in Optical Properties of Solids, (Academic, New York 1972)

  23. Massidda, S., Continenza, A., de Pascale, T.M., Monnier, R.: to appear in Z. Phys. B.

  24. Otsuka, Y., Ikehata, S., Kobayashi, S., Sasaki, W.: Solid State Comm. 20, 441 (1976)

  25. Monnier, R.: private communication

  26. Degiorgi, L., Hunt, M., Ott, H.R., Dressel, M., Feenstra, J., Grüner, G., Fisk, Z.: Europhys. Lett. 28, 341 (1994)

    Google Scholar 

  27. Mott, N.F., Davis, E.A.: in Electronic Processes in NonCrystalline Materials, (Clarendon, Oxford 1971)

  28. Milward, R.C., Neuringer, L.J.: Phys. Rev. Lett. 15, 664 (1965)

    Google Scholar 

  29. Pollak, M.: Phil Mag. 23, 519 (1971)

  30. Kimura, S., Nanba, N., Tomikawa, M., Kunii, S., Kasuya, Y.: Phys. Rev. B46, 12196 (1992)

  31. Fisk, Z., Canfield, P.C., Beyermann, W.P., Thompson, J.D., Hundley, M.F., Ott, H.R., Felder, E., Maple, M.B., Lopez de la Torre, M.A., Visani, P., Seaman, C.L.: Phys. Rev. Lett. 67, 3310 (1991)

    Google Scholar 

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Ott, H., Chernikov, M., Felder, E. et al. Structure and low temperature properties of SrB6 . Z. Phys. B 102, 337–345 (1997). https://doi.org/10.1007/s002570050297

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  • DOI: https://doi.org/10.1007/s002570050297

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