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Levels and Sources of PAHs in Air-borne PM2.5 of Hefei City, China

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Abstract

This work studied the concentrations and sources of polycyclic aromatic hydrocarbons (PAHs) in air-borne particulate matter of Hefei, China. Samples of PM2.5 were collected daily at two sites during May, 2014, and January, 2015. The average daily concentration of PM2.5 was 96.88 µg m−3, which is higher than the 2012 China Ambient Air Quality Standard (GB3095-2012 24-h grade II) of 75 µg m−3. The concentrations of 16 EPA priority polycyclic aromatic hydrocarbons (PAHs) were analyzed by gas chromatography-mass spectrometry. The PM2.5-bound PAH concentrations ranged from 4.92 to 71.00 ng m−3 (mean = 21.34 ng m−3), and exhibited obvious seasonal (31.38 ng m−3 in winter and 14.05 ng m−3 in summer) and spatial variability (27.23 ng m−3at site ME and 18.20 ng m−3 at site MS). Meteorological conditions such as ambient temperature, wind speed and humidity had influences on the concentrations of PAHs. As an index for PAH carcinogenicity, the annual average concentration of benzo(a)pyrene ranged from 0.46 to 2.31 ng m−3, with a mean of 1.15 ng m−3. This mean was lower than the China Ambient Air Quality Standard (GB3095-2012) of 2.5 ng m−3. The diagnostic PAH ratios and principal component analysis (PCA) suggested that combustion of coal and vehicle emissions were the main sources of PAHs in PM2.5.

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References

  • Baek SO, Goldstone ME, Kirk PWW, Lester JN, Perry R (1992) Concentrations of particulate and gaseous polycyclic aromatic hydrocarbons in London air following a reduction in the lead content of petrol in the United Kingdom. Sci Total Environ 111:169–199. doi:10.1016/0048-9697(92)90354-U

    Article  CAS  Google Scholar 

  • Brunner CR (1985) National ambient air quality standards. In: Hazardous air emissions from incineration. Springer, Berlin, pp 27–37

    Chapter  Google Scholar 

  • Cai Q-Y, Xiao P-Y, Lu H, Katsoyiannis A, Tian J-J, Zeng Q-Y, Mo C-H (2014) Evaluation of car air filters’ efficiency as active samplers for polycyclic aromatic hydrocarbons and heavy metals aerosol. Air Qual Res 14:431–439 doi:10.4209/aaqr.2013.03.0098

  • Chang K-F, Fang G-C, Chen J-C, Wu Y-S (2006) Atmospheric polycyclic aromatic hydrocarbons (PAHs) in Asia: A review from 1999 to 2004. Environ Pollut 142:388–396. doi:10.1016/j.envpol.2005.09.025

    Article  CAS  Google Scholar 

  • Chen W, Wang FS, Xiao GF, Wu K, Zhang SX (2015) Air quality of Beijing and impacts of the new ambient air quality standard. Atmos 6:1243–1258 doi:10.3390/atmos6081243

    Article  Google Scholar 

  • China M (2012) ambient air quality standards. GB 3095–2012 China environmental science press, Beijing

    Google Scholar 

  • Dachs J et al (2002) Processes driving the short-term variability of polycyclic aromatic hydrocarbons in the Baltimore and northern Chesapeake Bay atmosphere, USA. Atmos Environ 36:2281–2295. doi:10.1016/S1352-2310(02)00236-4

    Article  CAS  Google Scholar 

  • Deng X-l et al (2016) Characteristics of the water-soluble components of aerosol particles in Hefei, China. J Environ Sci 42:32–40

    Article  Google Scholar 

  • Fraser MP, Cass GR, Simoneit BRT (1998) Gas-phase and particle-phase organic compounds emitted from motor vehicle traffic in a Los Angeles roadway tunnel. Environ Sci Technol 32:2051–2060. doi:10.1021/es970916e

    Article  CAS  Google Scholar 

  • Guo H, Lee SC, Ho KF, Wang XM, Zou SC (2003) Particle-associated polycyclic aromatic hydrocarbons in urban air of Hong Kong. Atmos Environ 37:5307–5317. doi:10.1016/j.atmosenv.2003.09.011

    Article  CAS  Google Scholar 

  • Harrison RM, Smith DJT, Luhana L (1996) Source apportionment of atmospheric polycyclic aromatic hydrocarbons collected from an urban location in Birmingham, UK. Environ Sci Technol 30:825–832. doi:10.1021/es950252d

    Article  CAS  Google Scholar 

  • He L-Y, Hu M, Huang X-F, Zhang Y-H, Tang X-Y (2006) Seasonal pollution characteristics of organic compounds in atmospheric fine particles in Beijing. Sci Total Environ 359:167–176. doi:10.1016/j.scitotenv.2005.05.044

    Article  CAS  Google Scholar 

  • Hong H, Yin H, Wang X, Ye C (2007) Seasonal variation of PM10-bound PAHs in the atmosphere of Xiamen, China. Atmos Res 85:429–441 doi:10.1016/j.atmosres.2007.03.004

    Article  CAS  Google Scholar 

  • Hu J, Liu CQ, Zhang GP, Zhang YL (2012) Seasonal variation and source apportionment of PAHs in TSP in the atmosphere of Guiyang, Southwest China. Atmos Res 118:271–279 doi:10.1016/j.atmosres.2012.07.015

    Article  CAS  Google Scholar 

  • Jung DB, Cho YS, Kim IS, Lee JY, Kim YP (2015) Impact of energy consumption in northeast Asia to the particulate PAHs levels and composition at Seoul. Aerosol Air Qual Res 15:2190–2199 doi:10.4209/aaqr.2015.01.0038

    CAS  Google Scholar 

  • Khalili NR, Scheff PA, Holsen TM (1995) PAH source fingerprints for coke ovens, diesel and, gasoline engines, highway tunnels, and wood combustion emissions. Atmos Environ 29:533–542

    Article  CAS  Google Scholar 

  • Li H, Liu G, Cao Y (2014) Content and distribution of trace elements and polycyclic aromatic hydrocarbons in fly ash from a coal-fired CHP plant. Aerosol Air Qual Res 14:1179–1188 doi:10.4209/aaqr.2013.06.0216

    CAS  Google Scholar 

  • Liu JJ, Man RL, Ma SX, Li JS, Wu Q, Peng JY (2015) Atmospheric levels and health risk of polycyclic aromatic hydrocarbons (PAHs) bound to PM2.5 in Guangzhou, China. Mar Pollut Bull 100:134–143. doi:10.1016/j.marpolbul.2015.09.014

    Article  CAS  Google Scholar 

  • Ma W-L, Li Y-F, Qi H, Sun D-Z, Liu L-Y, Wang D-G (2010a) Seasonal variations of sources of polycyclic aromatic hydrocarbons (PAHs) to a northeastern urban city, China. Chemosphere 79:441–447. doi:10.1016/j.chemosphere.2010.01.048

  • Masih J, Singhvi R, Kumar K, Jain VK, Taneja A (2012) Seasonal variation and sources of polycyclic aromatic hydrocarbons (PAHs) in indoor and outdoor air in a semi arid tract of northern India. Aerosol Air Qual Res 12:515–525 doi:10.4209/aaqr.2011.11.0192

    CAS  Google Scholar 

  • Pui DYH, Chen S-C, Zuo Z (2014) PM2.5 in China: Measurements, sources, visibility and health effects, and mitigation. Particuology 13:1–26 doi:10.1016/j.partic.2013.11.001

    Article  CAS  Google Scholar 

  • Saxena M, Singh DP, Saud T, Gadi R, Singh S, Sharma SK, Mandal TK (2014) Study on particulate polycyclic aromatic hydrocarbons over Bay of Bengal in winter season. Atmos Res 145–146:205–213 doi:10.1016/j.atmosres.2014.04.001

    Article  Google Scholar 

  • Simcik MF, Eisenreich SJ, Lioy PJ (1999) Source apportionment and source/sink relationships of PAHs in the coastal atmosphere of Chicago and Lake Michigan. Atmos Environ 33:5071–5079. doi:10.1016/S1352-2310(99)00233-2

    Article  CAS  Google Scholar 

  • Talifu D, Wuji A, Tursun Y, Kang H, Hu Y, Guo Y, Shao L (2015) Micro-morphological characteristics and size distribution of PM2.5 in the Kuitun-Dushanzi egion of Xinjiang, China. Aerosol Air Qual Res 15:2258–2269 doi:10.4209/aaqr.2015.01.0053.

    CAS  Google Scholar 

  • Tang N et al (2005) Polycyclic aromatic hydrocarbons and nitropolycyclic aromatic hydrocarbons in urban air particulates and their relationship to emission sources in the Pan–Japan Sea countries. Atmos Environ 39:5817–5826. doi:10.1016/j.atmosenv.2005.06.018

    Article  CAS  Google Scholar 

  • Tekasakul P, Furuuchi M, Tekasakul S, Chomanee J, Otani Y (2008) Characteristics of PAHs in particulates in the atmospheric environment of Hat Yai City, Thailand, and relationship with rubber-wood burning in rubber sheet production. Aerosol Air Qual Res 8:265–278

    CAS  Google Scholar 

  • Tham YWF, Takeda K, Sakugawa H (2008) Polycyclic aromatic hydrocarbons (PAHs) associated with atmospheric particles in Higashi Hiroshima, Japan: influence of meteorological conditions and seasonal variations. Atmos Res 88:224–233 doi:10.1016/j.atmosres.2007.10.015

    Article  CAS  Google Scholar 

  • Wang XF, Cheng HX, Xu XB, Zhuang GM, Zhao CD (2008) A wintertime study of polycyclic aromatic hydrocarbons in PM2.5 and PM2.5-10 in Beijing: Assessment of energy structure conversion. J Hazard Mater 157:47–56. doi:10.1016/j.jhazmat.2007.12.092

    Article  CAS  Google Scholar 

  • Wang H et al. (2015) Chemical composition and light extinction contribution of PM2.5 in urban Beijing for a 1-year period. Aerosol Air Qual Res 15:2200–2211 doi:10.4209/aaqr.2015.04.0257

    CAS  Google Scholar 

  • You MQ (2014) Addition of PM2.5 into the national ambient air quality standards of China and the contribution to air pollution control: The case study of Wuhan, China. Sci World J doi:10.1155/2014/768405

    Google Scholar 

  • Yuan Z, Liu G, Da C, Wang J, Liu H (2015) Occurrence, sources, and potential toxicity of polycyclic aromatic hydrocarbons in surface soils from the yellow river delta natural reserve, China. Arch Environ Contam Toxicol 68:330–341. doi:10.1007/s00244-014-0085-8

    Article  CAS  Google Scholar 

  • Zheng M, Fang M (2000) Particle-associated polycyclic aromatic hydrocarbons in the atmosphere of Hong Kong Water. Air Soil Poll 117:175–189 doi:10.1023/a:1005169718072

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors acknowledge support from the National Natural Science Foundation of China (NO. 41173032 and NO. 41373110) and the Anhui Environmental Protection Scientific Research Fund (2015004). We acknowledge editors and reviewers for polishing the language of the paper and for in-depth discussion.

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Authors and Affiliations

  1. CAS Key Laboratory of Crust-Mantle Materials and Environment, School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui, 230026, China

    Ruoyu Hu, Guijian Liu, Hong Zhang, Huaqin Xue & Xin Wang

  2. State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, The Chinese Academy of Sciences, Xi’an, Shaanxi, 710075, China

    Ruoyu Hu & Guijian Liu

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  1. Ruoyu Hu
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  2. Guijian Liu
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  3. Hong Zhang
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  4. Huaqin Xue
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  5. Xin Wang
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Correspondence to Guijian Liu.

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Hu, R., Liu, G., Zhang, H. et al. Levels and Sources of PAHs in Air-borne PM2.5 of Hefei City, China. Bull Environ Contam Toxicol 98, 270–276 (2017). https://doi.org/10.1007/s00128-016-2019-9

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  • DOI: https://doi.org/10.1007/s00128-016-2019-9

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