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Testing and appraisal of polymer modified road bitumens—state of the art

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Abstract

Polymer of road applications and their effects of functional properties (permanent deformation, fatigue cracking, low temperature cracking, stripping, wear resistance and ageing) of asphalt pavements are described. The state of the art in test methods for polymer modified bitumens is presented. The methods are classified as standardized or non-standardized. A general description of each non-standardized test procedure is given. Current or proposed specification models for polymer modified bitumens are summarized. The present situation regarding test methods and specifications of polymer modified bitumens and the need for further development are discussed.

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References

  1. Isacsson, U. and Lu, X., ‘A compilation of test methods and specifications of polymer modified bitumens for road applications’ (Royal Institute of Technology, Department of Highway Engineering Stockholm) in press.

  2. Hancock, T., British Patent No. 4768 [1823], from reference [3].

  3. Zenke, G., ‘Polymer-modifizierte Straßenbaubitumen im Spiegel von literaturergebnissen versuch eines Resümees,’Die Asphaltstrasse 1 (1985) 5–16;4 (1985) 170–182;6 (1985) 264–284.

    Google Scholar 

  4. Fritz, H. W., Huet, J. and Urban, R., ‘English-French-German dictionary of technical terms related to hydrocarbon binders, hydrocarbon composite materials, processes for removing pavement material and for the rehabilitation of asphalt pavements,’Mater. Struct. 25 (1992) 171–185.

    Google Scholar 

  5. Hall, C., ‘Polymer Materials’ (Macmillan, London, 1985).

    Google Scholar 

  6. Billmeyer, Jr., F. W., ‘Textbook of Polymer Science’, 3rd Edn (Wiley, Chichester, 1984).

    Google Scholar 

  7. Whiteoak, D., ‘The Shell Bitumen Handbook’ (Shell Bitumen, UK, 1991) Chap. 10.

    Google Scholar 

  8. Downes, J. W., ‘Modified binders to the year 2000’, In 6th International Asphalt Conference, Sydney, Australia, January 1986, pp. 35–39.

  9. Dinnen, A., ‘Bitumen-thermoplastic rubber blends in road applications’, in Proceedings of 3rd Eurobitume Symposium, Hague, September 1985, Vol. I, pp. 646–651.

  10. Valkering, C. P., Vonk, W. C. and Whiteoak, C. D., ‘Improved asphalt properties using SBS modified bitumens’,Shell Bitumen Rev. 66 (May 1992) 9–11.

    Google Scholar 

  11. Rowlett, R. D., Martinez, D. F., Mofor, D. A., Romine, R. A. and Tahmoressi, M., ‘Performance of asphalt modifiers classification of modifiers and literature review’ (Strategic Highway Research Program, Center for Construction Materials Technology, Southwestern Laboratories, Houston, Texas, April 1990).

    Google Scholar 

  12. Peltonen, P., ‘Fibres as additives in bitumen’, in Proceedings of 4th Eurobitume Symposium, Madrid, October 1989, Vol. I, pp. 938–942.

  13. Cameleyre, J., Samanos, J. and Tessonneau, J., ‘In-situ behaviour of new types of fibre-based asphalt’,Ibbid, Proceedings of 4th Eurobitume Symposium, Madrid, October 1989 Vol. I, pp. 838–843.

  14. Gordillo, J., Tomas, R. and Gomez, F., ‘Advantages of the incorporation of fibre into cold microasphalt concrete’,Ibid, Proceedings of 4th Eurobitume Symposium, Madrid, October 1989 Vol. I, pp. 786–790.

  15. Muncy, H. W., King, G. N. and Prudhomme, J. B., ‘Improved rheological properties of polymer-modified asphalts’, in ‘Asphalt Rheology—Relationship to Mixture’, ASTM STP 941, edited by O. E. Briscoe (American Society for Testing and Materials, Philadelphia, 1987), pp. 146–165.

    Google Scholar 

  16. Breuer, J. U., ‘Storage stability test-homogeneity test for hot stored polymer modified binder’, in Proceedings of RILEM Residential Seminar, Dubrovnik, Yugoslavia, September 1988, p. 85.

  17. Berenguer, B. and Caba J. S. ‘Enhancement of the plasticity range in bitumen-SBS mixtures for roofing purposes’, in Proceedings of 4th Eurobitume Symposium, Madrid, October 1989, Vol. I, pp. 79–82.

  18. Fetz, E. and Angst, Ch., ‘Polymer modified bitumen requirements’, in Proceedings of 3rd Eurobitume Symposium, Hague, September 1985, Vol. I, pp. 506–511.

  19. Grimm, G., ‘Application of microscopic methods in the field of polymer-bitumen binders’, in Proceedings of 4th Eurobitume Symposium, Madrid, October 1989, Vol. I, pp. 54–59.

  20. Dony, A. and Durrieu, F., ‘Research work into modified bituminous binders with polymer additives,’Ibid. Proceedings of 4th Eurobitume Symposium, Madrid, October 1989, Vol. I, pp. 181–185.

  21. Lomi, C. and Varisco, F., ‘Compatibility of bitumen with acactic polypropylene, new experimental monitoring procedure’,Ibid, Proceedings of 4th Eurobitume Symposium, Madrid, October 1989, Vol. I, pp. 269–274.

  22. Thyrion, F., Cogneau, P. and Zwijsen, M., ‘Method for the evaluation of bitumens based on the characteristics of bitumen-polymer mixes’, in Proceedings of International Symposium on Chemistry of Bitumen, Rome, June 1991, Vol. II, pp. 969–999.

  23. Thompson, D. C. and Hagman, J. F., ‘The modification of asphalt with neoprene,’Proc. Assn Asphalt Paving Technol. 27 (1958) 494–512.

    Google Scholar 

  24. Denning, J. H. and Carswell, J., ‘Improvements in rolled asphalt surfacings by the addition of organic polymer’,TRRL Laboratory Report 989, 1981.

  25. Sybilski, D., ‘Non-Newtonian viscosity of polymer-modified bitumens,’Mater. Struct.,23 (1993) 15–23.

    Article  Google Scholar 

  26. Texas Transporation Institute, ‘Asphalt-rubber binder laboratory performance’, Research Report 347-IF.

  27. Harders, O., ‘Dropping of ball-test’, in Proceedings of RILEM Residential Seminar, Dubrovnik, Yugoslavia, September 1988, p. 91.

  28. Breuer, I. U., ‘Elastic recovery of polymer modified binder’,Ibid, Proceedings of RILEM Residential Seminar, Dubrovnik, Yugoslavia, September 1988 p. 83.

  29. Öster, R. and Silién, B., ‘The durability of modified bitumen in the asphalt making process and during one year on the road’, in Proceedings of 4th Eurobitume Symposium, Madrid, October 1989, Vol. I, pp. 324–328.

  30. Tosh, D. J., Taylor, M. B. and Robinson, H. L., ‘Simple but effective’,Highways (May 1992) 26–28.

  31. Oliver, J. W. H., Witt, H. P. and Isacsson, U., ‘Laboratory investigations of polymer modified bitumens using the ARRB elastometer’, in Proceedings of RILEM Residential Seminar, Dubrovnik, Yugoslavia, September 1988, pp 105–109.

  32. Jörgensen, T., ‘Creep testing with the controlled stress rheometer—A versatile tool for measuring elastic recovery of polymer modified bitumens’,Ibid, Proceedings of RILEM Residential Seminar, Dubrovnik, Yugoslavia, September 1988, pp. 93–95.

  33. Svetel, D., ‘Investigation of the elastic behaviour of bitumen’, in Proceedings of 3rd Eurobitume Symposium, Hague, September 1985, Vol. I, pp. 108–114.

  34. Benson, J. R., ‘New concepts for rubberized asphalts’Roads and Streets (April 1955) 138–142.

  35. Boussad, K. Carré, D. and Muller, J.-M., ‘The TTT: toughness tenacity test’, in Proceedings of RILEM Residential Seminar, Dubrovnik, Yugoslavia, September 1988, pp. 87–90.

  36. Woodside, A. R. and Lynch, H. G., ‘Assessment of performance of polymer modified binders when used in surface dressing’, in Proceedings of 4th Eurobitume Symposium, Madrid, October 1989, Vol. I, pp. 685–687.

  37. D-4 Proposal P226, ‘Proposed test methods for bituminous materials in tension’,

  38. Chaverot, P., ‘The force ductility test: a simple means of characterization of the polymer modified asphalt’, in Proceedings of 4th Eurobitume Symposium, Madrid, October 1989, Vol. I, p. 96–100.

  39. Verburg, H. A. and Molenaar, J. M. M., ‘Force-ductility test for specification of polymer modified bitumen’, in Proceedings of International Symposium on Chemistry of Bitumen, Rome, June 1991, Vol. II, pp. 922–931.

  40. Anderson, D. A. and Dongre, R. N., ‘Development of the SHRP direct tension test for bitumens’, in Proceedings of 5th Eurobitume Congress, Stockholm, June 1993, Vol. IA, pp. 250–255.

  41. SHRP Test Method B-002, Technology Information Sheet, 29 January 1993.

  42. Jovanovic, J. A., Djonlagic, J. and Dunjic B., ‘A rheological study of behaviour of polymer-bitumen blends’, in Proceedings of 5th Eurobitume Congress, Stockholm, June 1993, Vol. IA, pp. 256–262.

  43. De Ferrariis, L., Gallino, G., Italia, P., Mancini, G. and Rebesco, E., ‘Rheological characteristics of polymer modified bitumens’,Ibid, Proceedings of 5th Eurobitume Congress, Stockholm, June 1993, Vol. IA, pp. 133–137.

  44. Cavaliere, M. G., Diani, E. and Vitalini Sacconi, L., ‘Polymer modified bitumens for improved road application’Ibid, Proceedings of 5th Eurobitume Congress, Stockholm, June 1993, Vol. IA, pp. 133–137.

  45. Cavaliere, M. G., Diani, E. and Vitalini Sacconi, L., ‘Polymer modified bitumens for improved road application’Ibid, Proceedings of 5th Eurobitume Congress, Stockholm, June 1993, Vol. IA, pp. 138–142.

  46. Khalid, H. and Davies, E., ‘A dynamic approach to predict the performance of conventional and polymer modified binders and mixes containing them’.,Ibid, Proceedings of 5th Eurobitume Congress, Stockholm, June 1993, Vol. IA, pp. 246–249.

  47. Jørgensen, T., ‘Rheological testing of binders with a controlled stress rheometer’,Ibid, Proceedings of 5th Eurobitume Congress, Stockholm, June 1993, Vol. IA, pp. 171–174.

  48. Kolb, K. H., ‘Laboratory evaluation of polymer modified bitumen and polymer modified asphalt’, in Proceedings of 3rd Eurobitume Symposium, Hague, September 1985, VolI, pp. 533–536.

  49. SHRP Test Method B-003, Technology Information Sheet, 3 February 1993.

  50. King, G. N., Muncy, H. W. and Prudhomme, J. B., ‘Polymer modification: binders effect on mix properties,’Proc. Assn Asphalt Paving Technol. 55 (1986) 519–540.

    Google Scholar 

  51. Boussad, K., Muller J.-M. and Touzard, B., ‘Evaluation of brittleness temperature thru plate cohesion test’, in Proceedings of RILEM Residential Seminar, Dubrovnik Yukoslavia, September 1988, pp. 225–228.

  52. Breuer, J. U., ‘Dropping temperature of chips in the cold (KST) and in the heat (WST),’Ibid, Proceedings of RILEM Residential Seminar, Dubrovnik Yukoslavia, September 1988, pp. 229–231.

  53. Molenaar, J. M. M., ‘Polymer modified bitumens-functional properties and quality aspects’, in Proceedings of International Symposium on Chemistry of Bitumens, Rome, June 1991, Vol. II, pp. 860–886.

  54. Bononi, A., ‘Méthodologie de caractérisation des liants modifiés’, in Proceedings of RILEM Residential Seminar, Dubrovnik, Yugoslavia, September 1988, pp. 119–133.

  55. Belgian Road Research Centre Method of Measurement-ME 65/91, ‘Boiling water stripping test on coarse aggregates coated with a bituminous binder’,

  56. SHRP Test Method B-005, Technology Information Sheet, 29 January 1993.

  57. Choquet, F. S. and Verhasselt, A. F., ‘Ageing of bitumen: from the road to the laboratory and vice versa’, in Proceedings of Strategic Highway Research Program (SHRP) and Traffic Safety on Two Continents, The Hague, September 1993 (VTI Konferens, Linköping, 1994), No. 1A, Part 3, pp. 193–213.

  58. Fifield, F. W. and Kealey, D., ‘Principles and Practice of Analytical Chemistry’, 3rd Edn (Blackie, London, 1990) Chap. 9.

    Google Scholar 

  59. Little, D. N., Button, J. W., White, R. M., Ensley, E. K., Kim, Y. and Ahmed, S. J., ‘Investigation of asphalt additives’, Report No. FHWA/RD-87/001 (US Department of Transportation, Federal Highways Aministration, 1987) Chap. III.

  60. He, L. Y. and Button, J. W., ‘Methods to determine polymer content of modified, asphalt’, Transporation Research Record 1317 (TRB, National Research Council, Washington, DC, 1991) pp. 23–31.

    Google Scholar 

  61. Choquet, F. S. and Ista, E. J., ‘The determination of SBS, EVA and APP polymers in modified bitumens’, in ‘Polymer Modified Asphalt Binders,’ ASTM STP 1108, edited by K. R. Wardlaw and S. Shuler (American Society for Testing and Materials, Philadelphia, 1992) pp. 35–49.

    Google Scholar 

  62. Choquet, F., Ista, E. and Cogneau, P., ‘Determining the composition of roofing membranes manufactured with atactic polypropylene (APP)’, in Proceedings of Third International Symposium on Roofing Technology, 1991 pp. 436–444.

  63. SHRP A-004 Interim Report, ‘Summary of Phase I Results’ (Southwestern Laboratories, Texas, 1990).

  64. Jovanovic, J., Sokiv, M., Smiljanic, M., Pap, I. Neumann, H.-J. and Rahimian, I., ‘The production of stable bitumen-polymer blends’, in Proceedings of International Symposium on Chemistry of Bitumens, Rome, June 1991, Vol. II, pp. 906–921.

  65. Goodrich, J. L., Goodrich, J. E. and Kari, W. J., ‘Asphalt composition tests: Their application and relation to field performance’, Transportation Research Record 1096 (TRB, National Research Council, Washington, DC, 1986) pp. 146–167.

    Google Scholar 

  66. Giavarini, C. and Vecchi, C., ‘Evaluation of bitumen by NMR’, in Proceedings of 4th Eurobitume Symposium, Madrid, October 1989, Vol. I, pp. 260–263.

  67. Santagata, E. and Montepara, A., ‘An NMR based method for the chemical characterization and rheological selection of modified bitumens’, in Proceedings of 5th Eurobitume Congress, Stockholm, June 1993, Vol. IA, pp. 143–147.

  68. Fifield, F. W. and Kealey, D., ‘Principles and Practice of Analytical Chemistry’, 3rd Edn (Blackie, London, 1990) Chap. 4.

    Google Scholar 

  69. Ruud, O. E., ‘Characterization of bituminous binders by gas chromatography’, in Proceedings of 4th Eurobitume Symposium, Madrid, October 1989, Vol. I, pp. 285–289.

  70. Neubauer, O., ‘Chromatography of SBS in bitumen’, in Proceedings of RILEM Residential Seminar, Dubrovnik, Yugoslavia, September 1988, p. 155.

  71. Sherma, J. and Fried, B., ‘Handbook of Thin-Layer Chromatography’, (Marcel Dekker, New York, 1991) pp. 342–348.

    Google Scholar 

  72. Brule, B., Brion, Y. and Tanguy, A., ‘Paving asphalt polymer blends: relationships between composition, structure and properties,’Proc. Assn Asphalt Paving Technol. 57 (1988) 41–64.

    Google Scholar 

  73. Torres, J., Gonzalez, J. Ma. and Peralta, X., ‘Correlation between the fractionation of bitumen according to the methods ASTM D 4124 and Iatroscan’, in Proceedings of 5th Eurobitume Congress, Stockholm, June 1993, Vol. IA, pp. 203–208.

  74. Molenaar, J. M. M. ‘Polymer modified bitumens-Functional properties and quality aspects’, in Proceedings of International Symposium on Chemistry of Bitumens, Rome, June 1991, Vol. II, pp. 860–886.

  75. Johansson, U. and Linde, S., ‘Polymer modified asphalt binders, Part 1’, SP Report 1991:02 (Swedish National Testing and Research Institute).

  76. Anderson, D. A. and Kennedy, T. W., ‘Development of the SHRP binder specification’, presented at Binder Workshop, Stockholm, June 1993.

  77. Khosla, N. P. and Zahran, S. Z., ‘A mechanistic evaluation of mixes containing conventional and polymer modified (styrelf) asphalts’,Proc. Assn Asphalt Paving Technol. 58 (1989) 274–302.

    Google Scholar 

  78. Terrel, R. L. and Walter, J. L., ‘Modified asphalt pavement materials—The European experience’,Proc. Assn Asphalt Paving Technol. 55 (1986) 482–518.

    Google Scholar 

  79. Choyce, P. W., ‘Asphalt mixtures containing EVA modified bitumen’, in Proceedings of 4th Eurobitume Symposium, Madrid, October, 1989, Vol. I, pp. 505–508.

  80. Gschwendt, I. and Sekera, M., ‘Bituminous mixes with rubber modified binders’, in Proceedings of 5th Eurobitume Congress, Stockholm, June 1993, Vol. IB, pp. 516–519.

  81. Srivastava, A. and Baumgardner, G. L., ‘Polymer modified bitumen and related properties’,Ibid, Proceedings of 5th Eurobitume Congress, Stockholm, June 1993, Vol. IA, pp. 151–155.

  82. Schüller, S. and Forstén, L., ‘Effect of binder properties on polymer modified asphalt concrete’,Ibid, Proceedings of 5th Eurobitume Congress, Stockholm, June 1993, Vol. IB, pp. 520–525.

  83. Beecken, G., ‘‘Ten years’ experience with Caribit in Germany’,Shell Bitumen Rev. 66 (May 1992) 12–15.

    Google Scholar 

  84. Harlin, J. P., Jariel, J. L. and Blondel, J. C., ‘Twelve years service life without specific maintenance for the bitumen Cariflex TR-1101 bound wearing course of the Saint-Quentin Bridge’, in Proceedings of 4th Eurobitume Symposium, Madrid, October 1989, Vol. I, pp. 125–127.

  85. Mulder, E. A. and Whiteoak, C. D., ‘An objective assessment of the in-service performance of thermoplastic rubber modified bitumens for road applications’, in 16th ARRB Conference, Perth, Western, Australia, November 1992.

  86. Vonk, W. C., Phillips, M. C. and Roele, M., ‘Ageing resistance of bituminous road binders: benefits of SBS modification’, in Proceedings of 5th Eurobitume Congress, Stockholm, June 1993, Vol. IA, pp. 156–160.

  87. Button, J. W., ‘Summary of asphalt additive performance at selected sites’, Transportation Research Record 1342 (TRB, National Research Council, Washington, DC, 1992) pp. 67–75.

    Google Scholar 

  88. Button, J. W., Little, D. A. Kim, Y., and Ahmed, J., ‘Mechanistic evaluation of selected asphalt additives,’Proc. Assn Asphalt Paving Technol,56 (1987) 62–90.

    Google Scholar 

  89. Carpenter, S. H. and VanDam, T., ‘Laboratory performance comparisons of polymer-modified and unmodified asphalt concrete mixtures’, Transporation Research Record 1115 (TRB, National Research Council, Washington, DC, 1987) pp. 62–74.

    Google Scholar 

  90. King, G. N., King, H. W. Chaverot, P., Planche, J. P. and Harders, O., ‘Using European wheel-tracking and restrained tensile tests to validate SHRP performance graded binder specification for polymer modified asphalts’, in Proceedings of 5th Eurobitume Congress, Stockholm, June 1993, Vol. IA, pp. 51–55.

  91. King, G. N., King, H. W., Harders, O., Arand, W., Chaverot, P., Planche, J. P., ‘Influence of asphalt grade and polymer concentration on the low temperature performance of polymer modified asphalt’,Proc. Assn Asphalt Paving Technol. 62 (1993) 1–22.

    Google Scholar 

  92. Blomberg, T., ‘Better wear resistance with polymer modified bitumen’, in Proceedings of RILEM Residential Seminar, Dubrovnik, Yugoslavia, September 1988, pp. 315–317.

  93. Coplantz, J. S., Yapp, M. T. and Finn, F. N., ‘Review of relationships between modified asphalt properties and pavement performance’, SHRP-A-631, 1993.

  94. Reese, R., Letter summary of presentation made by Ron Resse at the 21st Pacific Coast Conference on Asphalt Specifications (California Department of Transportation, 1989) from reference [92].

  95. Berenguer, B., ‘Significant methods based on traditional tests or based on modern mechanical or rheological tests’, in Proceedings of RILEM Residential Seminar, Dubrovnik, Yugoslavia, September 1988, pp. 259–268.

  96. Ruud, O. E., ‘Polymer modified bitumen for road construction—A Nordic evaluation’,Ibid, Proceedings of RILEM Residential Seminar, Dubrovnik, Yugoslavia, September 1988, pp. 67–70.

  97. Vercoe, J., ‘Specification—Overseas experience’, ARRB Research Report 183 edited by J. W. H. Oliver (Australian Road Research Board, June 1990) pp. 65–81.

  98. Pallotta, D. S., ‘Significant methods based on modern physical and physicochemical test’, in Proceedings of RILEM Resisdential Seminar, Dubrovnik, Yugoslavia, September 1988, pp. 277–284.

  99. Valero, L., ‘Production control and reception control of polymer-bitumens either for waterproofing or for road construction’,Ibid. Proceedings of RILEM Residential Seminar, Dubrovnik, Yugoslavia, September 1988, pp. 285–286.

  100. McGennis, R. B., ‘Asphalt binder specification of the future’,Asphalt 7 (1993) 10–11.

    Google Scholar 

  101. Ramond, G., Pastor, M. and Such, C., ‘Determination of performance of a binder from its complex modulus’, in Proceedings of 5th Eurobitume Congress, Stockholm, June 1993, Vol. IA, pp. 81–85.

  102. Blomberg, T. of Neste OY, Borga, Finland, personal communication.

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Isacsson, U., Lu, X. Testing and appraisal of polymer modified road bitumens—state of the art. Materials and Structures 28, 139–159 (1995). https://doi.org/10.1007/BF02473221

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