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Synthesis and mesomorphic properties oftrans-[1,4-bis(5-R-pyrimidin-2-yl]-cyclohexanes and 1,2-bis-(5-R-pyrimidin-2-yl)ethanes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

New trans-bis(5-R-pyrimidin-2-yl)-1,4-cyclohexanes and-1,2-ethanes (R=C7H15, C6H4OR1, where R1=H, COCH3, C4H9, C5H11, C8H17) have been synthesized. Only nematic mesophases are found from a study of their mesomorphic properties, except for bis[5-(4-octyloxyphenyl)- and-(4-acetoxyphenyl)pyrimidin-2-yl)-cyclohexanes, which also exhibit smectic properties.

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Authors
  1. M. A. Mikhaleva
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  2. A. E. Kuznetsova
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Additional information

Novosibirsk Institute of Organic Chemistry of the Siberian Division of the Russian Academy of Sciences, Novosibirsk 630090, Russia; e-mail: benzol@nioch.nsc.ru. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 355–360, March, 1999.

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Mikhaleva, M.A., Kuznetsova, A.E. Synthesis and mesomorphic properties oftrans-[1,4-bis(5-R-pyrimidin-2-yl]-cyclohexanes and 1,2-bis-(5-R-pyrimidin-2-yl)ethanes. Chem Heterocycl Compd 35, 310–315 (1999). https://doi.org/10.1007/BF02259361

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  • DOI: https://doi.org/10.1007/BF02259361

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