Abstract
The Cahn-Allen model for the motion of phase-antiphase boundaries is generalized to account for nonlinearities in the kinetic coefficient (relaxation velocity) and the coefficient of the gradient free energy. The resulting equation is
wheref is bistable. Hereu is an order parameter and κ and α are physical quantities associated with the system's free energy and relaxation speed, respectively. Grain boundaries, away from triple junctions, are modeled by solutions with internal layers when ε≪1. The classical motion-by-curvature law for solution layers, well known when κ and α are constant, is shown by formal asymptotic analysis to be unchanged in form under this generalization, the only difference being in the value of the coefficient entering into the relation. The analysis is extended to the case when the relaxation time for the process vanishes for a set of values ofu. Then α is infinite for those values.
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Dedicated to Oliver Penrose on the occasion of his 65th birthday.
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Fife, P.C., Lacey, A.A. Motion by curvature in generalized Cahn-Allen models. J Stat Phys 77, 173–181 (1994). https://doi.org/10.1007/BF02186837
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DOI: https://doi.org/10.1007/BF02186837