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Atranes. II. Dipole moments and structure of silatranes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Possible steric configurations of 1-organyl- and 1-organoxysilatranes,

, are considered. The dipole moments of six compounds of this type (X=CH3, (CH3)2CH, CH2=CH, C6H5, C2H5O, C6H5O) have been found experimentally to be extremely high, 5.3–7.1 D. They conclusively show that the silatranes contain a semipolar transannular coordinate bond Si←N between the negatively charged 5 -covalent silicon atom in the middle of the planar SiO3 group and the tetrahederal onium nitrogen atom.

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References

  1. M. G. Voronkov, G. I. Zelchan, KhGS, 1, 51, 1965.

    Google Scholar 

  2. M. G. Voronkov, A. Ya. Deich, Izv. AN Latv. SSR, ser. khim., 145, 1964.

  3. M. G. Woronkow [Voronkov], A. J. Deitsch, J. pr. Chem., [4]22, 214, 1963.

    Google Scholar 

  4. J. E. Fergusson, D. K. Grant, R. H. Hickford, C. J. Wilkins, J. Chem. Soc., 99, 1955.

  5. A. B. Burg, J. Am. Chem. Soc., 76, 2674, 1954.

    Google Scholar 

  6. H. J. Emeleus, N. Miller, J. Chem. Soc., 819, 1939.

  7. B. J. Aylett, H. J. Emeleus, A. G. Meddock, J. Inorg. Nucl. Chem., 1, 185, 1955.

    Google Scholar 

  8. U. Wannagat, R. Schwarz, Z. anorg. Chem., 277, 73, 1954.

    Google Scholar 

  9. T. S. Piper, E. G. Rochow, J. Am. Chem. Soc., 76, 4318, 1954.

    Google Scholar 

  10. E. Schnell, Mon., 92, 1055, 1961; 93, 65, 1962.

    Google Scholar 

  11. V. Gutmann, P. Heilmayer, K. Utvary, Mon., 92, 322, 1961.

    Google Scholar 

  12. Fr. Hein, R. Burckhardt, Z. anorg. Chem., 268, 159, 1952.

    Google Scholar 

  13. C. L. Frye, G. E. Vogel, J. A. Hall, J. Am. Chem. Soc., 83, 996, 1961.

    Google Scholar 

  14. E. Larsson, Trans. Chalm. Univ., no. 115, 25, 15, 1951.

    Google Scholar 

  15. C. K. Ingold, Structure and Mechanism in Organic Chemistry [Russian Translation], IL, Moscow, 81–82, 1959.

    Google Scholar 

  16. O. A. Osipov, V. I. Minkin, Yu. B. Kletenik, Handbook of Dipole Moments (in Russian), Rostov State University, Rostov-on-Don, 34–40, 1961.

    Google Scholar 

  17. I. B. Mazheika, L. Kh. Avota, G. P. Sokolov, S. A. Giller, ZhOKh, 34, 3380, 1964.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Organic Synthesis AS Latvian SSR, Riga

    M. G. Voronkov, I. B. Mazheika & G. I. Zelchan

Authors
  1. M. G. Voronkov
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  2. I. B. Mazheika
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  3. G. I. Zelchan
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Part I, see [1].

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Voronkov, M.G., Mazheika, I.B. & Zelchan, G.I. Atranes. II. Dipole moments and structure of silatranes. Chem Heterocycl Compd 1, 38–41 (1965). https://doi.org/10.1007/BF01168916

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