Journal of Materials Science

, Volume 27, Issue 15, pp 4208–4210

Thermally induced transformations in GexAsyTe100−xy glasses

  • A. Srinivasan
  • E. S. R. Gopal
Papers

DOI: 10.1007/BF01105128

Cite this article as:
Srinivasan, A. & Gopal, E.S.R. J Mater Sci (1992) 27: 4208. doi:10.1007/BF01105128

Abstract

Chalcogenide glasses with compositions Ge7.5AsyTe92.5y (y=20, 40, 45, 47.5, 50, 52.5, 55) and Ge10AsyTe90−y (y=15, 20, 22.5, 35, 40, 45, 50) have been prepared by the melt-quenching technique. The amorphous nature of these glasses has been confirmed by X-ray powder diffractometry. The thermal stability of these glasses has been studied using differential scanning calorimetry (DSC). The compositional dependence of the glass transition temperature,Tg, the crystallization temperatures,Tc1 andTc2, and the melting temperature,Tm, are reported. The glass-forming tendency,Kgl, and the activation energy of crystallization,E, are calculated. The activation energy decreases with increasing tellurium content for both sets of glasses.

Copyright information

© Chapman & Hall 1992

Authors and Affiliations

  • A. Srinivasan
    • 1
  • E. S. R. Gopal
    • 1
  1. 1.Department of PhysicsIndian Institute of ScienceBangaloreIndia