Skip to main content
Log in

Periodic and aperiodic regimes in coupled dissipative chemical oscillators

  • Articles
  • Published:
Journal of Statistical Physics Aims and scope Submit manuscript

Abstract

Dynamic behavior of two identical reaction cells with linear symmetric coupling is studied in detail. The standard model reaction scheme “Brusselator” is used as the description of the kinetics. The uncoupled cells can exhibit either a stable stationary state or stable periodic oscillations. A number of stationary and periodic oscillatory patterns arise as a result of the coupling. A non-homogeneous spatio-temporal organization includes homoclinic and heteroclinic oscillations as well as chaotic regimes. Numerical continuation algorithms are used to determine the dependence of stationary and periodic solutions on parameters. Stable stationary nonhomogeneous regimes exist typically at intermediate levels of coupling intensity. The nonhomogeneous periodic solutions arise either via Hopf bifurcatios from stationary solutions or via period-doubling bifurcations from the homogeneous periodic solutions. The results obtained may serve as a standard for the study of the behavior of other coupled systems in which either a stable stationary state or stable oscillations exist in the single cell.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. I. Gmitro and L. E. Scriven, inIntracellular Transport, K. B. Warren, ed. (Academic Press, New York, 1966).

    Google Scholar 

  2. H. Martinez,J. Theor. Biol. 36:479 (1972).

    Google Scholar 

  3. I. Prigogine and R. Lefever,J. Chem. Phys. 48:1695 (1967).

    Google Scholar 

  4. R. A. Schmitz, inChemical Reaction Engineering Reviews, M. H. Hulburt, ed. (American Chemical Society, Washington, D.C., 1975), p. 165.

    Google Scholar 

  5. I. Stuchl and M. Marek,J. Chem. Phys. 77:1607 (1982a);77:2956 (1982b).

    Google Scholar 

  6. M. Marek and I. Stuchl,Biophys. Chem. 3:24 (1975).

    Google Scholar 

  7. O. E. Rössler,Z. Naturforsch. 31a:1168 (1976).

    Google Scholar 

  8. J. J. Tyson,J. Chem. Phys. 58:3919 (1973).

    Google Scholar 

  9. M. Kubíček,ACM Trans. Math. Software 2:98 (1976); M. Kubíček and M. Marek,Computational Methods in Bifurcation Theory and Dissipative Structures (Springer-Verlag, New York, 1983).

    Google Scholar 

  10. G. Nicolis and I. Prigogine,Self-Organization in Nonequilibrium Systems (John Wiley & Sons, New York, 1977).

    Google Scholar 

  11. E. N. Lorenz,J. Atm. Sci. 20:130 (1963).

    Google Scholar 

  12. C. Sparrow,The Lorenz Equations: Bifurcations, Chaos, and Strange Attractors (Springer-Verlag, New York, 1982).

    Google Scholar 

  13. J. Tyson and S. Kauffman,J. Math. Biol. 1:289 (1975); R. Lefever,Bull. Cl. Sci. Acad. Roy. Belg. 54:712 (1968).

    Google Scholar 

  14. M. Marek, inSynergetics—Far from Equilibrium, A. Pacault and C. Vidal, eds. (Springer-Verlag, New York, 1979), p. 12.

    Google Scholar 

  15. K. Bar-Eli,J. Phys. Chem. 88:3616 (1984); K. Bar-Eli,Physica 14D:242 (1985).

    Google Scholar 

  16. M. Holodniok and M. Kubíček,J. Comput. Phys. 55:254 (1984).

    Google Scholar 

  17. B. Fiedler,Global Hopf Bifurcation of Two Parameter Flows, preprint No. 293, University of Heidelberg, 1984; R. I. Bogdanov,Trudy Sent. I. G. Petrovskogo 2:23 (1976a);2:37 (1976b), (in Russian); see alsoSel. Math. Sou. 1:373, 389 (1984).

  18. J. Mallet-Paret and J. A. Yorke,J. Diff. Eq. 43:419 (1982).

    Google Scholar 

  19. M. Kawato and R. Suzuki,J. Theor. Biol. 86:547 (1980).

    Google Scholar 

  20. B. D. Hassard,Numerical Evaluation of Hopf Bifurcation Formulae, Report of the Department of Mathematics, State University of New York at Buffalo, 1978.

  21. M. Kubíček,SIAM J. Appl. Math. 38:103 (1980).

    Google Scholar 

  22. M. Feigenbaum,J. Stat. Phys. 19:25 (1978);J. Stat. Phys. 21:669 (1979).

    Google Scholar 

  23. I. Schreiber and M. Marek,Physica 5D:258 (1982); I. Schreiber, M. Kubíček, and M. Marek, inNew Approaches to Nonlinear Problems in Dynamics, P. J. Holmes, ed. (SIAM, Philadelphia, 1980), p. 496.

    Google Scholar 

  24. M. Marek and I. Schreiber,Stochastic Behaviour of Deterministic Systems (Academia, Praha, 1984), in Czech.

    Google Scholar 

  25. A. N. Sharkovskii,Ukr. Mat. Z. 16:61 (Kiev, 1964); P. štefan,Commun. Math. Phys. 54:237 (1977).

    Google Scholar 

  26. V. N. Shtern and L. V. Shumova,Phys. Lett. 103A:167 (1984); K. H. Alfsen and J. FrØyland, Systematics of the Lorenz Model atσ = 10, preprint (University of Oslo, Oslo, 1984).

    Google Scholar 

  27. M. Kubíček, A. Klič, and M. Holodniok, in preparation.

  28. A. Klíč,Aplikace matematiky 28:5 (1983); J. W. Swift and K. Wiesenfeld,Phys. Rev. Lett. 52:705 (1984).

    Google Scholar 

  29. I. Schreiber and M. Marek,Phys. Lett. 91A:263 (1982).

    Google Scholar 

  30. J. C. Alexander, Spontaneous Oscillations in Two 2-Component Cells Coupled by Diffusion, preprint (University of Maryland, Maryland, 1984).

    Google Scholar 

  31. V. I. Arnold,Geometrical Methods in the Theory of Ordinary Differential Equations (Springer-Verlag, New York, 1983).

    Google Scholar 

  32. P. Bryant and C. Jeffries,Phys. Rev. Lett. 53:250 (1984).

    Google Scholar 

  33. D. G. Aronson, M. A. Chory, G. R. Hall, and R. P. McGehee,Commun. Math. Phys. 83:303 (1982).

    Google Scholar 

  34. M. Sano and Y. Sawada,Phys. Lett. 97A:73 (1983).

    Google Scholar 

  35. M. Holodniok, M. Kubíček, and M. Marek, Stable and Unstable Periodic Solutions in the Lorenz Model (Technische UniversitÄt München, Technical report TUM-M 8217, Munich 1982).

  36. P. Raschmann, M. Kubíček, and M. Marek, inNew Approaches to Nonlinear Problems in Dynamics, P. J. Holmes, ed. (SIAM, Philadelphia, 1980), p. 271.

    Google Scholar 

  37. I. Schreiber, M. Kubíček, and M. Marek,Z. Naturforsch. 39c: 1170 (1984).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Schreiber, I., Holodniok, M., Kubíček, M. et al. Periodic and aperiodic regimes in coupled dissipative chemical oscillators. J Stat Phys 43, 489–519 (1986). https://doi.org/10.1007/BF01020650

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01020650

Key words

Navigation