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Estimates of general Mayer graphs III: Upper bounds obtained by means of spanningn-trees

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Abstract

We obtain computable upper bounds for any given Mayer graph withn root-points (orn-graph). These are products of integrals of the type\(\left( {\int {\left| {f_L } \right|^{z_{iL} y_i^{ - 1} } dx} } \right)^{yi} \), where thez iL andy i are nonnegative real numbers whose sum overi is equal to 1. As a particular case, we obtain the canonical bounds (see their definition in Section 2.2):

$$\left| {\int {\prod\limits_L {f_L \left( {x_i ,x_j } \right)dx_{n + 1} \cdot \cdot \cdot dx_{n + k} } } } \right| \leqslant \prod\limits_L {\left( {\int {\left| {f_L } \right|^{\alpha _L } dx} } \right)^{\alpha _L^{ - 1} } } $$

where theα L 's satisfy the conditionα L ≥1 for anyL, and ∑ L α −1L =k (k is the number of variables that are integrated over). These bounds are finite for alln-graphs of neutral systems. We obtain also finite bounds for all irreduciblen-graphs of polar systems, and for certainn-graphs occurring in the theory of ionized systems. Finally, we give a sufficient condition for an arbitraryn-graph to be finite.

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References

  1. M. Lavaud,Phys. Lett. 62A:295 (1977).

    Google Scholar 

  2. M. Lavaud, Estimates of general Mayer graphs. I: General theory,J. Stat. Phys. 27:593 (1982).

    Google Scholar 

  3. M. Lavaud, Thesis, Part II, A and B (1978).

  4. G. E. Uhlenbeck and G. W. Ford, inStudies in Statistical Mechanics, Vol. 1, J. de Boer and G. E. Uhlenbeck, eds. (North-Holland, Amsterdam, 1962).

    Google Scholar 

  5. A. Fetter and J. Walecka,Quantum Theory of Many Particle Systems (McGraw Hill, New York, 1972).

    Google Scholar 

  6. E. Speer,Generalized Feynman Amplitudes (Princeton University Press, Princeton, New Jersey, 1969).

    Google Scholar 

  7. R. Lefebvre and C. Moser, eds.,Advances in Chemical Physics, Vol. 14,Correlation Effects in Atoms and Molecules (Interscience, New York, 1969).

    Google Scholar 

  8. R. J. Riddell and G. E. Uhlenbeck,J. Chem. Phys. 21:2056 (1953).

    Google Scholar 

  9. J. Groeneveld, Thesis (1967). Published in Proc. Koninkl. Nederl. Akad. Wetenschappen, Ser. B70:454 (1967). See also Chap. 7 inGraph Theory and Theoretical Physics, F. Harary, ed. (Academic Press, New York, 1967), and Ref. 25.

  10. A Münster,Statistical Thermodynamics, Vols. 1 and 2 (Springer Verlag, Berlin, 1969 and 1974).

    Google Scholar 

  11. C. Berge,Graphes et hypergraphes (Dunod, Paris, 1970).

    Google Scholar 

  12. O. Penrose, inStatistical Mechanics T. Bak, ed. (Benjamin, New York, 1967).

    Google Scholar 

  13. F. Harary,Graph theory (Addison Wesley, Reading, Massachusetts, 1969), Theorem 4.1.

    Google Scholar 

  14. F. Harary, Ref. 13, Corollary 4.5 (b).

    Google Scholar 

  15. M. Simonnard,Programmation linéaire. Technique du calcul économique, Vols. 1 and 2 (Dunod, Paris, 1972 and 1973); G. B. Dantzig,Linear Programming and Extensions (Princeton Univ. Press, Princeton, New Jersey, 1962).

    Google Scholar 

  16. S. Kim, D. Henderson, and L. Oden,Trans. Faraday Soc. 65:2308 (1969).

    Google Scholar 

  17. M. Lavaud, Rapport d'activité au CNRS (1977).

  18. M. Lavaud, Estimates of general Mayer graphs. VI: Discussion of the accuracy of the upper bounds obtained by means of spanning n-trees, for a Lennard-Jones system (in preparation).

  19. M. Lavaud, Estimates of general Mayer graphs. V: The best upper bound obtained by means of spanning n-trees, for uniformly coverablen-graphs (in preparation).

  20. M. Lavaud,Phys. Lett. 63A:76 (1977).

    Google Scholar 

  21. M. Lavaud, Estimates of general Mayer graphs. II: Long-range behavior of 2-graphs occurring in the theory of ionized systems,J. Stat. Phys. 19:429 (1978).

    Google Scholar 

  22. M. Lavaud, Communication at the 7th Conference on Thermophysical properties, Washington, D.C., 10–12 May 1977; communication at the 13th IUPAP Conference on Statistical Physics, Haifa, Israël, 24–30 August 1977.

  23. E. E. Salpeter,Ann. Phys. (N.Y.) 5:183 (1958).

    Google Scholar 

  24. E. Meeron,J. Math. Phys. 1:192 (1960); J. M. J. Van Leeuwen, J. Groeneveld, and J. de Boer,Physica 25:792 (1959).

    Google Scholar 

  25. J. Groeneveld, inStatistical Mechanics, T. Bak, ed. (Benjamin, New York, 1967).

    Google Scholar 

  26. H. C. Andersen,Ann. Rev. Phys. Chem. 26:145 (1975).

    Google Scholar 

  27. J. D. Weeks, D. Chandler, and H. C. Andersen,J. Chem. Phys. 54:5237 (1971).

    Google Scholar 

  28. N. Dunford and J. T. Schwartz,Linear Operators (Wiley, New York, 1957), Vol. 1, p. 119.

    Google Scholar 

  29. J. O. Hirschfelder, C. F. Curtiss, and R. B. Byrd, Molecular theory of gases and liquids (Wiley, New York, 1964)

    Google Scholar 

  30. D. W. Jepsen and H. L. Friedman,J. Chem. Phys. 38:846 (1963), Appendix A.

    Google Scholar 

  31. R. Abe,Progr. Theor. Phys. 22:213 (1959).

    Google Scholar 

  32. M. Lavaud, Thesis, Part III B (1978), and Proceedings of the NATO Advanced Institute on Strongly Coupled PlasmasOrléans-la-source, France7–23 July 1977, G. Kalman, ed. (Plenum Press, New York, 1978).

    Google Scholar 

  33. I. S. Gradshteyn and I. N. Ryzhik,Table of Integrals, Series and Products (Academic Press, New York, 1965).

    Google Scholar 

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Lavaud, M. Estimates of general Mayer graphs III: Upper bounds obtained by means of spanningn-trees. J Stat Phys 27, 745–766 (1982). https://doi.org/10.1007/BF01013446

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