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Adsorption of dipolar hard spheres onto a smooth, hard wall in the presence of an electric field

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Abstract

Integral equations have been solved for the density profile of dipolar hard spheres against a hard, smooth wall in the presence of an electric field. This density profile was examined as a function of the bulk medium's temperature and density with different field strengths and field directions. It was found to depend primarily upon the competitive interactions of the field with the monolayer particles and the first outer shell with the monolayer particles.

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References

  1. J. A. Barker and D. Henderson,Rev. Mod. Phys. 48:587 (1976).

    Google Scholar 

  2. H. Reiss, H. L. Frisch, and J. L. Lebowitz,J. Chem. Phys. 31:369 (1959); E. Helfand, H. Reiss, H. L. Frisch, and J. L. Lebowitz,J. Chem. Phys. 33:1379 (1960).

    Google Scholar 

  3. J. W. Perram and E. R. Smith,Proc. R. Soc. Lond. A 353:193 (1977).

    Google Scholar 

  4. J. K. Percus,J. Stat. Phys. 15:423 (1976).

    Google Scholar 

  5. D. Henderson, F. F. Abraham, and J. A. Barker,Mol. Phys. 31:1291 (1976);32:1785 (1976).

    Google Scholar 

  6. L. Blum and G. Stell,J. Stat. Phys. 15:439 (1976).

    Google Scholar 

  7. F. F. Abraham, D. E. Schreiber, and J. A. Barker,J. Chem. Phys. 62:1958 (1975).

    Google Scholar 

  8. G. A. Chapela, G. Saville, and J. S. Rowlinson,J. Chem. Soc. Faraday Division, Gen. Disc. 59:22 (1975).

    Google Scholar 

  9. D. Isbister and R. J. Bearman,Mol. Phys. 28:1297 (1974)

    Google Scholar 

  10. D. Isbister and R. J. Bearman:Mol. Phys. 32:597 (1976)

    Google Scholar 

  11. D. Isbister,Mol. Phys. 32:949 (1976).

    Google Scholar 

  12. B. C. Freasier and D. Isbister, to appear inMol. Phys.

  13. D. Isbister, B. C. Freasier, and R. J. Bearman, to be published.

  14. H. C. Anderson,Ann. Rev. Phys. Chem. 26:145 (1975).

    Google Scholar 

  15. J. S. Høye, J. L. Lebowitz, and G. Stell,J. Chem. Phys. 61:3253 (1974); J. S. Høye and G. Stell,J. Chem. Phys. 67:524 (1977); G. Stell and J. J. Weiss,Phys. Rev. A 16:757(1977).

    Google Scholar 

  16. M. S. Wertheim,J. Chem. Phys. 55:4291 (1971).

    Google Scholar 

  17. R. J. Baxter,J. Chem. Phys. 52:4559 (1970).

    Google Scholar 

  18. E. Waisman, D. Henderson, and J. L. Lebowitz,Mol. Phys. 32:1373 (1976).

    Google Scholar 

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Isbister, D.J., Freasier, B.C. Adsorption of dipolar hard spheres onto a smooth, hard wall in the presence of an electric field. J Stat Phys 20, 331–345 (1979). https://doi.org/10.1007/BF01011941

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  • DOI: https://doi.org/10.1007/BF01011941

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