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A new graph expansion of virial coefficients

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Abstract

It is well known that the virial coefficients of the pressure of thermodynamic systems can be represented in terms of graphs. The existing graph expansions are compared with a new one, the overlap graph expansion. The merits of overlap graphs in general and especially for hard disks and spheres are discussed.

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Kratky, K.W. A new graph expansion of virial coefficients. J Stat Phys 27, 533–551 (1982). https://doi.org/10.1007/BF01011091

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  • DOI: https://doi.org/10.1007/BF01011091

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