Abstract
The recombination of nearest neighbors in a condensed matrix of free radicals was modeled by Jackson and Montroll as irreversible, sequential, random dimer filling of nearest-neighbor sites on an infinite, three-dimensional lattice. Here we analyze the master equations for random dimer filling recast as an infinite hierarchy of rate equations for subconfiguration probabilities using techniques involving truncation, formal density expansions (coupled with resummation), and spectral theory. A detailed analysis for the cubic lattice case produces, e.g., estimates for the fraction of isolated empty sites (i.e., free radicals) at saturation. We also consider the effect of a stochastically specified distribution of nonadsorptive sites (i.e., inert dilutents).
Similar content being viewed by others
References
A. M. Bass and H. P. Broida,Phys. Rev. 101:1740 (1956).
J. L. Jackson and E. W. Montroll,J. Chem. Phys. 28:1101 (1958); P. L. Chessin,J. Chem. Phys. 31:159 (1959); S. Golden,J. Chem. Phys. 29:61 (1958).
P. J. Flory,J. Am. Chem. Soc. 61:1518 (1939).
E. R. Cohen and H. Reiss,J. Chem. Phys. 38:680 (1963).
T. H. K. Barron and E. A. Boucher,Trans. Faraday Soc. 65:3301 (1969).
R. B. McQuistan and D. Lichtman,J. Math. Phys. 9:1680 (1968); T. H. K. Barron, R. J. Bawden, and E. A. Boucher,J. Chem. Soc. 70:651 (1974).
E. A. Boucher,Prog. Polym. Sci. 6:63 (1978).
P. D. Dawson and Y. K. Peng,Surf. Sci. 33:565 (1972); W. D. Dong,Surf. Sci. 42:609 (1974); D. R. Rossington and R. Borst,Surf. Sci. 3:202 (1965); J. B. Peri,J. Chem. Phys. 69:220 (1965).
R. B. McQuistan, D. Lichtman, and L. P. Levine,Surf. Sci. 20:401 (1970).
K. J. Vette, T. W. Orent, D. K. Hoffman, and R. S. Hansen,J. Chem. Phys. 60:4854 (1974).
D. K. Hoffman,J. Chem. Phys. 65:95 (1976); D. Knodel and D. K. Hoffman,J. Chem. Phys. 69:3438 (1978).
J. W. Evans,Physica A 123:297 (1984).
R. S. Nord and J. W. Evans,J. Chem. Phys. 82, in press (1985).
A. Silberberg and R. Simha,Biopolymers 6:479 (1968);Macromol. 5:332 (1972); R. H. Lacombe and R. Simha,J. Chem. Phys. 61:1899 (1974); A. Surda and I. Karasova,Surf. Sci. 109:605 (1981); J. Luque and A. Cordoba,J. Chem. Phys. 76:6393 (1982).
J. W. Evans, D. R. Burgess, and D. K. Hoffman,J. Chem. Phys. 79:5011 (1983).
J. W. Evans,J. Math. Phys. 25:2527 (1984).
J. J. Gonzalez and P. C. Hemmer,Polymer Lett. Ed. 14:645 (1976);J. Chem. Phys. 67:2496, 2509 (1977).
E. Merz, T. Alfrey, and G. Goldfinger,J. Polym. Sci. 1:75 (1946); H. J. Harwood, inReactions on Polymers, J. A. Moore, ed. Nato Adv. Study Inst. Series (D. Reidel, Dordrecht, 1973).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Evans, J.W., Nord, R.S. Random dimer filling of lattices: Three-dimensional application to free radical recombination kinetics. J Stat Phys 38, 681–705 (1985). https://doi.org/10.1007/BF01010485
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF01010485