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A geometrical measure for entropy changes

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Abstract

The geometrical approach to statistical mechanics is used to discuss changes in entropy upon sequential displacements of the state of the system. An interpretation of the angle between two states in terms of entropy differences is thereby provided. A particular result of note is that any state can be resolved into a state of maximal entropy (both states having the same expectation values for the constraints) and an orthogonal component. A cosine law for the general case is also derived.

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References

  1. F. Weinhold,J. Chem. Phys. 63:2479, 2484, 2488, 2496 (1975);65:559 (1976);Acc. Chem. Res. 9:236 (1976).

    Google Scholar 

  2. P. Salamon and R. S. Berry,Phys. Rev. Lett. 51:1127 (1983).

    Google Scholar 

  3. J. D. Nulton, P. Salamon, B. Andresen, and Qi Anmin,J. Chem. Phys. 83:334 (1985).

    Google Scholar 

  4. G. Ruppeiner,Phys. Rev. A20:1608 (1979);24:488 (1981).

    Google Scholar 

  5. G. Ruppeiner,Phys. Rev. Lett. 50:287 (1983);Phys. Rev. A27:1116 (1983).

    Google Scholar 

  6. P. Salamon, J. D. Nulton, and R. S. Berry,J. Chem. Phys. 82:2433 (1985); P. Salamon, J. D. Nulton, and E. Ihrig,J. Chem. Phys. 80:436 (1984).

    Google Scholar 

  7. R. D. Levine, Geometry in classical statistical thermodynamics,J. Chem. Phys. (to be published).

  8. W. K. Wootters,Phys. Rev. D23:357 (1981).

    Google Scholar 

  9. I. Procaccia and R. D. Levine,J. Chem. Phys. 65:3356 (1976).

    Google Scholar 

  10. F. Schlögl,Phys. Rep. 62:267 (1980).

    Google Scholar 

  11. R. D. Levine and M. Tribus, eds.,Maximum Entropy Formalism (M.I.T. Press, Cambridge, Massachusetts, 1979).

    Google Scholar 

  12. A. Hobson and B.-K. Cheng,J. Stat. Phys. 7:301 (1973).

    Google Scholar 

  13. R. D. Levine,J. Chem. Phys. 65:3302 (1976).

    Google Scholar 

  14. I. Procaccia, Y. Shimoni, and R. D. Levine,J. Chem. Phys. 65:3284 (1976).

    Google Scholar 

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Feldmann, T., Levine, R.D. & Salamon, P. A geometrical measure for entropy changes. J Stat Phys 42, 1127–1134 (1986). https://doi.org/10.1007/BF01010466

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  • DOI: https://doi.org/10.1007/BF01010466

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