Abstract
It is proved that every dynamic Monte Carlo algorithm for the self-avoiding walk based on a finite repertoire of local,N-conserving elementary moves is nonergodic (hereN is the number of bonds in the walk). Indeed, for largeN, each ergodic class forms an exponentially small fraction of the whole space. This invalidates (at least in principle) the use of the Verdier-Stockmayer algorithm and its generalizations for high-precision Monte Carlo studies of the self-avoiding walk.
Similar content being viewed by others
References
M. Delbrück, inMathematical Problems in the Biological Sciences (Proc. Symp. Appl. Math., Vol. 14), R. E. Bellman, ed. (American Mathematical Society, Providence, 1962), pp. 55–63.
P. H. Verdier and W. H. Stockmayer,J. Chem. Phys. 36:227 (1962).
P. H. Verdier,J. Comput. Phys. 4:204 (1969).
O. J. Heilmann,Mat. Fys. Medd. Dan. Vid. Selsk. 37, no. 2 (1968).
H. J. Hilhorst and J. M. Deutch,J. Chem. Phys. 63:5153 (1975).
P. H. Verdier and D. E. Kranbuehl,Polymer Preprints (ACS) 17:148 (1976).
T. M. Birshtein, V. N. Gridnev, Yu. Ya. Gotlib, and A. M. Skvortsov,Vysokomol. Soyed. A 19:1398 (1977) [Polymer Sci. USSR 19:1612 (1977)].
Yu. A. Taran and L. B. Stroganov,Vysokomol. Soyed. A 20:1787 (1978) [Polymer Sci. USSR 20:2007 (1978)].
D. E. Kranbuehl and P. H. Verdier,J. Chem. Phys. 71:2662 (1979).
K. Kremer, A. Baumgärtner, and K. Binder,J. Phys. A 15:2879 (1981).
O. J. Heilmann and J. Rotne,J. Stat. Phys. 27:19 (1982).
H. Meirovitch,Macromolecules 17:2038 (1984).
H. Kesten,J. Math. Phys. 4:960 (1963).
J. M. Hammersley and S. G. Whittington,J. Phys. A 18:101 (1985).
J. M. Hammersley and D. J. A. Welsh,Q. J. Math. (Oxford) Ser. 2 13:108 (1962).
J. P. J. Michels and F. W. Wiegel,Proc. R. Soc. Lond. A 403:269 (1986).
L. Monnerie and F. Gény,J. Chim. Phys. 66:1691 (1969); L. Monnerie, F. Gény, and J. Fouquet,J. Chim. Phys. 66:1698 (1969); F. Gény and L. Monnerie,J. Chim. Phys. 66:1708 (1969).
K. Kremer, A. Baumgärtner, and K. Binder,J. Phys. A 15:2879 (1981).
W. H. Stockmayer, W. Gobush, and R. Norvich,Pure Appl. Chem. 26:537 (1971).
A. Baumgärtner and K. Binder,J. Chem. Phys. 71:2541 (1979).
A. K. Kron,Vysokomol. Soyed. 7:1228 (1965) [Polymer Sci. USSR 7:1361 (1965)].
A. K. Kronet al., Molek. Biol. 1:576 (1967) [Molec. Biol. 1:487 (1967)].
F. T. Wall and F. Mandel,J. Chem. Phys. 63:4592 (1975).
F. Mandel,J. Chem. Phys. 70:3984 (1979).
C. Domb,J. Chem. Phys. 38:2957 (1963).
A. J. Guttmann, On the critical behaviour of self-avoiding walks, University of Melbourne, Department of Mathematics, Research Report #14 (1986).
P. H. Verdier,J. Chem. Phys. 45:2122 (1966).
D. E. Kranbuehl and P. H. Verdier,J. Chem. Phys. 56:3145 (1972).
M. Lax and C. Brender,J. Chem. Phys. 67:1785 (1977).
P. Romiszowski and W. H. Stockmayer,J. Chem. Phys. 80:485 (1984).
M. T. Gurleret al., Macromolecules 16:398 (1983).
S. Caracciolo and A. D. Sokal,J. Phys. A 19:L797 (1986).
K. Suzuki,Bull. Chem, Soc. Japan 41:538 (1968).
Z. Alexandrowicz,J. Chem. Phys. 51:561 (1969).
Z. Alexandrowicz and Y. Accad,J. Chem. Phys. 54:5338 (1971).
N. Madras and A. D. Sokal, in preparation.
F. T. Wall and J. J. Erpenbeck,J. Chem. Phys. 30:634 (1959).
N. Madras and A. D. Sokal, in preparation.
S. Redner and P. J. Reynolds,J. Phys. A 14:2679 (1981).
M. Lal,Molec. Phys. 17:57 (1969).
B. MacDonaldet al., J. Phys. A 18:2627 (1985).
N. Madras and A. D. Sokal, in preparation.
A. Berretti and A. D. Sokal,J. Stat. Phys. 40:483 (1985).
B. Berg and D. Foerster,Phys. Lett. 106B:323 (1981).
C. Aragão de Carvalho and S. Caracciolo,J. Phys. (Paris) 44:323 (1983).
C. Aragão de Carvalho, S. Caracciolo, and J. Fröhlich,Nucl. Phys. B 215[FS7]:209 (1983).
N. Madras, in preparation.
A. D. Sokal, Comparative analysis of Monte Carlo methods for the self-avoiding walk, in preparation.
L. Thomas and A. D. Sokal, in preparation.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Madras, N., Sokal, A.D. Nonergodicity of local, length-conserving Monte Carlo algorithms for the self-avoiding walk. J Stat Phys 47, 573–595 (1987). https://doi.org/10.1007/BF01007527
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF01007527