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Electric field gradients of111Cd in the hexagonal (A-phase) La2O3 and Nd2O3 sesquioxides

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Abstract

Perturbed angular correlation measurements of111In in hexagonal La2O3 and Nd2O3 yield well defined symmetric electric field gradients with coupling constantv Q =280 MHz (extrapolated) in La2O3 andv Q =269 MHz for Nd2O3 at room temperature. The coupling constant in La2O3 linearly decreases with temperature. The spectra of La2O3, strongly damped at RT, rise to full amplitude at 870 K indicating dynamical interactions.

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Lupascu, D., Albohn, J., Shitu, J. et al. Electric field gradients of111Cd in the hexagonal (A-phase) La2O3 and Nd2O3 sesquioxides. Hyperfine Interact 80, 959–964 (1993). https://doi.org/10.1007/BF00567447

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