Chemistry of Heterocyclic Compounds

, Volume 18, Issue 2, pp 127–130

Investigation of the kinetics of the nitration of thiophene derivatives

Authors

  • G. N. Freidlin
    • All-Union Scientific-Research and Design Institute of Monomers
  • A. A. Glushkova
    • All-Union Scientific-Research and Design Institute of Monomers
  • K. A. Solop
    • All-Union Scientific-Research and Design Institute of Monomers
Article

DOI: 10.1007/BF00512952

Cite this article as:
Freidlin, G.N., Glushkova, A.A. & Solop, K.A. Chem Heterocycl Compd (1982) 18: 127. doi:10.1007/BF00512952

Abstract

The kinetics of the nitration of thiophene derivatives with nitric acid in acetic anhydride were investigated. The nitration of 2-substituted thiophenes is a second-order reaction. The rate constants and activation parameters of the reaction were calculated. The possibility of the use of the Hanmett and Yukawa-Tsuno equations for this reaction series is demonstrated. An isokinetic dependence is observed.

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Copyright information

© Plenum Publishing Corporation 1982