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Investigation of the kinetics of the nitration of thiophene derivatives

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The kinetics of the nitration of thiophene derivatives with nitric acid in acetic anhydride were investigated. The nitration of 2-substituted thiophenes is a second-order reaction. The rate constants and activation parameters of the reaction were calculated. The possibility of the use of the Hanmett and Yukawa-Tsuno equations for this reaction series is demonstrated. An isokinetic dependence is observed.

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Authors and Affiliations

  1. All-Union Scientific-Research and Design Institute of Monomers, 300026, Tula

    G. N. Freidlin, A. A. Glushkova & K. A. Solop

Authors
  1. G. N. Freidlin
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  2. A. A. Glushkova
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  3. K. A. Solop
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 167–170, February, 1982.

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Freidlin, G.N., Glushkova, A.A. & Solop, K.A. Investigation of the kinetics of the nitration of thiophene derivatives. Chem Heterocycl Compd 18, 127–130 (1982). https://doi.org/10.1007/BF00512952

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  • DOI: https://doi.org/10.1007/BF00512952

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