Summary
The coefficient of thermal expansion is measured for irradiated Polyvinyl Chloride (PVC) from 10K to 340K. The samples of PVC are irradiated, up to 500 Mrad in steps of 100 Mrad, in air at room temperature by using Co gamma rays with a dose rate of 0.3 Mrad/h. The PVC is an amorphous sample which is confirmed by X-ray diffraction. The coefficient of thermal expansion is found to decrease with radiation dose from 10K to 110K and it increaseswith radiation dose from 110K to 340K. The results are explained on the basis of radiation induced degradation of the sample.
Similar content being viewed by others
References
Subrahmanyam H.N. and Subramanyam S.V., (1987) J. Polym. Sci. Polym. Phys., 25: 1549
Subrahmanyam H.N. and Subramanyam S.V., (1987) Polymer (GB) 20:1331
Lawton E.J., Bueche A.M. and Balwit J.S., (1953) Nature 172:76
Karpov V.L., (1855)Sessiya Akad. Nauk. SSSR Po. Mirnomu Ispolzovaniyu Atomnoi Energii, Moscow pp 1.
Charlesby A., (1953) Plastics 18: 142
Chapiro A. (1962) Radiation chemistry of polymeric systems Interscience, NY., pp 464.
Hiroshi Sobue, Yoneho Tabata and Yoshio Tajima (1958) J. Polym. Sci. 115: 598
Chapiro A. (1956) J. Chim. Physique, 53: 895
Charlesby A. (1960) Atomic radiation and polymers, Pergamon Press, Oxford, pp 312.
Miller A.A., (1958) J. Phy. Chem., 63:1755
Subrahmanyam H.N. and Subramanyam S.V., (1986) Framana 27:647
Krishnapur P.P., Subramanyam S.V. and Rajagopal E.S., (1979) Ind. J. Technol., 17: 165
Pott R. and Schefzyk, (1983) J. Phys. E., 16: 444
Subrahmanyam H.N., (1985) Ph.D., Thesis, Indian Institute of Science, Bangalore India.
Wang L.H., Choy C.L. and Porter R.S., J. Polym.Sci. (1982) Polym. Phys., 20:633
Wang L.H., Choy C.L. and Porter R.S., (1983) J.Polym.Sci. Polym.Phys., 21: 657
Hellwege K.H., Hennig J. and Knappe W., (1963) Kolloid-Z., 188: 121
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Jayanna, H.S., Subramanyam, S.V. Thermal expansion of irradiated polyvinyl chloride from 10 K to 340 K. Polymer Bulletin 28, 481–487 (1992). https://doi.org/10.1007/BF00297343
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00297343