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Geochemistry of Proterozoic molybdenite — mineralized aplites in Northern Sweden

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Abstract

The largest known Precambrian molybdenite occurrences in Sweden are of the aplitic type. In order to improve the understanding of their genesis, 67 samples of aplites, aplitic granites and associated granites were analyzed for major elements, Mo, Sn, Be, Ba, Rb, Sr, Cu, Zn, Zr, V, Cr, Ni, Y, Nb, F, Cl and S. Five samples were analyzed for rare earth elements. The following genetic model can be proposed:

In the upper parts of granitic intrusions the magma is enriched in lithophile elements and elements such as F and Mo. The aplites represent direct differentiation products of the granites and have solidified without the development of a second mobile aqueous phase, except locally, where small pegmatite segregations have formed. As crystallization proceeds, the concentration of Mo in the magma increases, and when the aplites solidify, the Mo that cannot be incorporated in the rock-forming minerals is precipitated as molybdenite. Biotite seems to be the major Mo-carrier among the rock-forming minerals in the aplites.

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References

  • Adamek, P.M., Wilson, M.R..: The evolution of a uranium province in northern Sweden. Phil. Trans. R. Soc. London A 291:355–368 (1979)

    Google Scholar 

  • Bowden, P., Whitley, J.E.: Rare-earth patterns in peralkaline and associated granites. Lithos, 7:15–21 (1974)

    Google Scholar 

  • Burman, J.-O., Boström, B., Boström, K.: Geochemical analyses by plasma spectroscopy. Geol. Fören. Stockh. Förh. 99:102–110 (1977)

    Google Scholar 

  • Burman, J.-O., Pontér, C., Boström, K.: Metaborate digestion procedure for inductively coupled plasma optical emission spectroscopy. Anal. Chem. 50:679–680 (1978)

    Google Scholar 

  • Burnol, L.: Different types of leucogranites and classification of the types of mineralization associated with acid magmatism in the north-western parts of the French Massif Central. In: Mineralization Associated with Acid Magmatism, M. Burnol, G. Tischendorf, Eds., Vol. 3, 191–204. Geol. Surv. Czech. Prague (1978)

  • Drake, K.M.: Geochemistry of tin, tungsten and molybdenum in Swedish Proterozoic granitoids; its potential use in regional mineral exploration. Phil. D. thesis. Medd. Stockh. Univ. Geol. Inst. 249:1–106 (1981)

    Google Scholar 

  • Groves, D.I., McCarthy, T.S.: Fractional crystallization and the origin of tin deposits in granitoids. Mineral. Dep. 13:11–26 (1978)

    Google Scholar 

  • Haffty, I., Noble, D.C.: Release and migration of molybdenum during the primary crystallization of peralkaline silicic volcanic rocks. Econ. Geol. 67:768–775 (1972)

    Google Scholar 

  • Isaksson, H.: K»taberget, geofysisk undersökning. Internal report FM 8204, Geol. Surv. Swed., Lule» (1982)

    Google Scholar 

  • Jahns, R.H., Burnham, W.C.: Experimental studies of pegmatite genesis: I. A model for the derivation and crystallization of grantitic pegmatites. Econ. Geol. 64:843–864 (1969)

    Google Scholar 

  • Krauskopf, K.: Introduction to geochemistry, 2nd ed., New York: McGraw-Hill (1979)

    Google Scholar 

  • Kuroda, P., Sandell, E.B.: Geochemistry of molybdenum. Geochim. et Cosmochim. Acta 6:35–63 (1954)

    Google Scholar 

  • Lawrence, G.: The use of Rb/Sr-ratios as a guide to mineralization in the Galway granite, Ireland. In: Geochemical Exploration, 353–370. Inst. Min. Metall. London (1974)

    Google Scholar 

  • Lundberg, B.: Aspects of the geology of the Skellefte field, northern Sweden. Geol. Fören. Stockh. Förh. 102:156–166 (1980)

    Google Scholar 

  • Masuda, A., Nakamura, N., Tanaka, T.: Fine structures of mutually normalized rare-earth patterns of chondrites. Geochim. Cosmochim. Acta 37:239–248 (1973)

    Google Scholar 

  • Mittlefehldt, D.W., Miller, C.F.: Geochemistry of Seetwater Wash Pluton, California: Implications for “anomalous” trace element behavior during differentiation of felsic magmas. Geochim. Cosmochim. Acta 47:109–124 (1983)

    Google Scholar 

  • Mutschler, F.E., Wright, E.G., Ludington, S., Abbott, J.T.: Granite molybdenite systems. Econ. Geol. 76:874–897 (1981)

    Google Scholar 

  • Noble, D.C., Smith, V.V., Peck, L.C.: Loss of halogens from crystallized and glassy silicic rocks. Geochem. et Cosmochim. Acta 31:215–223 (1967)

    Google Scholar 

  • dNoyes, H.J., Frey, F.A., Wones, D.R., A tale of two plutons: Geochemical evidence bearing on the origin and differentiation of the Red Lake and Eagle Peak Plutons, central Sierra Nevada, California. Jour. Geol. 91:487–509 (1983)

    Google Scholar 

  • Öhlander, B.: A molybdenite province in Norrbotten and Västerbotten, northern Sweden. Geol. Fören. Stockh. Förh. 105:229–234 (1983)

    Google Scholar 

  • Öhlander, B.: Geochemical characteristics of granites associated with Proterozoic molybdenite mineralization in northern Sweden. Chem. Geol., (in press)

  • Öhlander, B., Nisca, D.H.: Tectonic control of Precambrian molybdenite mineralization in northern Sweden. Econ. Geol. 80:505–512 (1985)

    Google Scholar 

  • Rickard, D.T., Zweifel, H.: Genesis of Precambrian sulphide ores, Skellefte district, Sweden. Econ. Geol. 70:255–274 (1975)

    Google Scholar 

  • Samarkin, G.I., Smarkina, E.Ya: Molybdenum in the granitic rocks of the principal granite belt of the southern Urals. Geochem. Int. 15:35–44 (1978)

    Google Scholar 

  • Sandell, E.B.: Colorimetric determination of traces of metals. New York: Interscience publishers 1958

    Google Scholar 

  • Shatkov, G., Shatkova, L.N., Guschin, E.N.: The distribution of uranium, thorium, fluorine, clorine, molybdenum and niobium in liparites and acid volcanic glasses. Geochem. Int. 7:1051–1063 (1970)

    Google Scholar 

  • Smirnova, N.V.: Age and space relations between granites and rare-metal metasomatites in the southern parts of the Baltic shield. In: Mineralization Associated with Acid Magmatism, M. Stemprok, Ed., Vol. 1, 119–122. Geol. Surv. Czech. Prague (1974)

    Google Scholar 

  • Statens Industriverk.: Berg och malm i Västerbottens län. SIND 1979: 9. Stockholm (1979) (Swedish)

  • Streckeisen, A.L.: Plutonic rocks: classification and nomenclature recommended by the IUGS subcomission on the Systematics of Igneous Rocks. Geotimes 18:26–30 (1973)

    Google Scholar 

  • Tauson, L.V., Kozlov, U.B.: Distribution functions and ratios of trace elements as estimators of the ore-bearing potential of granites. In: Geochemical Exploration, 37–44. Inst. Min. Metall. London 1974

    Google Scholar 

  • Thompson, M., Walsh, J.N.: A handbook of inductively coupled plasma spectrometry. London: Blackie and Lon Ltd 1983

    Google Scholar 

  • Tischendorf, G.: Geochemical and petrographic characteristics of silicic magmatic rocks associated with rare-metal mineralization. In: Mineralization Associated with Acid Magmatism, M. Stemprok, L. Burnol, G. Tischendorf, Eds., Vol. 2, 41–96. Geol. Surv. Czech. Prague 1977

    Google Scholar 

  • Walser, G., Einarsson, Ö.: The geological context of molybdenum occurrences in the southern Norrbotten region, northern Sweden. Geol. Rundsch. 71:213–229 (1982)

    CAS  PubMed  Google Scholar 

  • Westra, G., Keith, S.B.: Classification and genesis of stockwork molybdenum deposits. Econ. Geol. 76:844–873 (1981)

    Google Scholar 

  • Whalen, J.B.: Geology and geochemistry of the molybdenite showings of the Ackley City batholith, southeast Newfoundland. Can. J. Earth Sci. 17:1246–1258 (1980)

    Google Scholar 

  • Whalen, J.B.: The Ackley City Batholith, southeastern Newfoundland: evidence for crystal versus liquid-state fractionation. Geochim. Cosmochim. Acta 47:1443–1457 (1983)

    Google Scholar 

  • Wilson, M.R., Fallick, A.E.: The relationship between uraniumenriched granites and hydrothermal mineralization in northern Sweden. In: NEA-IAEA, OECD Symposium on uranium exploration methods, 293–306. Paris 1982

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Öhlander, B. Geochemistry of Proterozoic molybdenite — mineralized aplites in Northern Sweden. Mineral. Deposita 20, 241–248 (1985). https://doi.org/10.1007/BF00204280

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