Skip to main content
Log in

Tunable diode laser measurements of trace gases during the 1988 Polarstern cruise and intercomparisons with other methods

  • Published:
Journal of Atmospheric Chemistry Aims and scope Submit manuscript

Abstract

Measurements of NO2, HCHO, and H2O2 were made by the highly specific method of mid infra-red absorption spectroscopy using tunable diode lasers (TDLAS) during the 1988 Polarstern expedition. The TDLAS data are compared to those obtained during the cruise using less direct methods. Southern Hemisphere NO2 levels suggest nett photochemical destruction of O3 in the boundary layer. Northern Hemisphere HCHO averaged 0.47±0.2 ppbv; the HCHO measurements are used in a simple calculation to estimate OH noontime maxima of 3–6×106 cm-3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Arlander, D. W., Cronn, D. R., Farmer, J. C., Menzia, F. A., and Westberg, H. H., 1990, Gaseous oxygenated hydrocarbons in the remote marine atmosphere, J. Geophys. Res. 95, 16391–16403.

    Google Scholar 

  • Brüning, D. and Rohrer, F., 1990, Surface NO and NO2 mixing ratios measured between 30° N and 30° S in the Atlantic region, in G., Restelli and G., Angeletti (eds.), Physico-Chemical Behaviour of Atmospheric Pollutants, Kluwer Academic Publishers, Dordrecht, pp. 699–704.

    Google Scholar 

  • Callies, J., Platt, U., and Brauers, T., 1990, Measurements of photolysis frequencies of O3 and NO2 and ambient O3 concentration on the Polarstern cruise ANT VII/1, in G., Restelli and G., Angeletti (eds.), Physico-Chemical Behaviour of Atmospheric Pollutants, Kluwer Academic Publishers, Dordrecht, pp. 625–629.

    Google Scholar 

  • Carroll, M. A., Hastie, D. R., Ridley, B. A., Rodgers, M. O., Torres, A. L., Davis, D. D., Bradshaw, J. D., Sandholm, S. T., Schiff, H. I., Karecki, D. R., Harris, G. W., Mackay, G. I., Gregory, G. L., Condon, E. P., Trainer, M., Hubler, G., Montzka, D. D., Madronich, S., Albritton, D. L., Singh, H. B., Beck, S. M., Shipham, M. C. and Bachmeier, A. S., 1990, Aircraft measurements of NOx over the eastern Pacific Ocean and continental United States and implications for ozone production, J. Geophys. Res. 95, 10205–10233.

    Google Scholar 

  • Crutzen, P., 1979, The role of NO and NO2 in the chemistry of the troposphere and the stratosphere, Ann. Rev. Earth Planet. Sci. 7, 443–472.

    Google Scholar 

  • Harris, G. W., Mackay, G. I., Iguchi, T., Mayne, L. K., and Schiff, H. I., 1989a, Measurements of formaldehyde in the troposphere by tunable diode laser absorption spectroscopy, J. Atmos. Chem. 8, 119–137.

    Google Scholar 

  • Harris, G. W., Burrows, J. P., Klemp, D., and Zenker, T., 1989b, Tunable diode laser measurements in the tropical Atlantic boundary layer, International Conference on the Generation of Oxidants on Regional and Global Scales, Norwich U.K., July 3–7.

  • Jacob, P., Tavares, T. M., and Klockow, D., 1986, Methodology for the determination of gaseous hydrogen peroxide in ambient air, Fres. Z. Anat. Chem. 325, 359–364.

    Google Scholar 

  • Jacob, P. and Klockow, D., 1992, Hydrogen peroxide measurements in the Marine atmosphere, J. Atmos. Chem. 15, 353–360 (this issue).

    Google Scholar 

  • Kanakidou, M., Singh, H. B., Valentin, K. M., and Crutzen, P. J., 1991a, A 2-D study of ethane and propane in the troposphere, J. Geophys, Res., in press.

  • Kanakidou, M., Crutzen, P. J., Zimmermann, P. H., and Bonsang, B., 1991b, A 3 dimensional global study of the photochemistry of ethane and propane in the troposphere: Production and transport of organic nitrogen compounds, in H.van, Dopp (ed.), Air Pollution Modeling and its Application IX, Plenum, New York, in press.

    Google Scholar 

  • Koppmann, R., Johnen, F. J., Plass, Ch., and Rudolph, J., 1990, The latitudinal distribution of light non-methane hydroearbons over the mid Atlantic between 40° N and 30° S, in G., Restelli and G., Angeletti (eds.), Physioco-Chemical Behaviour of Atmospheric Pollutants, Kluwer Academic Publishers, Dordrecht, pp. 657–662.

    Google Scholar 

  • Koppmann, R., Bauer, R., Johnen, F. J., Plass, C., and Rudolph, J., 1992, The distribution of light non-methane hydrocarbons over the mid-Atlantic: results of the Polarstern cruise ANT VII/1, J. Atmos. Chem. 15, 215–234 (this issue).

    Google Scholar 

  • Leighton, P. A., 1961, The Photochemistry of Air Pollution, Academie Press, New York.

    Google Scholar 

  • Lowe, D. C. and Schmidt, U., 1983, Formaldehyde (HCHO) measurements in the nonurban atmosphere, J. Geophys. Res. 88, 10884–10858.

    Google Scholar 

  • Plass, Ch., Johnen, F. J., Koppmann, R., and Rudolph, J., 1990, The latitudinal distribution of NMHC in the Atlantic and their fluxes into the atmosphere, in G., Restelll and G., Angeletti (eds.), Physico-Chemical Behaviour of Atmospheric Pollutants, Kluwer Academic Publishers, Dordrecht, pp. 663–666.

    Google Scholar 

  • Platt, U., Callies, J., and Brauers, T., 1990, unpublished results: Due to technical difficulties, detection limits for IO and NO3 were at 10 ppt, neither species exceeded that limit.

  • Platt, U., Rudolph, J., Brauers, T., and Harris, G. W., 1992. Atmospheric measurements during Polarstern Cruise ANT VII/1, 54° N to 32° S: and overview, J. Atmos. Chem. 15, 203–214 (this issue).

    Google Scholar 

  • Schubert, B., Schmidt, U., and Ehhalt, D. H., 1988, Untersuchungen zum Nachweis und zur Chemie von Formaldehyde und Acetaldehyde in der unteren Troposphaere. KFA Bericht Jul-2257, December 1988.

  • Slemr, F., Harris, G. W., Hastie, D. R., Mackay, G. I., and Schiff, H. I., 1986, Measurement of gas phase hydrogen peroxide in air by tunable diode laser absorption spectroscopy, J. Geophys. Res. 91, 5371.

    Google Scholar 

  • Smit, H. G. J., Gilge, S., and Kley, D., 1990, The meridional distribution of ozone and water vapour over the Atlantic Ocean between 30° S and 50° N in September/October 1988, in G., Restelli and G., Angeletti (eds.), Physico-Chemical Behaviour of Atmospheric Pollutants, Kluwer Academic Publishers, Dordrecht, pp. 630–637.

    Google Scholar 

  • Zafariou, O. C., Alford, J., Herrea, M., Peltzer, E. T., and Gagosian, R. B., 1980, Formaldehyde in remote marine air and rain: Flux measurements and estimates, Geophys. Res. Lett. 7, 341–344.

    Google Scholar 

  • Zenker, T., 1990, Absorptionsspektroskopische Messungen troposphärischer Spurengase in der bodennahen Grenzschicht über dem Atlantik. PhD Thesis, University of Mainz.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Harris, G.W., Klemp, D., Zenker, T. et al. Tunable diode laser measurements of trace gases during the 1988 Polarstern cruise and intercomparisons with other methods. J Atmos Chem 15, 315–326 (1992). https://doi.org/10.1007/BF00115401

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00115401

Key words

Navigation