Abstract
Two new methylsilylsulfides are synthesized. Propeller-like chirality is described for triaryloxysilanethiol and its methyl derivative. S-methylation of the silanethiol lowers the overall symmetry of the unit cell.
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Wolf C (2008) Dynamic Stereochemistry of Chiral Compounds. Principles and Applications. The Royal Society of Chemistry, Cambridge
Chojnacki J, Ciborska A, Wojnowski W (2008) Acta Crystallogr C64:m240
Pladzyk A, Baranowska K, Gudat D, Godlewska S, Wieczerzak M, Chojnacki J, Bulman M, Januszewicz K, Dołȩga A (2011) Polyhedron 30:1191
Dołe̹ga A, Marynowski W, Baranowska K, Śmiechowski M, Stangret J (2012) Inorg Chem 51:836
Sheldrick GM (2008) Acta Crystallogr A64:112
te Velde G, Bickelhaupt FM, van Gisbergen SJA, Fonseca Guerra C, Baerends EJ, Snijders JG, Ziegler T (2001) J Comput Chem 22:931
Fonseca Guerra C, Snijders JG, te Velde G, Baerends EJ (1998) Theor Chem Account 99:391
Baerends EJ, Ziegler T, Autschbach J, Bashford D, Bérces A, Bickelhaupt FM, Bo C, Boerrigter PM, Cavallo L, Chong DP, Deng L, Dickson RM, Ellis DE, van Faassen M, Fan L, Fischer TH, Fonseca Guerra C, Franchini M, Ghysels A, Giammona A, van Gisbergen SJA, Götz AW, Groeneveld JA, Gritsenko OV, Grüning M, Gusarov S, Harris FE, van den Hoek P, Jacob CR, Jacobsen H, Jensen L, Kaminski JW, van Kessel G, Kootstra F, Kovalenko A, Krykunov MV, van Lenthe E, McCormack DA, Michalak A, Mitoraj M, Morton SM, Neugebauer J, Nicu VP, Noodleman L, Osinga VP, Patchkovskii S, Pavanello M, Philipsen PHT, Post D, Pye CC, Ravenek W, Rodríguez JI, Ros P, Schipper PRT, Schreckenbach G, Seldenthuis JS, Seth M, Snijders JG, Solà M, Swart M, Swerhone D, te Velde G, Vernooijs P, Versluis L, Visscher L, Visser O, Wang F, Wesolowski TA, van Wezenbeek EM, Wiesenekker G, Wolff SK, Woo TK, Yakovlev AL ADF2013, SCM,Theoretical Chemistry, Vrije Universiteit, Amsterdam, The Netherlands. http://www.scm.com
Rocha GB, Freire RO, Simas AM, Stewart JJP (2006). J Comput Chem 27:1101
Baker J (1986) J. Comput. Chem 7:385
Piękoś R, Wojnowski W (1962) Z Anorg Allg Chem 318:212
Marynowski W, Klucznik T, Baranowska K, Dołe̹ga A, Wojnowski W (2010) Z Anorg Allg Chem 636:685
Gust D, Mislow K (1973) J Am Chem Soc 95:1535
Andreetti GD, Bocelli G, Calestani G, Sgarabotto P (1984) J Organomet Chem 273:31
Jabłońska A, Ponikiewski Ł, Ejsmont K, Herman A, Dołe̹ga A (2013) J Mol Struct 1054-1055:359
Bassindale AR, Lau JC-Y, Taylor PG (1995) J Organomet Chem 499:137
Olszewska T, Sikorski A, Herman A, Połoński T (2013) Org Biomol Chem 11:7522
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Herman, A., Godlewska, S., Ponikiewski, Ł. et al. Propeller-Like Chirality of Methyl-Tris (2,6-diisopropylphenoxy)Silylsulfide. Silicon 8, 105–110 (2016). https://doi.org/10.1007/s12633-014-9207-1
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DOI: https://doi.org/10.1007/s12633-014-9207-1