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Invited paper: Recent development of bulk-type solid-state rechargeable lithium batteries with sulfide glass-ceramic electrolytes

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Abstract

The recent development of bulk-type solid-state rechargeable lithium batteries with sulfide glass-ceramics as a solid electrolyte was reviewed. Sulfide glasses and glass-ceramics in the system Li2S-P2S5 have an advantage of high conductivity, wide electrochemical window and low grain-boundary resistance. Bulk-type solid-state batteries composed of compressed powder layers of electrode and electrolyte were fabricated with Li2S-P2S5 glass-ceramic electrolytes. Formation of a favorable solid-solid interface between electrode and electrolyte is a key to achieving excellent performance in solid-state batteries. The mechanochemical preparation of nanocomposite electrodes and surface modification of active materials by softening of the electrolyte, or PLD coating, were useful for increasing the electrode-electrolyte contact area and improving battery performance.

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Authors and Affiliations

  1. Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Gakuen-cho, Naka-ku, Sakai, Osaka, 599-8531, Japan

    Akitoshi Hayashi & Masahiro Tatsumisago

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  1. Akitoshi Hayashi
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  2. Masahiro Tatsumisago
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Correspondence to Akitoshi Hayashi.

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Hayashi, A., Tatsumisago, M. Invited paper: Recent development of bulk-type solid-state rechargeable lithium batteries with sulfide glass-ceramic electrolytes. Electron. Mater. Lett. 8, 199–207 (2012). https://doi.org/10.1007/s13391-012-2038-6

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  • DOI: https://doi.org/10.1007/s13391-012-2038-6

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