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Multicommuted Flow Analysis Procedure for Total Polyphenols Determination in Wines Employing Chemiluminescence Detection

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Abstract

A flow procedure based on a multicommuted flow analysis process for the determination of polyphenolic compounds in wine employing chemiluminescence as detection technique is described. The method was based on the reaction of hypochlorite with gallic acid, the remaining hypochlorite reacted with luminol in an alkaline medium generating electromagnetic radiation with maximum emission at 425 nm. The luminescence intensity presented an inverse relationship to the concentration of polyphenol compounds, which was monitored employing a homemade luminometer. The flow system manifold was designed to use solenoid mini-pumps for propelling fluids in order to obtain a setup of downsized dimension. After setting the variables control of the flow system and the concentrations of the reagent, the following features were achieved: a linear response ranging from 10 to 100 mg L−1 gallic acid (R 2 = 0.997), a relative standard deviation of 3.4 (n = 11) for a 50 mg L−1 gallic acid solution, a detection limit of 6.6 mg L−1, a sampling throughput of 180 determination h−1, and a waste generation of 1.1 mL per determination.

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Acknowledgments

The authors acknowledge the financial support from CAPES, CNPq, and FACEPE. MF Andrade thanks CNPq for the fellowship.

Conflict of Interest

Marcelo Farias de Andrade declares that he has no conflict of interest. Suelle Gisian Farias de Assis declares that she has no conflict of interest. Ana Paula Silveira Paim declares that she has no conflict of interest. Boaventura Freire dos Reis declares that he has no conflict of interest. This article does not contain any studies with human or animal subjects.

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Authors and Affiliations

  1. Departamento de Química Fundamental, Universidade Federal de Pernambuco—Centro de Ciências Exatas e da Natureza, Av. Jornalista Aníbal Fernandes, s/n—Cidade Universitária, 50740-560, Recife, PE, Brazil

    Marcelo Farias de Andrade, Suelle Gisian Farias de Assis & Ana Paula Silveira Paim

  2. Universidade de São Paulo - Centro de Energia Nuclear na Agricultura, PO Box 96, 13400-970, Piracicaba, SP, Brazil

    Boaventura Freire dos Reis

Authors
  1. Marcelo Farias de Andrade
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  2. Suelle Gisian Farias de Assis
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  3. Ana Paula Silveira Paim
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  4. Boaventura Freire dos Reis
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Corresponding author

Correspondence to Ana Paula Silveira Paim.

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de Andrade, M.F., de Assis, S.G.F., Paim, A.P.S. et al. Multicommuted Flow Analysis Procedure for Total Polyphenols Determination in Wines Employing Chemiluminescence Detection. Food Anal. Methods 7, 967–976 (2014). https://doi.org/10.1007/s12161-013-9699-0

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  • DOI: https://doi.org/10.1007/s12161-013-9699-0

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