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Synthesis, photophysical and preliminary investigation of the dye-sensitized solar cells properties of functionalized anthracenyl-based bipyridyl and phenanthrolyl Ru(II) complexes

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Abstract

Four new amphiphilic ligands: 4-(2,3-dimethylacrylic acid)-2,2′-bipyridine (L1), 4-(9-anthracenyl-10-(2,3-dimethylacrylic acid)-2,2′-bipyridine (L2), 5-(2,3-dimethylacrylic acid)-1,10-phenanthroline (L3) and 5-(9-anthracenyl-10-(2,3-dimethylacrylic acid)-1,10-phenanthroline (L4), with their corresponding homonuclear ruthenium(II) complexes formulated as cis-[Ru-(L1)3(PF6)2] (C1), cis-[Ru-(L2)3(PF6)2] (C2), cis-[Ru-(L3)3(PF6)2] (C3) and cis-[Ru-(L4)3(PF6)2] (C4), have been synthesized and characterized by elemental analysis, 1H- and 13C- NMR, FT-IR, UV-Vis and photoluminescence spectroscopy. The complexes exhibit broad and intense metal-to-ligand charge transfer (MLCT) transition bands in the visible region (400–700 nm), and red light emitting properties at room temperature. By comparison however, complexes C1 and C2 bipyridine moiety gave lower molar absorptivity coefficient at relatively similar wavelength characteristics (410–520 nm) when compared to C3 and C4 with phenanthroline based molecules. Cyclic voltammograms of the complexes revealed complex C4 with most reduction potential which might be due to increase in the conjugation of the anthracene functionalized units. Preliminary investigation of the solar cell efficiency of the complexes on TiO2 nanocrystalline films gave the best result with efficiency of 0.103% for C1 under illumination at 1000 W/m2 AM 1.5. Electrochemical impedance spectroscopy (EIS) technique however, revealed the charge transfer resistances (Rct) of the electrons on the TiO2 semiconductor.

Ruthenium(II) complexes of functionalized bipyridine and phenanthroline were synthesized and characterized by spectroscopic techniques. The complexes showed intense charge transfer transition and their electrochemical properties were studied. Preliminary investigations were carried out to study their potential as sensitizers for dye sensitized solar cells.

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References

  1. Kay A and Grätzel M 1993 J. Phys. Chem. 117 6272

    Article  Google Scholar 

  2. Nazeeruddin Md K, Humphry-Baker R, Grätzel M and Murrer B A 1998 Chem. Commun. 719

  3. Sayama K, Sugino M, Sugihara H, Abe Y and Arakawa H 1998 Chem. Lett. 753

  4. Ferrere S, Zaban A and Gregg B A 1997 J. Phys. Chem. B 101 4490

    Article  CAS  Google Scholar 

  5. O’Regan B and Grätzel M 1991 Nature 353 737

    Article  Google Scholar 

  6. Nazeeruddin Md K, Kay A, Rodicio I, Humphry-Baker R, Muller E, Liska P, Vlachopoulos N and Grätzel M 1993 J. Am. Chem. Soc. 115 6382

    Article  Google Scholar 

  7. Hara K, Sugihara H, Singh L P, Islam A, Kator R, Yanagida M, Sayama K, Murata S and Arakawa H 2001 J. Photochem. Photobiol. A: Chem. 145 117

    Article  CAS  Google Scholar 

  8. Nazeeruddin Md K, Bessho T, Le Cevey, Ito S, Klein C, De Angelis F, Fantacci S, Comte P, Liska P, Imai H and Grätzel M 2007 J. Photochem. Photobiol. A: Chem. 185 331

    Article  CAS  Google Scholar 

  9. Pearson P, Bond A M, Deacon G B, Forsyth C and Spiccia L 2008 Inorg. Chim. Acta 361 601

    Article  CAS  Google Scholar 

  10. Funaki T, Yanagida M, Onozawa-Komatsuzaki N, Kawanishi Y, Kasuga K and Sugihara H 2009 Solar Energy Mat. Solar Cells 93 729

    Article  CAS  Google Scholar 

  11. Li C, Yang X, Chen R, Pan J, Tian H, Zhu H, Wang X, Hagfeldt A and Sun L 2007 Solar Energy Mat. Solar Cells 91 1863

    Article  CAS  Google Scholar 

  12. Wang X F, Fujii R, Ito S, Koyama Y, Yamano Y, Ito M, Kitamura T and Yanagida S 2005 Chem. Phys. Lett. 416 1

    Article  CAS  Google Scholar 

  13. Song A, Zhang H, Zhang M and Shen T 1999 Dyes Pigments 42 149

    Article  CAS  Google Scholar 

  14. Mosurkal R, He J, Yang K, Samuelson L A and Kumar J 2004 J. Photochem. Photobiol. A 168 191

    Article  CAS  Google Scholar 

  15. Wang P, Zakeeruddin S M, Moser J E, Humphry-Baker R, Comte P, Aranyos V, Hagfeldt A, Nazeeruddin M K and Grätzel M 2004 Adv. Mater. 16 1806

    Article  CAS  Google Scholar 

  16. Chen C Y, Wu S J, Wu C G, Chen J G and Ho K C 2006 Angew. Chem. Int. Ed. 45 5822

    Article  CAS  Google Scholar 

  17. Yamagushi T, Yanagida M, Kator R, Sugihara H and Arakawa H 2004 Chem. Lett. 33 986

    Article  Google Scholar 

  18. Goze C, Kozlov D V, Castellano F N, Suffert J and Ziessel R 2003 Tetrahedron 44 8713

    Article  CAS  Google Scholar 

  19. Jiang K J, Masaki N, Xia J B, Noda S and Yanagida S 2006 Chem. Commun. 2460

  20. Kukrek A, Wang D, Hou Y, Zong R and Thummel R 2006 Inorg. Chem. 45 10131

    Article  CAS  Google Scholar 

  21. Yanagida M, Yamagushi T, Kurashige M, Hara K, Kator R, Sugihara H and Arakawa H 2003 Inorg. Chem. 42 7921

    Article  CAS  Google Scholar 

  22. Sauve G, Cass M E, Coia G, Doig S J, Lauermann I, Pomykal K E and Lewis N S 2000 J. Phys. Chem. 104 6831

    Google Scholar 

  23. Argazzi R, Bignozzi C A, Heimer T A, Castellano F N and Meyer G J 1994 Inorg. Chem. 33 5741

    Article  CAS  Google Scholar 

  24. Heimer T A, Heilweil E J, Bignozzi C A and Meyer G J 2000 J. Phys. Chem. A 104 4256

    Article  CAS  Google Scholar 

  25. Polo A S, Itokazu M-K and Iha N Y M 2004 Coord. Chem. Rev. 248 1343

    Article  CAS  Google Scholar 

  26. Ajayagosh A, Carol P and Sreejith S 2005 J. Am. Chem. Soc. 127 14962

    Article  Google Scholar 

  27. Li Y, Shi L-X, Qin L, Qu L-L, Jing C, Lan M, James T D and Long Y-T 2011 Chem. Commun. 47 4361

    Article  CAS  Google Scholar 

  28. Sreejith S, Divya K P, Manojkumar T K and Ajayagosh A 2011 Chem. Asian J. 6 430

    Article  CAS  Google Scholar 

  29. Sreejith S, Divya K P and Ajayagosh A 2008 Chem. Commun. 44 2903

    Article  Google Scholar 

  30. Li Y, Shi L-X, Qin L and Gratzel M 2011 Nano Lett. 11 5501

    Article  Google Scholar 

  31. Guo L, Deng J, Zhang L, Xiu Q, Wei G and Zhong C 2012 Dyes Pigm. 92 1062

    Article  CAS  Google Scholar 

  32. Vyas P, Bhatt A K, Ramachandraiah G and Bedekar A V 2003 Tetrahedron Lett. 44 4085

    Article  CAS  Google Scholar 

  33. Evans I P, Spencer A and Wilkinson G 1973 J. Chem. Soc. Dalton Trans. 204

  34. Mitsopoulou C A, Veroni I, Philippopoulos A I and Falaras P 2007 J. Photochem. Photobiol. A: Chem. 191 6

    Article  CAS  Google Scholar 

  35. Adeloye A O and Ajibade P A 2010 Int. J. Mol. Sci. 11 3158

    Article  CAS  Google Scholar 

  36. Gunzler H and Gremlich H 2002 Infrared spectroscopy — An introduction; Weinheim, Germany: WILEY-VCH Verlag GmbA

  37. Sun S S and Lees A 2001 J. Inorg. Chem. 3154

  38. Ali S, Arta S, Sina H, Siguang C, Pierre G P and Sylvie M 2008 J. New Mat. Electrochem. Systems 11 281

    Google Scholar 

  39. Ruhle S, Greenshtein M, Chen S G, Merson A, Pizen H, Sukenik S, Cahen D and Zaban A 2005 J. Phys. Chem. B 109 18907

    Article  Google Scholar 

  40. Hoshikawa T, Kikuchi R and Egushi K 2006 J. Electrochem. Chem. 589 59

    Google Scholar 

  41. Roy M S, Balraju P, Kumar M and Sharma G D 2008 Sol. Energy Mater. Sol. Cells. 92 1516

    Article  CAS  Google Scholar 

  42. Fey G T K, Chen J G, Subramanian V and Osaka T 2002 J. Power Sources 112 384

    Article  CAS  Google Scholar 

  43. Van de Lagemaat J, Park N G and Frank A J 2000 J. Phys. Chem. B. 104 2044

    Article  Google Scholar 

Download references

Acknowledgements

We are grateful to the South African National Energy Research Institute (SANERI) and Govan Mbeki Research Centre and University of Fort Hare, Alice, South Africa for financial support. AOA acknowledges Obafemi Awolowo Unversity, Ile-Ife, Nigeria for study leave.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science and Agriculture, University of Fort Hare, PMB X1314, Alice, 5700, South Africa

    ADEWALE O ADELOYE & PETER A AJIBADE

  2. CSIR Materials Science and Manufacturing, PO Box 395, Pretoria, 0001, South Africa

    FRANCES R CUMMINGS & LUKAS J LE ROUX

  3. Fort Hare Institute of Technology, University of Fort Hare, PMB X1314, Alice, 5700, South Africa

    SAMPSON N MAMPHWELI & EDSON L MEYER

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  1. ADEWALE O ADELOYE
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  2. PETER A AJIBADE
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Correspondence to PETER A AJIBADE.

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ADELOYE, A.O., AJIBADE, P.A., CUMMINGS, F.R. et al. Synthesis, photophysical and preliminary investigation of the dye-sensitized solar cells properties of functionalized anthracenyl-based bipyridyl and phenanthrolyl Ru(II) complexes. J Chem Sci 125, 17–27 (2013). https://doi.org/10.1007/s12039-012-0349-7

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  • DOI: https://doi.org/10.1007/s12039-012-0349-7

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