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Tin Coatings Electrodeposited from Sulfonic Acid-Based Electrolytes: Tribological Behavior

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Abstract

A high efficiency methane sulfonic acid electrolyte used for tin electrodeposition was studied, and the properties of the resulting deposits were compared to those of tin coatings obtained from an industrial phenol sulfonic acid electrolyte. Cyclic voltammetry was used to study the effect of organic additives on the reduction process to define the composition of the electrolytic bath. Thick tin electrodeposits were obtained on rotating cylinder steel electrodes, and their surface morphology, preferred crystal orientation, surface roughness, micro hardness, and tribological behavior were measured. Smooth, adherent, and bright tin coatings were obtained from the methane sulfonic acid electrolyte, which differed in morphology and texture from tin electrodeposited from the industrial bath. Influence of organic additives on preferred crystal orientation of the coatings was found to be stronger than changing the supporting sulfonic acid type. Tribological tests showed that the two types of deposits have a similar coefficient of friction. However, tin coatings obtained from methane sulfonic electrolytes presented a lower wear resistance and underwent galling at lower loads.

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Acknowledgments

The authors would like to thank the Comisión de Investigaciones Científicas de la Provincia de Buenos Aires (CICPBA), Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Universidad Nacional de La Plata (UNLP) and Universidad Nacional del Sur (UNS) for the financial support provided. This research was partially financed by SIDERCA S.A.I.C. (Tenaris) through a collaboration agreement with CONICET.

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Authors and Affiliations

  1. Centre for Paints and Coatings Development, CICBA-CONICET, Av. 52 e/121 y 122, La Plata, Argentina

    L. N. Bengoa & W. A. Egli

  2. School of Engineering, Universidad Nacional de La Plata, Av. 1 y 47, La Plata, Argentina

    L. N. Bengoa

  3. Tribology Group, Engineering Department, Universidad Nacional del Sur, CONICET, Av. Alem 1253, 1° Piso, 8000, Bahía Blanca, Buenos Aires, Argentina

    W. R. Tuckart, N. Zabala & G. Prieto

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  1. L. N. Bengoa
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Correspondence to L. N. Bengoa.

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Bengoa, L.N., Tuckart, W.R., Zabala, N. et al. Tin Coatings Electrodeposited from Sulfonic Acid-Based Electrolytes: Tribological Behavior. J. of Materi Eng and Perform 24, 2274–2281 (2015). https://doi.org/10.1007/s11665-015-1503-4

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