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Stereoselective Synthesis of Alicylic Amines

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Abstract

The hydrogenation 4-alkylanilines over Rh/silica catalysts display an antipathetic particle size effect suggesting that the active site is a terrace face. The effect of the solvent on product cis:trans ratio was related to polar solvents stabilising an imine intermediate. The products inhibited the reaction due to their increased basicity which allowed a strong metal–nitrogen interaction.

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Authors and Affiliations

  1. Centre for Catalysis Research, WestCHEM, Department of Chemistry, University of Glasgow, Glasgow, G12 8QQ, Scotland, UK

    Kristoffer F. Graham, Kenneth T. Hindle, S. David Jackson, David J. M. Williams & Stefan Wuttke

Authors
  1. Kristoffer F. Graham
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  2. Kenneth T. Hindle
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  3. S. David Jackson
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  4. David J. M. Williams
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  5. Stefan Wuttke
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Correspondence to S. David Jackson.

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Graham, K.F., Hindle, K.T., David Jackson, S. et al. Stereoselective Synthesis of Alicylic Amines. Top Catal 53, 1121–1125 (2010). https://doi.org/10.1007/s11244-010-9544-2

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