Space Science Reviews

, Volume 156, Issue 1, pp 13–72

Reaction Networks for Interstellar Chemical Modelling: Improvements and Challenges


    • Observatoire Aquitain des Sciences de l’UniversUniversité de Bordeaux
    • Laboratoire d’Astrophysique de BordeauxCNRS, UMR 5804
  • I. W. M. Smith
    • University Chemical Laboratories
  • E. Herbst
    • Departments of Physics, Astronomy, and ChemistryThe Ohio State University
  • J. Troe
    • Institut für Physikalische ChemieUniversität Göttingen
    • Max-Planck-Institut für Biophysikalische Chemie
  • W. Geppert
    • Department of PhysicsUniversity of Stockholm
  • H. Linnartz
    • Sackler Laboratory for Astrophysics, Leiden ObservatoryUniversity of Leiden
  • K. Öberg
    • Sackler Laboratory for Astrophysics, Leiden ObservatoryUniversity of Leiden
    • Harvard-Smithsonian Center for Astrophysics
  • E. Roueff
    • Universit Paris 7 and Observatoire de Paris, LUTH, UMR 8102 CNRS
  • M. Agúndez
    • Observatoire de Paris-MeudonLUTH
  • P. Pernot
    • Univ Paris-Sud, Laboratoire de Chimie PhysiqueUMR 8000
    • CNRS
  • H. M. Cuppen
    • Sackler Laboratory for Astrophysics, Leiden ObservatoryUniversity of Leiden
  • J. C. Loison
    • Institut des Sciences Moléculaires, CNRS UMR 5255Université Bordeaux I
  • D. Talbi
    • Université Montpellier II—GRAALCNRS-UMR 5024
Open AccessArticle

DOI: 10.1007/s11214-010-9712-5

Cite this article as:
Wakelam, V., Smith, I.W.M., Herbst, E. et al. Space Sci Rev (2010) 156: 13. doi:10.1007/s11214-010-9712-5


We survey the current situation regarding chemical modelling of the synthesis of molecules in the interstellar medium. The present state of knowledge concerning the rate coefficients and their uncertainties for the major gas-phase processes—ion-neutral reactions, neutral-neutral reactions, radiative association, and dissociative recombination—is reviewed. Emphasis is placed on those key reactions that have been identified, by sensitivity analyses, as ‘crucial’ in determining the predicted abundances of the species observed in the interstellar medium. These sensitivity analyses have been carried out for gas-phase models of three representative, molecule-rich, astronomical sources: the cold dense molecular clouds TMC-1 and L134N, and the expanding circumstellar envelope IRC +10216. Our review has led to the proposal of new values and uncertainties for the rate coefficients of many of the key reactions. The impact of these new data on the predicted abundances in TMC-1 and L134N is reported. Interstellar dust particles also influence the observed abundances of molecules in the interstellar medium. Their role is included in gas-grain, as distinct from gas-phase only, models. We review the methods for incorporating both accretion onto, and reactions on, the surfaces of grains in such models, as well as describing some recent experimental efforts to simulate and examine relevant processes in the laboratory. These efforts include experiments on the surface-catalyzed recombination of hydrogen atoms, on chemical processing on and in the ices that are known to exist on the surface of interstellar grains, and on desorption processes, which may enable species formed on grains to return to the gas-phase.


Astrochemistry Reaction rate coefficients Gas-phase chemistry Grain-surface chemistry Chemical modelling Uncertainty propagation Sensitivity analysis

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© The Author(s) 2010