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Oxidation of Alcohols with Tetramethylammonium Fluorochromate in Aceticoi Acid

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Abstract

A number of alcohols were oxidized to the corresponding carbonyl compounds in excellent yields using tetramethylammonium fluorochromate in acetic acid. The oxidant takes up two electrons, the reaction follows first-order kinetics with respect to the oxidant under pseudofirst-order conditions, and the concentration of alcohols changes according to the Michaelis-Menten dependence.

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Authors and Affiliations

  1. Department of Chemistry, Azad Islamic University, Tonekaboon Campus, Iran

    B. Sadeghy

  2. Department of Chemistry, Faculty of Science, Azad Islamic University, Saveh Campus, Iran

    Sh. Ghammami

Authors
  1. B. Sadeghy
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  2. Sh. Ghammami
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Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 12, 2005, pp. 1975–1977.

Original Russian Text Copyright © 2005 by Sadeghy, Ghammami.

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Sadeghy, B., Ghammami, S. Oxidation of Alcohols with Tetramethylammonium Fluorochromate in Aceticoi Acid. Russ J Gen Chem 75, 1886–1888 (2005). https://doi.org/10.1007/s11176-006-0008-0

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  • DOI: https://doi.org/10.1007/s11176-006-0008-0

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