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Electrocatalytic reduction of aryldichlorophosphines with the (2,2′-bipyridine)nickel complexes

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Abstract

The reduction of aryldichlorophosphines in organic solvents was studied by cyclic voltammetry, preparative electrolysis, and chemical reduction. The reaction of the electrochemically generated (2,2′-bipyridine)nickel(0) complexes with aryldichlorophosphines PhPCl2 and tippPCl2 (tipp is 2,4,6-triisopropylphenyl) proceeds through the formation of highly reactive organophosphorus intermediates, whose reactions with diphenylacetylene and hex-1-ene afford phosphirene and phosphirane heterocycles, respectively.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    D. G. Yakhvarov, R. M. Kagirov, Yu. H. Budnikova, Yu. S. Ganushevich & O. G. Sinyashin

  2. Institute of Inorganic Chemistry, Leipzig University, 29 Johannisallee, D-04103, Leipzig, Germany

    E. Hey-Hawkins

Authors
  1. D. G. Yakhvarov
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  2. E. Hey-Hawkins
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  3. R. M. Kagirov
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  4. Yu. H. Budnikova
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  5. Yu. S. Ganushevich
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  6. O. G. Sinyashin
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Correspondence to D. G. Yakhvarov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 901–907, May, 2007.

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Yakhvarov, D.G., Hey-Hawkins, E., Kagirov, R.M. et al. Electrocatalytic reduction of aryldichlorophosphines with the (2,2′-bipyridine)nickel complexes. Russ Chem Bull 56, 935–942 (2007). https://doi.org/10.1007/s11172-007-0142-9

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  • DOI: https://doi.org/10.1007/s11172-007-0142-9

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