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Synthesis and 1-butene hydrogenation activity of platinum decorated bamboo-shaped multiwall carbon nanotubes

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Abstract

Bamboo-shaped carbon nanotubes (BCNT) were prepared from three different amines on supported iron (Fe) and nickel (Ni) catalysts by catalytic chemical vapor deposition. The main factors governing product morphology and defect site density were identified. Post-synthetic oxidative functionalization was used to add carboxyl groups to the nanotubes, and then platinum (Pt) nanoparticles were deposited on the surface by the in situ reduction of a platinum salt. The average Pt nanoparticle diameter was found to be affected by the extent of surface functionalization. The catalytic performance of the synthesized Pt/BCNT samples were examined in the hydrogenation of 1-butene, in order to show that the catalytic activity of the bamboo like carbon nanotube supported Pt catalyst is similar to the conventional Pt catalysts in heterogeneous catalytic hydrogenation. The best overall performance was achieved when the bamboo-shaped nanotube support was synthesized on 5 wt% Fe/Al(OH)3 catalyst from triethylamine and decorated with 5 wt% platinum nanoparticles.

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Acknowledgments

This research was partially carried out in the framework of the Center of Applied Materials Science and Nano-Technology at the University of Miskolc. The financial support of the OTKA NN 110676 and OTKA K 112531 Projects is acknowledged.

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Authors and Affiliations

  1. Institute of Chemistry, University of Miskolc, Miskolc-Egyetemváros, 3515, Hungary

    László Vanyorek, Olivér Bánhidi & János Lakatos

  2. Institute of Mineralogy and Geology, University of Miskolc, Miskolc-Egyetemváros, 3515, Hungary

    Ferenc Kristály

  3. Wanhua BorsodChem Zrt, Bolyaitér 1, Kazincbarcika, 3700, Hungary

    Andrea Mihalkó

  4. Department of Applied & Environmental Chemistry, University of Szeged, Rerrich B. tér 1, Szeged, 6720, Hungary

    Ákos Kukovecz & Zoltán Kónya

  5. MTA-SZTE “Lendület” Porous Nanocomposites Research Group, Rerrich B. tér 1, Szeged, 6720, Hungary

    Ákos Kukovecz

  6. MTA-SZTE Reaction Kinetics and Surface Chemistry Research Group, Rerrich B. tér 1, Szeged, 6720, Hungary

    Zoltán Kónya

Authors
  1. László Vanyorek
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Correspondence to László Vanyorek.

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Vanyorek, L., Kristály, F., Mihalkó, A. et al. Synthesis and 1-butene hydrogenation activity of platinum decorated bamboo-shaped multiwall carbon nanotubes. Reac Kinet Mech Cat 116, 371–383 (2015). https://doi.org/10.1007/s11144-015-0906-4

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  • DOI: https://doi.org/10.1007/s11144-015-0906-4

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