Abstract
Several catalytic systems containing Ni/Mg/Al/Ce were synthesized from nitrates of Ni2+, Mg2+, Al3+ and Ce3+ cations with M2+/M3+ = 2 ratios by means of the carbonate co-precipitation method and subsequent calcination at 800 °C. Atomic absorption spectroscopy, X-ray diffraction (XRD), FT-IR spectroscopy, BET, temperature programmed reduction and scanning electron microscopy were used in order to describe the structural, morphological and surface characteristics of the solids completely. The effect of substitution/incorporation of Al by Ce and/or Mg on NiAl sample was studied. XRD analyses confirm that on Al-containing samples (NiAl, NiMgAl), the formation of the precursors layered double hydroxide structure. On the other hand, on cerium containing samples (NiCe, NiMgCe), poorly resolved diffractograms were observed what can be explained by the large radius of cerium. The catalysts were evaluated in the reaction of CO2 reforming of methane at 750 °C. NiCe and NiMgAl catalysts exhibit higher activity and a H2/CO ratio of almost 1. NiAl and NiMgCe samples showed lower conversions and a CH4/CO2 ratio <1, indicating the occurrence of reverse water gas shift reaction.
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Tsyganok AI, Suzuki K, Hamakawa S, Takehira K, Hayakawa T (2001) Catal Lett 77:75–86
Batiot-Dupeyrat C, Sierra GA, Mondragon F, Barrault J, Tatibouet JM (2005) Catal Today 474:107–108
Lemonidou AA, Vasalos IA (2002) Appl Catal A 228:227–235
Martinez R, Romero E, Guimon C, Bilbao R (2004) Appl Catal A 274:139–149
Zhan Y, Li D, Nishida K, Shishido T, Oumi Y, Sano T, Takehira K (2009) Appl Clay Sci 45:147–154
Takehira K, Shishido T, Wang P, Kosaka T, Takaki K (2004) J Catal 221:43–54
Rostrup-Nielsen JR, Sehested J, Norskov JK (2002) Adv Catal 47:65–139
Takheira K (2002) Catal Surv Japan 6:19–32
Araujo GC, Lima SM, Assaf JM, Pena MA, Fierro JLG, Rangel MC (2008) Catal Today 133:129–135
Shishido T, Sukenobu M, Morioka H, Furukawa R, Shirahase H, Takehira K (2001) Catal Lett 73:21–26
Vaccari A (1998) Catal Today 41:53–71
Tsyganok AI, Tsunoda T, Hamakawa S, Suzuki K, Takehira K, Hayakawa T (2003) J Catal 213(2):191–203
Takehira K (2009) J Nat Gas Chem 18:237–259
Li D, Nishida K, Zhan Y, Shishido T, Oumi Y, Sano T, Takehira K (2009) Appl Clay Sci 43:49–56
Hou Z, Yashima T (2004) Appl Catal A 261:205–209
Takehira K, Shishido T, Shoro D, Murakami K, Honda M, Kawabata T, Takaki K (2004) Catal Commun 5:209–213
Wang N, Chu W, Zhang T, Zhao XS (2012) Int J Hydrogen Energy 37:19–30
Yu X, Wanga N, Chu W, Liu M (2012) Chem Eng J 209:623–632
Vizcarno AJ, Lindo M, Carrero A, Calles JA (2012) Int J Hydrogen Energy 37:1985–1992
Bae JW, Kim AR, Baek SC, Jun KW (2011) Reac Kinet Mech Cat 104:377–388
Munoz M, Moreno S, Molina R (2012) Int J Hydrogen Energy 37:18827–18842
Kim DK, Stöwe K, Müller F, Maier WF (2007) J Catal 247:101–111
Centeno MA, Paulis M, Montes M, Odriozola JA (2002) Appl Catal A 234:65–78
Daza CE, Gallegob J, Andre J, Moreno S, Mondrago F, Moreno S, Molina R (2008) Catal Today 133–135:357–366
Daza CE, Gallego J, Mondragon F, Moreno S, Molina R (2010) Fuel 89:592–603
Daza CE, Moreno S, Molina R (2010) Catal Commun 12:173–179
Daza CE, Cabrera CR, Moreno S, Molina R (2010) Appl Catal A 378:125–133
Daza CE, Moreno S, Molina R (2011) Int J Hydrogen Energy 36:3886–3894
Malet P, Caballero A (1988) J Chem Soc I(84):2369–2375
Wu GD, Wang XL, Chen B, Li JP, Zhao N, Wei W (2007) Appl Catal A 329:106–111
Holgado MJ, Rives V, San Raman S (2001) Appl Catal A 214:219–228
Cantrell DG, Gillie LJ, Lee AF, Wilson K (2005) Appl Catal A 287:183–190
Rives V (2002) Mater Chem Phys 75:19–25
Melo F, Morlane N (2008) Catal Today 133–135:374–382
Das J, Das D, Parida KM (2006) J Colloid Interface Sci 301:569–574
Tsyganok AI, Inaba M, Tsunoda T, Hamakawa S, Suzuki K, Hayakawa T (2003) Catal Commun 4:493–498
Hai-Peng WU, Wen-jing LI, Li GUO, Yan-fei PAN, Xiu-feng XU (2011) J Fuel Chem Technol 39:550–555
Albertazzi S, Basile F, Benito P, Del Gallo P, Fornasari G, Gary D, Rosetti V, Vaccari A (2007) Catal Today 128:258–263
Sahli N, Petit C, Roger AC, Kiennemann A, Libs S, Bettahar MM (2006) Catal Today 113:187–193
Gonzalez-Delacruz VM, Ternero F, Pereníguez R, Caballero A, Holgado JP (2010) Appl Catal A 384:1–9
Holgado JP, Alvarez R, Munuera G (2000) Appl Surf Sci 161:301–315
Chen YG, Tomishige K, Yokoyama K, Fujimoto K (1997) App Catal A 165:335–347
Holgado JP, Munuera G (1995) Stud Surf Sci Catal 96:109–122
Cavani F, Trifiro F, Vaccari A (1991) Catal Today 11:173–301
Kloprogge JT, Frost RL (2001) In: Rives V (ed) Layered Double Hydroxides: Present and Future. Nova Science Publishers, New York, pp 139–192
Montoya JA, Romero-Pascal E, Gimon C, Del Angel P, Monzon A (2000) Catal Today 63:71–85
Djaidja A, Libs S, Kiennemann A, Barama A (2006) Catal Today 113:194–200
Tsyganok AI, Inaba M, Tsunoda T, Uchida K, Suzuki K, Takehira K (2005) Appl Catal A 292:328–343
Xu G, Shi K, Gao Y, Xu H, Wei Y (1999) J Mol Catal A 147:47–54
Gonzalez-DelaCruz VM, Holgado JP, Pereñíguez R, Caballero A (2008) J Catal 257:307–314
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Djebarri, B., Gonzalez-Delacruz, V.M., Halliche, D. et al. Promoting effect of Ce and Mg cations in Ni/Al catalysts prepared from hydrotalcites for the dry reforming of methane. Reac Kinet Mech Cat 111, 259–275 (2014). https://doi.org/10.1007/s11144-013-0646-2
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DOI: https://doi.org/10.1007/s11144-013-0646-2