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Fluorescence emission modulation in singlefluoroforic submicro-sized silica particles

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Abstract

A new class of singlefluoforic submicro-sized spherical silica particles based on an ESIPT-exhibiting dye is presented in this work. The particles are able to generate a modulated response in the blue–green region varying the incident excitation wavelength. The submicro silica particles present monodisperse size distribution with a size range of 0.9–0.95 μm. The morphology and homogeneity combined with the observed fluorescence emission modulation and the absence of energy transfer between the fluorescent dyes open up new perspectives in the application of these fluorescent particles in the field of optical sensors and devices.

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References

  1. Livage J (2001) New J Chem 25:1

    Article  CAS  Google Scholar 

  2. Corriu RJP (2001) New J Chem 25:2

    Article  CAS  Google Scholar 

  3. Gómez-Romero P, Sanchez C (2004) Functional hybrid materials. Wiley, NY

    Google Scholar 

  4. Burns A, Ow H, Wiesner U (2006) Chem Soc Rev 35:1028–1042

    Article  CAS  PubMed  Google Scholar 

  5. Jakob AM, Schmedake TA, Jakob AM (2006) Chem Mater 18:3173–3175

    Article  CAS  Google Scholar 

  6. Prodi L (2005) New J Chem 29:20–31

    Article  CAS  Google Scholar 

  7. Roy I, Ohulchanskyy TY, Pudavar HE, Bergey EJ, Oseroff AR, Morgan J, Dougherty TJ, Prasad PN (2003) J Am Chem Soc 125:7860–7865

    Article  CAS  PubMed  Google Scholar 

  8. Clark HA, Hoyer M, Philbert MA, Kopelman R (1999) Anal Chem 71:4831–4836

    Article  CAS  PubMed  Google Scholar 

  9. Klymchenko AS, Demchenko AP (2002) J Am Chem Soc 124:12372–12379

    Article  CAS  PubMed  Google Scholar 

  10. Lo L-W, Tsai P-J, Huang SH-Y, Chen W-Y, Wang Y-T, Chang C-H, Yang C-S (2005) Anal Chem 77:1125–1131

    Article  CAS  PubMed  Google Scholar 

  11. Wnag L, Yang C, Tan W (2005) Nano Lett 5:37–43

    Article  ADS  CAS  Google Scholar 

  12. Zhao X, Tapec-Dytioco R, Tan W (2003) J Am Chem Soc 125:11474–11475

    Article  CAS  PubMed  Google Scholar 

  13. Montalti M, Prodi L, Zaccheroni N, Zattoni A, Reschiglian P, Falini G (2004) Langmuir 20:2989–2991

    Article  CAS  PubMed  Google Scholar 

  14. Ireland JF, Wyatt PAH (1976) Adv Phys Org Chem 12:131–221

    Article  CAS  Google Scholar 

  15. Doroshenko AO, Posokhov EA, Verezubova AA, Ptyagina LM (2000) J Phys Org Chem 13:253–265

    Article  CAS  Google Scholar 

  16. Seo J, Kim S, Park S, Park SY (2005) Bull Korean Chem Soc 26:1706–1710

    Article  CAS  Google Scholar 

  17. Tong H, Zhou G, Wang L, Jing X, Wang F, Zhang J (2003) Tetrahedron Lett 44:131–134

    Article  CAS  Google Scholar 

  18. Rodembusch FS, Leusin FP, Bordignon LB, Gallas MR, Stefani V (2005) J Photochem Photobiol A: Chem 173:81–92

    Article  CAS  Google Scholar 

  19. Rodembusch FS, Campo LF, Rigacci A, Stefani V (2005) J Mater Chem 15:1537–1541

    Article  CAS  Google Scholar 

  20. Granzhan A, Ihmels H, Viola G (2007) J Am Chem Soc 129:1254–1267

    Article  CAS  PubMed  Google Scholar 

  21. Rodembusch FS, Leusin FP, Medina LFC, Brandelli A, Stefani V (2005) Photochem Photobiol Sci 4:254–259

    Article  CAS  PubMed  Google Scholar 

  22. Rodembusch FS, Campo LF, Leusin FP, Stefani V (2007) J Lumin 126:728–734

    Article  CAS  Google Scholar 

  23. Santra S, Dogra SK (1998) Chem Phys 226:285–296

    Article  CAS  ADS  Google Scholar 

  24. Campo LF, Corrêa DS, Araújo MA, Stefani V (2000) Macromol Rapid Commun 21:832–836

    Article  CAS  Google Scholar 

  25. Campo LF, Sanchez F, Stefani V (2006) J Photochem Photobiol A: Chem 178:26–32

    Article  CAS  Google Scholar 

  26. Ramos G, del Monte F, Zurro B, McCarthy KJ, Baciero A, Levy D (2002) Langmuir 18:984–986

    Article  CAS  Google Scholar 

  27. Ramasamy SM, Senthilnathan VP, Hurtubise RJ (1986) Anal Chem 58:612–616

    Article  CAS  Google Scholar 

  28. Anthony K, Brown RG, Hepworth JD, Hodgson KW, May B, West MA (1984) J Chem Soc Perkin Trans 2:2111–2117

    Google Scholar 

  29. Douhal A, Amat-Guerri F, Lillo MP, Acuña AU (1994) J. Photochem Photobiol A: Chem 1994(78):127–138

    Article  Google Scholar 

  30. Nagaoka S-I, Kusunoki J, Fujibuchi T, Hatakenaka S, Mukai K, Nagashima U (1999) J Photochem Photobiol A: Chem 122:151–159

    Article  CAS  Google Scholar 

  31. Montalti M, Prodi L, Zaccheroni N, Falini G (2002) J Am Chem Soc 124:13540–13546

    Article  CAS  PubMed  Google Scholar 

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Acknowledgments

We are grateful for scholarships and/or financial support from the Brazilian agencies CNPq, CAPES and FAPERGS.

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Correspondence to Valter Stefani.

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Kober, U.A., Gallas, M.R., Campo, L.F. et al. Fluorescence emission modulation in singlefluoroforic submicro-sized silica particles. J Sol-Gel Sci Technol 52, 305–308 (2009). https://doi.org/10.1007/s10971-009-2075-2

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  • DOI: https://doi.org/10.1007/s10971-009-2075-2

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