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Inversion of electron spin resonance signal in coals

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Journal of Applied Spectroscopy Aims and scope

Samples of coal from the Donetsk basin (carbon content ~90 mass%) in both lump and powder forms were studied by continuous-wave electron spin resonance (ESR) at room temperature in air. Inversion of the ESR signal (being in phase with modulation of the constant magnetic field) with an increase of lump size along the magnetic component of the microwave field was observed in the cavity of the radiospectrometer.

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References

  1. N. D. Rus’yanova, Coal Chemistry [in Russian], Nauka, Moscow (2003).

    Google Scholar 

  2. A. D. Alekseev, E. V. Ul’yanova, and T. A. Vasilenko, Usp. Fiz. Nauk, 175, No. 11, 1217–1232 (2005).

    Article  Google Scholar 

  3. V. K. Malinovskii, Fiz. Tverd. Tela, 41, No. 5, 805–808 (1999).

    Google Scholar 

  4. V. S. Dotsenko, Usp. Fiz. Nauk, 181, No. 3, 269–292 (2011).

    Article  Google Scholar 

  5. M. L. Gorbaty, Fuel, 73, No. 12, 1819–1828 (1994).

    Article  Google Scholar 

  6. G. D. Frolkov and A. G. Frolkov, Khim. Tverd. Topl., No. 1, 9–13 (2011).

  7. V. I. Al’shits, E. V. Darinskaya, M. V. Koldaeva, and E. A. Petrzhik, Fiz. Tverd. Tela, 54, No. 2, 305–312 (2012).

    Google Scholar 

  8. A. L. Buchachenko, Zh. Eksp. Teor. Fiz., 132, No. 3(9), 673–679 (2007).

  9. R. Sh. Vartapetyan and A. M. Voloshchuk, Usp. Khim., 64, No. 11, 1055–1072 (1995).

    Article  Google Scholar 

  10. I. I. Lishtvan, V. K. Zhukov, N. T. Kartel’, and L. V. Strigutskii, Khim. Tverd. Topl., No. 4, 50–57 (1999).

  11. E. Houzé and M. Nechtschein, Synth. Met., 84, Nos. 1–3, 947–948 (1997).

    Article  Google Scholar 

  12. L. S. Lyubchenko and M. L. Lyubchenko, Solid Fuel Chem., 32, No. 4, 19–41 (1998).

    Google Scholar 

  13. A. N. Gubkin, P. P. Zaitsev, V. A. Zagoruiko, E. M. Panchenko, O. I. Prokopalo, and G. D. Frolkov, Pisma Zh. Tekh. Fiz., 16, No. 5, 88–90 (1990).

    Google Scholar 

  14. V. A. Nikerov and G. V. Sholin, Kinetics of Dehydration Processes [in Russian], Energoatomizdat, Moscow (1985).

    Google Scholar 

  15. N. F. Uvarov and V. V. Boldyrev, Usp. Khim., 70, No. 4, 307–329 (2001).

    Article  Google Scholar 

  16. O. A. Petrii and G. A. Tsirlina, Usp. Khim., 70, No. 4, 330–344 (2001).

    Article  Google Scholar 

  17. V. A. Klimova, Principal Microanalytical Methods for Organic Compounds [in Russian], Khimiya, Moscow (1975).

    Google Scholar 

  18. F. F. Mazda, Electronic Instruments and Measurement Techniques, Cambridge University Press, Cambridge, New York (1987).

    Google Scholar 

  19. D. K. Schroder, Semiconductor Material and Device Characterization, Wiley, New York (2006).

    Google Scholar 

  20. M. Jonas, Radiat. Meas., 27, No. 5/6, 943–973 (1997).

    Article  Google Scholar 

  21. G. R. Eaton, S. S. Eaton, D. P. Barr, and R. T. Weber, Quantitative EPR, Springer, Vienna (2010).

    Book  Google Scholar 

  22. N. A. Poklonskii, T. M. Lapchuk, N. I. Gorbachuk, V. A. Nikolaenko, and I. V. Bachuchin, Fiz. Tekh. Poluprovodn., 39, No. 8, 931–934 (2005).

    Google Scholar 

  23. J. R. Harbridge, G. A. Rinard, R. W. Quine, S. S. Eaton, and G. R. Eaton, J. Magn. Reson., 156, No. 1, 41–51 (2002).

    Article  ADS  Google Scholar 

  24. J. A. Weil and J. R. Bolton, Electron Paramagnetic Resonance: Elementary Theory and Practical Applications, Wiley, New York (2007).

    Google Scholar 

  25. V. T. Dolgopolov, Usp. Fiz. Nauk, 130, No. 2, 241–278 (1980).

    Article  Google Scholar 

  26. A. V. Timofeev, Usp. Fiz. Nauk, 176, No. 11, 1227–1236 (2006).

    Article  Google Scholar 

  27. M. Giordano, M. Martinelli, L. Pardi, and S. Santucci, Phys. Rev. Lett., 59, No. 3, 327–330 (1987).

    Article  ADS  Google Scholar 

  28. D. Gourier, L. Binet, and O. Guillot-Noel, C. R. Chim., 7, Nos. 3–4, 293–302 (2004).

    Article  Google Scholar 

  29. V. F. Stel’makh and L. V. Strigutskii, Zh. Prikl. Spektrosk., 65, No. 2, 224–229 (1998).

    Google Scholar 

  30. M. Sueki, G. A. Rinard, S. S. Eaton, and G. R. Eaton, J. Magn. Reson., Ser. A, 118, No. 2, 173–188 (1996).

    Article  Google Scholar 

  31. A. I. Smirnov, E. N. Degtyarev, O. E. Yakimchenko, and Ya. S. Lebedev, Prib. Tekh. Eksp., No. 1, 195–200 (1991).

  32. S. A. Afanas’ev and D. I. Sementsov, Usp. Fiz. Nauk, 178, No. 4, 377–384 (2008).

    Article  Google Scholar 

  33. M. Dressel and G. Grüner, Electrodynamics of Solids: Optical Properties of Electrons in Matter, Cambridge University Press, Cambridge (2002).

    Book  Google Scholar 

  34. J. D. Jackson, Classical Electrodynamics, Wiley, New York (1998).

    Google Scholar 

  35. C. A. Balanis, P. W. Shepard, F. T. C. Ting, and W. F. Kardosh, IEEE Trans. Geosci. Rem. Sens., GE-18, No. 3, 250–256 (1980).

    Article  ADS  Google Scholar 

  36. C. A. Balanis, J. Microwave Power, 18, No. 1, 45–54 (1983).

    Google Scholar 

  37. M. Hotta, M. Hayashi, M. T. Lanagan, D. K. Agrawal, and K. Nagata, ISIJ Int., 51, No. 11, 1766–1772 (2011).

    Article  Google Scholar 

  38. I. G. Zamaleev, A. R. Kessel’, G. B. Teitel’baum, and E. G. Kharakhash’yan, Fiz. Met. Metalloved., 34, No. 1, 16–20 (1972).

    Google Scholar 

  39. A. I. Spitsyn, Zh. Tekh. Fiz., 75, No. 9, 60–63 (2005).

    Google Scholar 

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Correspondence to N. A. Poklonski.

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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 80, No. 3, pp. 379–384, May–June, 2013.

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Poklonski, N.A., Vyrko, S.A., Poklonskaya, O.N. et al. Inversion of electron spin resonance signal in coals. J Appl Spectrosc 80, 366–371 (2013). https://doi.org/10.1007/s10812-013-9775-7

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  • DOI: https://doi.org/10.1007/s10812-013-9775-7

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