Abstract
Supported MnCuCe and MnCe mixed oxides catalysts were prepared and evaluated in n-hexane combustion reaction. They presented an excellent catalytic activity in total combustion of n-hexane. Catalysts were characterized by means of XRD, XPS, SBET and TPR techniques. The addition of Cu did not enhance the catalytic activity of MnO x /Al2O3 due to the formation of the complete Mn2CuO4 spinel. The presence of cerium favored the formation of manganese oxide species with low crystallinity, with high oxygen mobility and high oxygen vacancies. A higher content of Ce was necessary to obtain catalysts with higher oxidation state of Mn and Ce species.
Graphical Abstract
Similar content being viewed by others
References
Larsson PO, Andersson A (1998) J Catal 179:72
Papaefthimiou P, Ioannides T, Verykios XE (1998) Appl Therm Eng 18:1005
Atkinson R, Arey J (2003) Chem Rev 103:4605
Everaert K, Baeyens J (2004) J Hazard Mater B 109:113
Spivey J (1987) Ind Eng Chem Res 26:2165
Burgos N, Paulis M, Antxustegi MM, Montes M (2002) Appl Catal B 38:251
Gil A, Vicente MA, Lambert JF, Gandía LM (2001) Catal Today 68:41
van den Brink RW, Louw R, Mulder P (1998) Appl Catal B 16:219
Scire S, Minico S, Crisafulli C (2003) Appl Catal B 45:117
Larsson PO, Andersson A (2000) Appl Catal B 24:175
Martínez-Arias A, Fernández-García M, Soria J, Conesa JC (1999) J Catal 182:367
Qi G, Yang RT (2003) J Catal 217:434
Liu W, Stephanopoulos MF (1995) J Catal 153:317
Avgouropoulos G, Ioannides T, Papadopoulou Ch, Batista J, Hocevar S, Matralis HK (2002) Catal. Today 75:157
Avgouropoulos G, Ioannides T (2006) Appl Catal B 67:1
Trovarelli A, de Leitenmburg C, Dolcetti G (1997) ChemTech 27:32
Yao MH, Baird RJ, Kunz FW, Hoost TE (1997) J Catal 166:67
Schmitz PJ, Usmen RK, Peters CR, Graham GW, McCabe RW (1993) Appl Surf Sci 72:181
Zafiris GS, Gorte RJ (1993) J Catal 143:86
Hori CE, Permana H, Ng KYS, Brenner A, More K, Rahmoeller KM, Belton DN (1998) Appl Catal B 16:105
Lin R, Zhong YJ, Luo MF, Liu WP (2001) Indian J Chem A 40:36
Arena F, Trunfio G, Negro J, Fazio B, Spadaro L (2007) Chem Mater 19:2269
Stobbe ER, de Boer BA, Geus JW (1999) Catal Today 47:161
Kim SC, Shim WG (2010) Appl Catal B 98:180
Tang X, Li Y, Huang X, Xu Y, Zhu H, Wang J, Shen W (2006) Appl Catal B 62:265
Li TY, Chiang SJ, Liaw BJ, Chen YZ (2011) Appl Catal B 103:143
Morales MR, Barbero BP, Cadús LE (2008) Fuel 87:1177
Avila P, Montes M, Miro E (2005) Chem Eng J 11:11
Huang SJ, Walters AB, Vannice MA (2000) J Catal 192:29
Park PW, Kil JK, Kung HH, Kung MC (1998) Catal Today 42:51
Barr TL, Fries CG, Cariati F, Bart JCJ, Giordano N, Trans Dalton (1983) J Chem Soc 9:1825
Shyu JZ, Otto K, Watkins WLH, Graham GW, Belitz RK, Gandhi HS (1988) J Catal 114:23
Schmitz P, Usmen R, Peters C, Graam J, McCabe R (1993) Appl Surf Sci 72:181
Fernandez-Garcia M, Gomez-Rebollo E, Guerrero Ruiz A, Conesa JC, Soria J (1997) J Catal 172:146
Jiratova K, Mikulova J, Klempa J, Grygar T, Bastl Z, Kovanda F (2009) Appl Catal A 361:106
Burgos N, Paulis M, Montes M (2003) J Mater Chem 13:1458
Aguero FN, Scian A, Barbero BP, Cadús LE (2008) Catal Today 133(135):493
Lahousse C, Bernier A, Grange P, Delmon B, Papaefthimiou P, Ionnides T, Verykios X (1998) J Catal 178:214
Lamaita L, Peluso MA, Sambeth JE, Thomas HJ (2005) Appl Catal B 611:28
Picasso G, Gutierrez M, Pina MP, Erguido J (2007) Chem Eng J 126:119
Tichenor BA, Palazzolo MA (1987) Environ Prog 6:172
Hutchings GJ, Mirzaei AA, Joyner RW, Siddiqui MRH, Taylor SH (1998) Appl Catal A 166:143
Mirzaei AA, Shaterian HR, Habibi M, Hutchings GJ, Taylor SH (2003) Appl Catal A 253:499
White WB, Keramidas VG (1972) Spectrochim Acta A 28:501
McCabe RW, Mitchell PJ (1984) Ind Eng Chem Prod Res Dev 23:196
Hutchings GJ, Mirzaei AA, Joyner RW, Siddiqui MRH, Taylor SH (1998) Appl Catal A 166:143
Tanaka Y, Utaka T, Kikuchi R, Takeguchi T, Sasaki K, Eguchi K (2003) J Catal 215:271
Larachia F, Pierrea J, Adnota A, Bernis A (2002) Appl Surf Sci 195:236
Águila G, Gracia F, Araya P (2008) Appl Catal A 343:16
Hu C, Zhu Q, Jiang Z, Chen L, Wu R (2009) Chem Eng J 152:583
Blanco G, Cauqui MA, Delgado JJ, Galtayries A, Perez-Omil JA, Rodríguez-Izquierdo JM (2004) Surf. Interface Anal 367:52
Li T, Chiang S, Liaw B, Chen Y (2011) Appl Catal B 103:143
Kapteijn F, Singoredjo L, Andreini A (1994) Appl Catal B 3:173
Park JS, Doh DS, Lee KY (2000) Top Catal 10:127
Acknowledgments
The financial support from UNSL, CONICET and ANPCyT of Argentina is gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Morales, M.R., Agüero, F.N. & Cadus, L.E. Catalytic Combustion of n-Hexane Over Alumina Supported Mn–Cu–Ce Catalysts. Catal Lett 143, 1003–1011 (2013). https://doi.org/10.1007/s10562-013-1083-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-013-1083-6