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Gas-Phase Maleic Anhydride Hydrogenation Over Ni/SiO2–Al2O3 Catalysts: Effect of Metal Loading

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Abstract

The gas-phase maleic anhydride hydrogenation was studied at 170 °C and 1 bar using Ni/SiO2–Al2O3 catalysts varying metal loading. The maximum γ-butyrolactone selectivity was reached for a 10 wt% nickel load. On the basis of temperature programmed experiments, it is proposed that new active sites in selective succinic anhydride hydrogenolysis are formed when Ni loads are higher than 8 wt%.

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Acknowledgments

We thank to Universidad Nacional del Litoral (UNL), Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) and Agencia Nacional de Promoción Científica y Tecnológica (ANPCyT), Argentina, for the financial support to this work.

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Authors and Affiliations

  1. Catalysis Science and Engineering Research Group (GICIC), Instituto de Investigaciones en Catálisis y Petroquímica—INCAPE, Universidad Nacional del Litoral—CONICET, Santiago del Estero 2654, S3000AOJ, Santa Fe, Argentina

    C. I. Meyer, S. A. Regenhardt, M. E. Bertone, A. J. Marchi & T. F. Garetto

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  1. C. I. Meyer
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  2. S. A. Regenhardt
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  3. M. E. Bertone
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  4. A. J. Marchi
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  5. T. F. Garetto
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Correspondence to T. F. Garetto.

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Meyer, C.I., Regenhardt, S.A., Bertone, M.E. et al. Gas-Phase Maleic Anhydride Hydrogenation Over Ni/SiO2–Al2O3 Catalysts: Effect of Metal Loading. Catal Lett 143, 1067–1073 (2013). https://doi.org/10.1007/s10562-013-1069-4

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  • DOI: https://doi.org/10.1007/s10562-013-1069-4

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