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Reversible Modification of Magnetic Properties of Fe3C Nanoparticles by Chemisorption of CO

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Abstract.

The paper is devoted to the electron spin resonance and magnetic measurements of Fe3C nanoparticles covered by a carbon structure. There is a reversible modification of the magnetic properties by the chemisorption of CO and O2. The CO chemisorption results in the transition of the majority of the Fe3C nanoparticles from the ferromagnetic to the superparamagnetic state. The O2 chemisorption results in the backward transition.

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Authors and Affiliations

  1. Institute of Chemical Kinetics and Combustion, Russian Academy of Sciences, Novosibirsk, Russia

    N. A. Ivanova, A. A. Onischuk, S. V. Vosel & P. A. Purtov

  2. Institute of Geology and Mineralogy, Russian Academy of Sciences, Novosibirsk, Russia

    S. V. Vosel

  3. Novosibirsk State University, Novosibirsk, Russia

    P. A. Purtov

  4. Boreskov Institute of Catalysis, Russian Academy of Sciences, Novosibirsk, Russia

    N. T. Vasenin & V. F. Anufrienko

  5. International Tomography Center, Russian Academy of Sciences, Novosibirsk, Russia

    V. N. Ikorski

Authors
  1. N. A. Ivanova
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  2. A. A. Onischuk
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  3. S. V. Vosel
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  4. P. A. Purtov
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  5. N. T. Vasenin
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  6. V. F. Anufrienko
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  7. V. N. Ikorski
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Authors' address: Petr A. Purtov, Institute of Chemical Kinetics and Combustion, Institutskaya ulitsa 3, Novosibirsk 630090, Russia

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Ivanova, N., Onischuk, A., Vosel, S. et al. Reversible Modification of Magnetic Properties of Fe3C Nanoparticles by Chemisorption of CO. Appl Magn Reson 33, 285–291 (2008). https://doi.org/10.1007/s00723-008-0073-0

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  • DOI: https://doi.org/10.1007/s00723-008-0073-0

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