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Monolayer assembly and striped architecture of Co nanoparticles on organic functionalized Si surfaces

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Abstract

We present a new strategy to fabricate a monolayer assembly of Br-terminated Co nanoparticles on functionalized Si surfaces by using chemical covalent bonding and microcontact printing method. Self-assembled monolayers (SAMs) of the Co nanoparticles formed on the hydroxyl-terminated Si surface exhibit two-dimensional island networks with locally ordered arrays via covalent linkage between nanoparticles and surface. On the other hand, SAMs of the nanoparticles on the aminopropyl-terminated Si surface show an individual and random distribution over an entire surface. Furthermore, we have fabricated striped architectures of Co nanoparticles using a combination of microcontact printing and covalent linkage. Microcontact printing of octadecyltrichlorosilane and selective covalent linkage between nanoparticles and functionalized Si surfaces lead to a hybrid nanostructure with selectively assembled nanoparticles stripes on the patterned functionalized Si surfaces.

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Authors and Affiliations

  1. Department of Chemistry and School of Molecular Science (BK 21), Korea Advanced Institute of Science and Technology, Daejeon, 305-701, South Korea

    S.-S. Bae, D.K. Lim, J.-I. Park & S. Kim

  2. Department of Chemistry, College of Sciences, Yonsei University, Seoul, 120-749, South Korea

    J. Cheon

  3. Department of Chemistry, College of Natural Sciences, Chonbuk National University, Jeonju, Chonbuk, 561-756, South Korea

    I.C. Jeon

Authors
  1. S.-S. Bae
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  2. D.K. Lim
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  3. J.-I. Park
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  4. J. Cheon
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  5. I.C. Jeon
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  6. S. Kim
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Correspondence to S.-S. Bae.

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PACS

81.07.Ta; 61.46.+w; 81.16.Dn; 81.16.Be; 68.37.Hk; 82.80.Pv

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Bae, SS., Lim, D., Park, JI. et al. Monolayer assembly and striped architecture of Co nanoparticles on organic functionalized Si surfaces. Appl. Phys. A 80, 1305–1310 (2005). https://doi.org/10.1007/s00339-004-3159-z

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  • DOI: https://doi.org/10.1007/s00339-004-3159-z

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