Conclusions
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1.
The α,α,ω-trihydroperfluoroalkyl esters of phosphorous acid react with polyfluorocarbonyl compounds the same as unfluorinated phosphites, but exhibit a lower reactivity.
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2.
The reaction of tris (1,1,3-trihydroperfluoropropyl) phosphite with the hydrates of hexafluoroacetone and trifluoroacetaldehyde respectively givesα-monohydroperfluoroisopropyl bis (1,1,3-trihydroperfluoropropyl) phosphate and 2,2,2-trifluoroethyl bis (1,1,3-trihydroperfluoropropyl) phosphate.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1655–1658, July, 1981.
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Fokin, A.V., Studnev, Y.N., Rapkin, A.I. et al. Reaction of α,α,ω-trihydroperfluoroalkyl esters of phosphorous acid with polyfluorocarbonyl compounds. Russ Chem Bull 30, 1344–1347 (1981). https://doi.org/10.1007/BF01418013
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DOI: https://doi.org/10.1007/BF01418013