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Binding studies of sodium dodecyl benzene sulphonate with poly(N-vinyl-2-pyrrolidone)

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Abstract

The binding of sodium dodecyl benzene sulphonate (SDBS) with poly(N-vinyl-2-pyrrolidone) (PVP) has been investigated at 303.15 and 313.15 K using equilibrium dialysis, surface tension, viscosity, ultrasound velocity and ultrasound absorption techniques. From each of these studies four distinct regions of SDBS-PVP interactions were observed. Interaction of SDBS with PVP was found to involve the binding of surfactant dimers with the polymer molecule followed by usual micellization. The binding data has been analyzed in terms of various models of polymer-surfactant interaction.

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Author notes

  1. K. Anand

    Present address: Department of Chemistry & Biochemistry, Haryana Agricultural University, 125 004, Hisar, India

Authors and Affiliations

  1. Department of Chemistry & Biochemistry, Haryana Agricultural University, 125 004, Hisar, India

    O. P. Yadav

  2. Chemistry Department, M.D. University, Rohtak, India

    P. P. Singh

Authors
  1. K. Anand
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  2. O. P. Yadav
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  3. P. P. Singh
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Anand, K., Yadav, O.P. & Singh, P.P. Binding studies of sodium dodecyl benzene sulphonate with poly(N-vinyl-2-pyrrolidone). Colloid Polym Sci 270, 1201–1207 (1992). https://doi.org/10.1007/BF01095061

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  • DOI: https://doi.org/10.1007/BF01095061

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