Conclusions
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1.
The boron atom is capable of coordinating four perchlorato groups with the formation of the complex anion [B(ClO4)4]−.
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2.
The properties of cesium perchloratoborate were studied. The low heat stability of Cs[B(ClO4)4] is explained by the substantial deviation in the symmetry of the ClO4 groups from tetrahedral and a weakening of the Cl-O(B) bonds.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 873–875, April, 1971.
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Rosolovskii, V.Y., Babaeva, V.P. Some properties of cesium perchloratoborate. Russ Chem Bull 20, 792–794 (1971). https://doi.org/10.1007/BF00853930
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DOI: https://doi.org/10.1007/BF00853930