Some properties of cesium perchloratoborate

  • V. Ya. Rosolovskii
  • V. P. Babaeva
Brief Communications

DOI: 10.1007/BF00853930

Cite this article as:
Rosolovskii, V.Y. & Babaeva, V.P. Russ Chem Bull (1971) 20: 792. doi:10.1007/BF00853930

Conclusions

  1. 1.

    The boron atom is capable of coordinating four perchlorato groups with the formation of the complex anion [B(ClO4)4].

     
  2. 2.

    The properties of cesium perchloratoborate were studied. The low heat stability of Cs[B(ClO4)4] is explained by the substantial deviation in the symmetry of the ClO4 groups from tetrahedral and a weakening of the Cl-O(B) bonds.

     

Copyright information

© Consultants Bureau 1971

Authors and Affiliations

  • V. Ya. Rosolovskii
    • 1
  • V. P. Babaeva
    • 1
  1. 1.N. S. Kurnakov Institute of General and Inorganic ChemistryAcademy of Sciences of the USSRUSSR