Abstract
LiMn2O4 (LMO) is a very attractive choice as cathode material for power lithium-ion batteries due to its economical and environmental advantages. However, LiMn2O4 in the 4-V region suffers from a poor cycling behavior. Recent research results confirm that modification by coating is an important method to achieve improved electrochemical performance of LMO, and the latest progress was reviewed in the paper. The surface treatment of LMO by coating oxides and nonoxide systems could decrease the surface area to retard the side reactions between the electrode and electrolyte and to further diminish the Mn dissolution during cycling test. At present, LiMn2O4 is the mainstreaming cathode material of power lithium-ion battery, and, especially the modified LMO, is the trend of development of power lithium-ion battery cathode material in the long term.
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Thackeray MM, Johnson PJ, de Picciotto LA, Bruce PG, Goodenough JB (1984) Mater Res Bull 19:179
Amatucci GG, Schmutz CN, Blyr A, Sigala C, Gozdz AS, Larcher D, Tarascon JM (1997) J Power Sources 69:11
Wohlfahrt-Mehrens M, Vogler C, Garche J (2004) J Power Sources 127:58
Xia Y, Zhou Y, Yoshio M (1997) J Electrochem Soc 144:2593
Xia Y, Zhang Q, Wang H, Nakamura H, Noguchi H, Yoshio M (2007) Electrochim Acta 52:4708
Jeong I-S, Kim J-U, Gu H-B (2001) J Power Sources 102:55
Sun Y-K, Hong K-J, Prakash J, Amine K (2002) Electrochem Commun 4:344
Ein-Eli Y, Vaughey JT, Thackeray MM, Mukerjee S, Yang XQ, McBreen J (1999) J Electrochem Soc 146:908
Molenda J, Marzec J, Świerczek K, Pałubiak D, Ojczyk W, Ziemnicki M (2004) Solid State Ionics 175:297
Yi TF, Hu XG, Huo HB, Gao K (2006) Rare Metal Mat Eng 35:1350
Arora P, White RE, Doyle M (1998) J Electrochem Soc 145:3647
Aubarch D, Zaban A, Schlecter A, Ein-Eli Y, Zinigrad E, Markowsky B (1995) J Electrochem Soc 142:2873
Jang DH, Oh SM (1997) J Electrochem Soc 144:3342
Arumugam D, Kalaignan GP (2008) J Electroanal Chem 624:197–204
Lim S, Cho J (2008) Chem Commun 37:4472–4474
Gnanaraj JS, Pol VG, Gedanken A, Aurbach D (2003) Electrochem Commun 5:940–945
Liu D, Liu X, He Z (2007) J Alloys Compd 436:387–391
Tu J, Zhao XB, Xie J, Cao GS, Zhuang DG, Zhu TJ, Tu JP (2007) J Alloys Compd 432:313–317
Liu H, Cheng C, Hu Z, Zhang K (2007) Mater Chem Phys 101:276–279
Liu H, Cheng C, Hu Z, Zhang K (2005) J Mater Sci 40:5767–5769
Ha H-W, Yun NJ, Kim K (2007) Electrochim Acta 52:3236–3241
Lin Y-M, Wu H-C, Yen Y-C, Guo Z-Z, Yang M-H, Chen H-M, Sheu H-S, Wu N-L (2005) J Electrochem Soc 152:A1526–A1532
Kim J-S, Johnson CS, Vaughey JT, Hackney SA, Walz KA, Zeltner WA, Anderson MA, Thackeray MM (2004) J Electrochem Soc 151:A1755–A1761
Lee S-W, Kim K-S, Moon H-S, Kim H-J, Cho B-W, Cho W-I, Ju J-B, Park J-W (2004) J Power Sources 126:150–155
Yang Z, Yang W, Evans DG, Zhao Y, Wei X (2009) J Power Sources 189:1147–1153
Cho J, Kim Y-W, Kim B, Lee J-G, Park B (2003) Angew Chem Int Ed 42:1618
Cho J, Lee J-G, Kim B, Park B (2003) Chem Mater 15:3190
Liu DQ, He ZZ, Liu XQ (2007) Mater Lett 25:4703
Tu J, Zhao XB, Cao GS, Tu JP, Zhu TJ (2006) Mater Lett 60:3251–3254
Zhou W-J, He B-L, Li HL (2008) Mater Res Bull 43:2285
Son JT, Park KS, Kim HG, Chung HT (2004) J Power Sources 126:182
Kannan AM, Manthiram A (2002) Electrochem Solid State Lett 5:A167
Park SC, Kim YM, Kang YM, Kim KT, Lee PS, Lee JY (2001) J Power Sources 103:86
Park SC, Han YS, Kang YS, Lee PS, Ahn S, Lee HM, Lee JY (2001) J Electrochem Soc 148:A680
Liu Z, Wang H, Fang L, Lee JY, Gan LM (2002) J Power Sources 104:101
Park S-C, Kim Y-M, Han S-C, Ahn S, Ku C-H, Lee J-Y (2002) J Power Sources 107:42
Liu D-Q, Liu X-Q, He Z-Z (2007) Mater Chem Phys 105:362–366
Liu D-Q, Yu J, Sun Y-H, He Z-Z, Liu X-Q (2007) Chin J Inorg Chem 23:41
Yuan YF, Wu HM, Guo SY, Wu JB, Yang JL, Wang XL, Tu JP (2008) Appl Surf Sci 255:2225
Chan H-W, Duh J-G, Sheu H-S (2006) J Electrochem Soc 153:A1533
Han AR, Kim TW, Park DH, Hwang S-J, Choy J-H (2007) J Phys Chem C 111:11347
Patey TJ, Büchel R, Ng SH, Krumeich F, Pratsinis SE, Novák P (2009) J Power Sources 189:149
Li JG, He XM, Zhao RS (2007) Trans Nonferrous Met Soc China (English Edition) 17:1324
Lee K-S, Myung S-T, Amine K, Yashiro H, Sun Y-K (2009) J Mater Chem 19:1995
Eddrief M, Dzwonkowski P, Julien C, Balkanski M (1991) Solid State Ionics 45:77
Soppe W, Aldenkamp F, den Hartog HW (1987) J Non-Cryst Solids 91:351
Chan H-W, Duh J-G, Sheen S-R (2004) Surf Coat Technol 188–189:116
Şahan H, Göktepe H, Patat Ş, Ülgen A (2008) Solid State Ionics 178:1837
Chan HW, Duh JG, Sheen SR (2006) Electrochim Acta 51:3645
Hu G, Wang X, Chen F, Zhou J, Li R, Deng Z (2005) Electrochem Commun 7:383
Arbizzani C, Mastragostino M, Rossi M (2002) Electrochem Commun 4:545
Li C, Zhang HP, Fu LJ, Liu H, Wu YP, Rahm E, Holze R, Wu HQ (2006) Electrochim Acta 51:3872–3883
Hung F-Y, Lui T-S, Liao H-C (2007) Appl Surf Sci 253:7443
Vidu R, Stroeve P (2004) Ind Eng Chem Res 43:3314
Sugita M, Noguchi H, Soejima Y, Yoshio M (2000) Electrochemistry 68:587
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An erratum to this article can be found at http://dx.doi.org/10.1007/s11581-009-0386-5
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Yi, TF., Zhu, YR., Zhu, XD. et al. A review of recent developments in the surface modification of LiMn2O4 as cathode material of power lithium-ion battery. Ionics 15, 779–784 (2009). https://doi.org/10.1007/s11581-009-0373-x
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DOI: https://doi.org/10.1007/s11581-009-0373-x