Skip to main content
Log in

Molecular fossil and paleovegetation records of paleosol S4 and adjacent loess layers in the Luochuan loess section, NW China

  • Published:
Science in China Series D: Earth Sciences Aims and scope Submit manuscript

Abstract

Using gas chromatography-mass spectrometry (GC-MS) technique, a series of biomarkers were identified, including n-alkanes, n-alkane-2-ones, isoprenoid etc. from the loess-paleosol samples collected from the S4 and adjacent L5, L4 of the Luochuan loess section, Northwestern China. Based on these data, especially n-alkanes and high-resolution magnetic susceptibility and grain size data, the paleoenvironment and paleovegetation history during S4 was reconstructed. The CPI (Carbon Predominance Index) and correlation between n-alkanes and magnetic susceptibility and grain size data demonstrated that the molecular fossils in paleosol and loess layers can reflect the vegetation condition during the loess-paleosol formation, if the allochthonous organic inputs could be excluded reasonably. The ACL (average chain length) index is correlated well with paleomagnetic susceptibility and grain size variations, displaying their good synchrony with warm and humid climate. However, it relatively lagged behind the paleomagnetic susceptibility and the grain size variations when the climate began to deteriorate. During the formation period of paleosol, the n-alkanes was dominated by C31 homologue, indicating that the primary organic input originated from herbs. Our study also demonstrated that the herbs were more flourish than wood plants in Loess Plateau, especially in the Luochuan area during the warm and humid phase, and there was no typical forest vegetation developed in the studied period.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Fu J M, Sheng G Y. Molecular organic geochemistry and its application to the study of paleoclimate and paleoenvironments. Quat Sci (in Chinese with English abstract), 1992, (4): 306–320

  2. Ohkouchi N, Kawamura K, Taira A. Molecular paleoclimatology: Reconstruction of climate variabilities in the late Quaternary. Org Geochem, 1997, 27: 173–183

    Article  Google Scholar 

  3. Simoneit B R T, Sheng G Y, Chen X J, et al. Molecular marker study of extractable organic matter in aerosols from urban areas of China. Atmos Environ, 1991, 25A(10): 2111–2129

    Google Scholar 

  4. Volkmam J K, Barrett S M, Blackbum S I, et al. Allkenones in gephyrocapsa oceanica: Implications for studies of paleoclimate. Geochim Cosmochim Acta, 1995, 59: 513–520

    Article  Google Scholar 

  5. Pearson A, McNichol A P, Benitez-Nelson B C, et al. Origins of lipid biomarkers in Santa Monica Basin surface sediment: A case study using compound—Specific Δ14C analysis. Geochim Cosmochim Acta, 2001, 65: 3123–3137

    Article  Google Scholar 

  6. Lu B, Chen R H, Wang Z P, et al. Ocean environment change in the Bering Sea over the past 100 years—Evidences from the molecular fossil. Sci China Ser D-Earth Sci, 2005, 48(4): 555–564

    Article  Google Scholar 

  7. Meyers P A, Ishiwatari R. Lacustrine Organic Geochemistry: An overview of indicators of organic matters sources and diagenesis in lake sediments. Org Geochem, 1993, 20(7): 867–900

    Article  Google Scholar 

  8. Zhang H C, Chang F Q, Li B, et al. Branched aliphatic alkanes of the Late Pleistocene paleolake deposits from the Qaidam Basin, NE Tibetan Plateau. Chin Sci Bull, 2007, 52(9): 1248–1256

    Article  Google Scholar 

  9. Sheng G Y, Cai K Q, Yang X X, et al. Long-chain alkenones in Hotong Qagan Nur lake sediments and its paleoclimatic implications. Chin Sci Bull, 1999, 44(3): 259–263

    Article  Google Scholar 

  10. Xie S C, Evershed R P. Peat molecular fossils recording climatic variation and organism replacement. Chin Sci Bull, 2001, 46(10): 863–866

    Google Scholar 

  11. Xie S C, Yi Y, Huang J H, et al. Lipid distribution in a subtropical southern China stalagmite as a record of soil ecosystem response to paleoclimate change. Quat Res, 2003, 60(3): 340–347

    Article  Google Scholar 

  12. Xie S C, Yao T D, Kang S C, et al. Geochemical analysis of a Himalayan snowpit profile: Implication for atmospheric pollution and climate. Org Geochem, 2000, 31: 15–23

    Article  Google Scholar 

  13. Xie S C, Wang Z Y, Wang H M, et al. The occurrence of a grassy vegetation over the Chinese Loess Plateau since the last inter-glacier: The molecular fossil record. Sci China Ser D-Earth Sci, 2002, 45(1): 53–62

    Article  Google Scholar 

  14. Wang Z Y, Xie S C, Chen F H. n-Alkane distributions as indicators for paleo-vegetation from Yuanbao S1 paleosol in Linxia, Gansu Province. Quat Sci (in Chinese with English abstract), 2004, 24(2): 231–235

    Google Scholar 

  15. Yang M S, Zhang H C, Lei G L, et al. Biomarkers in weakly developed paleosol (L1SS1) in the luochuan loess section and reconstructed paleovegetation-environment during the interstade of the last glaciation. Quat Sci (in Chinese with English abstract), 2006, 26(6): 984–996

    Google Scholar 

  16. Mitra S, Bianch T S, Guo L, et al. Terrestrially derived dissolved organic matter in the Chesapeake Bay and the Middle Atlantic Bight. Geochim Cosmochim Acta, 2000, 64: 3547–3557

    Article  Google Scholar 

  17. Williams M A J, Dunkertey D L, de Deckker P, et al. Quaternary Environments. Beijing: Science Press, 1997. 189–239

    Google Scholar 

  18. Liu T S. Loess and the Environment. Beijing: China Ocean Press, 1985. 1–251

    Google Scholar 

  19. Kukla G J, Heller F, Liu X M, et al. Pleistocene climate in China dated by magnetic susceptibility. Geology, 1998, 16: 811–814

    Article  Google Scholar 

  20. An Z S, Porter S, Kukla G, et al. The susceptibility evidence of the monsoon variation in the Loess Plateau since recent 130,000 years. Chin Sci Bull, 1990, 35(7): 529–532

    Google Scholar 

  21. Yang M S, Zhang H C, Ding H, et al. 14C dating of paleosol and animal remains in loess deposit: A comparative study. Earth Sci-J China Univ of Geosci (in Chinese with English abstract), 2005, 30(5): 589–596

    Google Scholar 

  22. Kukla G, An Z. Loess stratigraphy in central China. Palaeogeogr Palaeoclimatol Palaeoeocol, 1989, 72: 203–225

    Article  Google Scholar 

  23. Zhang Z H, Zhao M X, Lu H Y, et al. Lower temperature as the main cause of C4 plant declines during the glacial periods on the Chinese Loess Plateau. Earth Planet Sci Lett, 2003, 214: 467–481

    Article  Google Scholar 

  24. Zhang Z H, Zhao M X, Eglinton G, et al. Leaf wax lipids as paleovegetational and paleoenvironmental proxies for the Chinese Loess Plateau over the last 170 kyr. Quat Sci Rev, 2006, 25: 575–594

    Article  Google Scholar 

  25. Liu W G, Huang Y S, An Z S, et al. Summer monsoon intensity controls C4/C3 plant abundance during the last 35 ka in the Chinese Loess Plateau: Carbon isotope evidence from bulk organic matter and individual leaf waxes. Palaeogeogr Palaeoclimatol Palaeoecol, 2005, 220: 243–254

    Article  Google Scholar 

  26. Lei G L, Zhang H C, Zhang W X, et al. The reliability and significance of the grainsize obtained by Mastersize 2000 laser analyzer. Acta Sediment Sin (in Chinese with English abstract), 2006, 24(4): 531–539

    Google Scholar 

  27. Simoneit B R T, Cardoso J N, Robinson N. An assessment of terrestrial higher molecular weight lipid compounds in aerosol particulate matter over the south Atlantic from about 30-705. Chemosphere, 1991, 23: 447–465

    Article  Google Scholar 

  28. Sicre M A, Marty J C, Saliot A, et al. Aliphatic and aromatic hydro-carbons in different sized aerosols over the Mediterranean Sea: Occurrence and origin. Atmos Environ, 1987, 21(10): 2247–2259

    Article  Google Scholar 

  29. Schneider J K, Gagosian R B, Cochran J K, et al. Particle size distribution of n-alkanes and 210Pb in aerosols off the coast of Peru. Nature, 1983, 304: 429–432

    Article  Google Scholar 

  30. Cranwell P A. Chain-length distribution of n-alkanes from lake sediments in relation to post—Glacial environmental change. Freshwater Biol, 1973, 3: 259–265

    Article  Google Scholar 

  31. Cranwell P A, Eblinton G, Robinson N. Lipids of aquatic organisms as potential contributors to lacustrine sediments. Org Geochem, 1987, 11: 513–527

    Article  Google Scholar 

  32. Schwark L, Zink K, Lechterbeck J. Reconstruction of postglacial to early Holocene vegetation history in terrestrial Central Europe via cuticular lipid biomarkers and pollen records from lake sediments. Geology, 2002, 30: 463–466

    Article  Google Scholar 

  33. Poynter J G, Farrimond P, Brassel S C, et al. Aeolian-derived higher-plant lipids in the marine sedimentary record: Links with paleoclimate. In: Leinen M, Sarnthein M, eds. Palaeoclimatology and Palaeometeorology: Modern and Past Patterns of Global Atmosphere Transport. Amsterdam: Kluwer, 1989. 426–435

    Google Scholar 

  34. Zhou W J, Xie S C, Meyers P A, et al. Reconstruction of late glacial and Holocene climate evolution in southern China from geolipids and pollen in the Dingnan peat sequence. Org Geochem, 2005, 36: 1272–1284

    Article  Google Scholar 

  35. Schefuss E, Ratmeyer V, Stuut J B W, et al. Carbon isotope analysis of n-alkanes in dust from the lower atmosphere over the central eastern Atlantic. Geochem Cosmochim Acta, 2003, 67(10): 1757–1767

    Article  Google Scholar 

  36. Gagosian R B, Peltzer E T, Merrill J T. The importance of atmospheric input of terrestrial organic material to deep sea sediments. Org Geochem, 1986, 10: 661–669

    Article  Google Scholar 

  37. Hanisch S, Ariztegui D, Püttmann W. The biomarker record of Lake Albano, central Italy—Implications for Holocene aquatic system response to environmental change. Org Geochem, 2003, 34: 1223–1235

    Article  Google Scholar 

  38. Schwark L, Zink K, Lechterbeck J. Reconstruction of Postglacial to Early Holocene vegetation history in terrestrial Mid-Europe via cuticular lipid biomarkers and pollen records from lake sediments. Geology, 2002, 30: 463–466

    Article  Google Scholar 

  39. Rommerskirchen F, Eglinton G, Dupont L, et al. A north to south transect of Holocene southeast Atlantic continental margin sediments: Relationship between aerosol transport and compound-specific δ13C land plant biomarker and pollen records. Geochem Geophys Geosys, 2003, 4(12): 1101

    Article  Google Scholar 

  40. Shi J S, Li Z H, Wei M J, et al. Loess and Paleoclimate Evolution (in Chinese). Beijing: Geological Press, 1998. 26–34

    Google Scholar 

  41. Fakes L A, Sun J A. Carbon isotope record of the upper Chinese loess sequence estimates of plant types during stadials and interstadials. Palaeogeogr Palaeoclimatol Palaeocol, 1994, 108: 183–189

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yang MingSheng.

Additional information

Supported by the Hundred Talent Project of Chinese Academy of Sciences and the National Natural Science Foundation of China (Grant No. 40371117)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhang, H., Yang, M., Zhang, W. et al. Molecular fossil and paleovegetation records of paleosol S4 and adjacent loess layers in the Luochuan loess section, NW China. Sci. China Ser. D-Earth Sci. 51, 321–330 (2008). https://doi.org/10.1007/s11430-008-0012-9

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11430-008-0012-9

Keywords

Navigation